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VANADIUM(IV) OXIDE

VANADIUM(IV) OXIDE structure

VANADIUM(IV) OXIDE 

structure
  • CAS No:

    12036-21-4

  • Formula:

    O2V

  • Chemical Name:

    VANADIUM(IV) OXIDE

  • Synonyms:

    Vanadium oxide (VO2);vanadiumoxide(vo2);VO2;VANADIUM TETRAOXIDE;VANADIUM OXIDE;VANADIUM(IV) OXIDE;VANADIUM DIOXIDE;Vanadium(Ⅳ)oxide

  • Categories:

    Inorganic Chemistry  >  Oxides and Peroxides

Description

CBI


Vanadium dioxide is a vanadium oxide.


Vanadium (IV) dioxide is a kind of inorganic compound with its chemical formula being VO2. It can undergo a phase transition at a normal temperature (~66 °C). Its electrical resistivity and opacity can also change several fold. These special properties make it have many applications. For example, it can be used in chemical sensors, energy-conserving coatings, transparent conductors and switching materials. It can also be used as a stationary optical shutter, optical modulators, cameras and data storage. Moreover, it can be applied to the missile guidance system due to its infrared modulation capability. It can also be used to make thin films which have been used in electro-optical switches, micro-optical switch, passive smart radiators and sunshields for spacecraft. It can also be used in phase change computing and memory.


Blue-black powder. Insoluble in water; soluble in alkalies and acids.


Vanadium(IV) Oxide (vanadium dioxide, VO2) is a blue-black solid, having a distorted rutile (TiO2) structure. It can be prepared from the reaction of V2O5 at the melting point with sulfur or carbonaceous reductants such as sugar or oxalic acid. The dioxide slowly oxidizes in air. Vanadium dioxide dissolves in acids to give the stable (VO)2+ ions and in hot alkalies to yield vanadate(IV) species, eg, (HV2O5).

VANADIUM(IV) OXIDE Basic Attributes

82.94

82.93380

234-841-1

TSCA listed

DTXSID5065194

black

28253090

Characteristics

34.1

-0.23760

black Powder

4.339 g/mL at 25 °C(lit.)

1967°C

Insoluble in water.

Non flammable

Store at room temperature, keep dry and cool

Safety Information

II

6.1

UN3285

3

Xi

26-37/39

Xi

P305 + P351 + P338

Toxic and irritating.

UN3285

|Warning|H315 (99.53%): Causes skin irritation [Warning Skin corrosion/irritation]|P264, P280, P302+P352, P305+P351+P338, P321, P332+P313, P337+P313, and P362|Aggregated GHS information provided by 214 companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Toxicity

NIOSH: Ceiling 0.05 mg/m3

Drug Information

vanadium dioxide

VANADIUM(IV) OXIDE Use and Manufacturing

Uses

Vanadium(IV) oxide is used in chemical sensors, energy-conserving coatings, transparent conductors and switching materials. It acts as a stationary optical shutter, optical modulators, cameras and data storage. As infrared modulators, it is used for the missile guidance systems. Thin films made up of vanadium dioxide find applications in electro-optical switches, micro-optical switch, passive smart radiators and sunshields for spacecraft.

Vanadium oxide (VO2): ACTIVE

Computed Properties

Molecular Weight:82.940
Hydrogen Bond Acceptor Count:2
Exact Mass:82.933787
Monoisotopic Mass:82.933787
Topological Polar Surface Area:34.1
Heavy Atom Count:3
Complexity:18.3
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes

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