Nickel tetrafluoroborate
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Nickel tetrafluoroborate
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CAS No:
14708-14-6
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Formula:
BF4.1/2Ni
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Chemical Name:
Nickel tetrafluoroborate
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Synonyms:
Borate(1-),tetrafluoro-,nickel(2+) (2:1);Borate(1-),tetrafluoro-,nickel(2+);Nickel tetrafluoroborate;Nickel fluoborate (Ni(BF4)2);Nickel fluoroborate;Nickelous tetrafluoroborate;Nickel tetrafluoroborate (Ni(BF4)2);Nickel borofluoride;Nickel(2+) tetrafluoroborate(1-);Nickel(II) tetrafluoroborate;Nickel bis(tetrafluoroborate);Nickel(2+) tetrafluoroborate;27494-85-5
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CAS No:
Description
NICKEL FLUOROBORATE is a green odorless aqueous solution. Sinks in and mixes with water. (USCG, 1999)
Nickel fluoroborate is a green odorless aqueous solution. Sinks in and mixes with water. (USCG, 1999)
Nickel fluoroborate is a green odorless aqueous solution. Sinks in and mixes with water. (USCG, 1999)
Characteristics
0
2.60000
greenIish solution
1.5 at 68° F (USCG, 1999)
Water soluble.
Non-Redox-Active Inorganic Compounds
Acidic inorganic salts, such as NICKEL FLUOROBORATE, are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions.
Safety Information
III
6.1(b)
1759
45-34-42/43-31
53-45-36/37/39-26-23
QR6650000
T,C
Corrosive
P201, P202, P260, P261, P264, P270, P271, P272, P280, P281, P285, P301+P312, P302+P352, P304+P312, P304+P340, P304+P341, P308+P313, P312, P314, P321, P330, P332+P313, P333+P313, P342+P311, P362, P363, P405, P501
H302
Excerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]: Some may burn but none ignite readily. Containers may explode when heated. Some may be transported hot. For UN3508, be aware of possible short circuiting as this product is transported in a charged state. (ERG, 2016)
|Danger|H317: May cause an allergic skin reaction [Warning Sensitization, Skin]|P201, P202, P260, P261, P264, P270, P272, P273, P280, P281, P285, P302+P352, P304+P341, P308+P313, P314, P321, P333+P313, P342+P311, P363, P391, P405, and P501|H317 (97.73%): May cause an allergic skin reaction [Warning Sensitization, Skin]|Aggregated GHS information provided by 44 companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.|H302: Harmful if swallowed [Warning Acute toxicity, oral]|P201, P202, P260, P261, P264, P270, P271, P272, P280, P281, P285, P301+P312, P302+P352, P304+P312, P304+P340, P304+P341, P308+P313, P312, P314, P321, P330, P332+P313, P333+P313, P342+P311, P362, P363, P405, and P501
Excerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]: SMALL FIRE: Dry chemical, CO2, water spray or regular foam. LARGE FIRE: Water spray, fog or regular foam. Do not scatter spilled material with high-pressure water streams. Move containers from fire area if you can do it without risk. Dike fire-control water for later disposal. FIRE INVOLVING TANKS: Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks engulfed in fire. (ERG, 2016)
Excerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]: As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. SPILL: Increase, in the downwind direction, as necessary, the isolation distance shown above. FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2016)
Excerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]: Do not touch or walk through spilled material. Stop leak if you can do it without risk. Prevent dust cloud. Avoid inhalation of asbestos dust. SMALL DRY SPILL: With clean shovel, place material into clean, dry container and cover loosely; move containers from spill area. SMALL SPILL: Pick up with sand or other non-combustible absorbent material and place into containers for later disposal. LARGE SPILL: Dike far ahead of liquid spill for later disposal. Cover powder spill with plastic sheet or tarp to minimize spreading. Prevent entry into waterways, sewers, basements or confined areas. (ERG, 2016)
Safety glasses and face shield; rubber gloves; rubber apron (USCG, 1999)
Drug Information
Ingestion causes irritation of mouth and stomach. Liquid irritates eyes and skin and may cause dermatitis. (USCG, 1999)
INGESTION: give large amount of water; induce vomiting; get medical attention. EYES: flush with water for at least 15 min. SKIN: flush with water. (USCG, 1999)
Nickel tetrafluoroborate Use and Manufacturing
Used in the manufacture of organic synthesis catalysts, nickel electroplating, nickel flux, etc.
Borate(1-), tetrafluoro-, nickel(2+) (2:1): ACTIVE
Computed Properties
Molecular Weight:232.31
Hydrogen Bond Acceptor Count:10
Exact Mass:231.941177
Monoisotopic Mass:231.941177
Heavy Atom Count:11
Complexity:19.1
Covalently-Bonded Unit Count:3
Compound Is Canonicalized:Yes
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