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Home > Encyclopedia > Boc-L-beta-homoglutamic acid 6-benzyl ester

Boc-L-beta-homoglutamic acid 6-benzyl ester

Boc-L-beta-homoglutamic acid 6-benzyl ester structure

Boc-L-beta-homoglutamic acid 6-benzyl ester 

structure
  • CAS No:

    218943-30-7

  • Formula:

    C18H25NO6

  • Chemical Name:

    Boc-L-beta-homoglutamic acid 6-benzyl ester

  • Synonyms:

    BOC-BETA-HOGLU(OBZL)-OH;BOC-BETA-HOMOGLU(OBZL)-OH;BOC-L-BETA-HOMOGLUTAMIC ACID 6-BENZYL ESTER;BOC-L-BETA-HOMOGLUTAMIC ACID DELTA-BENZYL ESTER;BOC-L-BETA-HOMOGLUTAMIC ACID(OBZL);BOC-GLU(OBZL)-(C*CH2)OH;(S)-3-(BOC-AMINO)ADIPIC ACID 6-BENZYL ESTER;(S)-N-BETA-T-BUTOXYCARBONYL-3-AMINO-N-EPSILON-BENZYL ESTER-6-HYDROXY-6-OXOHEXANOIC ACID

  • Categories:

    Biochemical Engineering  >  Amino Acids and Derivatives

Description

White powder

Boc-L-beta-homoglutamic acid 6-benzyl ester Basic Attributes

351.39

351.168182

DTXSID70402794

29242990

Characteristics

102

2.2

1.2±0.1 g/cm3

530°C at 760 mmHg

274.4±28.7 °C

1.521

4.6E-12mmHg at 25°C

Safety Information

IRRITANT

NONH for all modes of transport

3

Boc-L-beta-homoglutamic acid 6-benzyl ester Use and Manufacturing

Methods of Manufacturing

3-tert-Butoxycarbonylamino-hexanedioic acid 6-benzyl ester (6) The diazoketone (5) (3.00 g, 8.30 mmol), was dissolved in a mixture 5:1 of THF/H2O (60 ml), and cooled in an ice bath in a flask covered with aluminium foil to protect from the light. Silver trifluoroacetate (0.37 g, 1.66 mmol) was then added, followed by a drop- wise addition of NMM (2.28 ml, 20.75 mmol). The reaction mixture was stirred for 4.5 hrs and warmed to room temperature. After completion was reached, THF was evaporated, IN KHSO

Uses

Biochemical reagents-unnatural amino acids

Computed Properties

Molecular Weight:351.4
XLogP3:2.2
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:11
Exact Mass:351.16818752
Monoisotopic Mass:351.16818752
Topological Polar Surface Area:102
Heavy Atom Count:25
Complexity:451
Defined Atom Stereocenter Count:1
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes

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