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(Trimethylsilyl)imidazole

(Trimethylsilyl)imidazole structure

CAS No:
18156-74-6
Formula:
C6H12N2Si
Chemical Name:
(Trimethylsilyl)imidazole
Synonyms:
1H-Imidazole,1-(trimethylsilyl)-;Imidazole,1-(trimethylsilyl)-;1-(Trimethylsilyl)-1H-imidazole;N-(Trimethylsilyl)imidazole;(Trimethylsilyl)imidazole;N-(Trimethylsilyl)imidazol;1-(Trimethylsilyl)imidazole;TSIM;1-Imidazolyltrimethylsilane;Trimethylimidazosilane;TMSI;NSC 139860;N-(Trimethylsilyl)-1H-imidazole;150059-66-8
Categories:
Chemical Reagents > Silane Reagent

Description

Colorless transparent liquidChEBI: A member of the class of imidazoles in which the hydrogen at position 1 is replaced by a trimethylsilyl group. N-trimethylsilylimidazole is a derivatisation agent used in gas chromatography/mass spectrometry applications.

N-trimethylsilylimidazole is a member of the class of imidazoles in which the hydrogen at position 1 is replaced by a trimethylsilyl group. N-trimethylsilylimidazole is a derivatisation agent used in gas chromatography/mass spectrometry applications. It has a role as a chromatographic reagent. It is a member of imidazoles and a N-silyl compound.

(Trimethylsilyl)imidazole Basic Attributes

Molecular Weight：

140.26

Exact Mass：

140.26

BRN：

606148

EC Number：

242-040-3

NSC Number：

139860

DSSTox ID：

DTXSID5066326

HScode：

29332990

Characteristics

PSA：

17.8

Appearance：

Clear colorless to yellow Liquid

Density：

0.956 g/cm³

Melting Point：

105-106 °C

Boiling Point：

99 °C @ Press: 14 Torr

Flash Point：

42 °F

Refractive Index：

n 20/D 1.475(lit.)

Water Solubility：

Decomposes in water

Storage Conditions：

2-8°C

Safety Information

Packing level：

Hazard category：

Transport codes：

UN 1993 3/PG 2

wgk germany：

hazard class code：

11-36/37/38-14-40-34-37-35-20/21/22

safety instructions：

16-26-33-37/39-45-36/37/39

RTECS Number：

NI8700000

Marks：

F,Xi,C

Precautionary statement(s)：

P210-P261-P305 + P351 + P338

Hazard Statements：

H225-H315-H319-H335

GHS Classification：

|Danger|H225 (59.04%): Highly Flammable liquid and vapor [Danger Flammable liquids]|P201, P202, P210, P233, P240, P241, P242, P243, P260, P261, P264, P270, P271, P273, P280, P281, P301+P312, P301+P330+P331, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P308+P313, P310, P312, P321, P330, P332+P313, P337+P313, P362, P363, P370+P378, P391, P403+P233, P403+P235, P405, and P501|Aggregated GHS information provided by 83 companies from 8 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Drug Information

MeSH Entry Terms：

1-(trimethylsilyl)-1H-imidazole

(Trimethylsilyl)imidazole Use and Manufacturing

Uses

Used as an antibiotic intermediate and a strong silanizing agent; high-efficiency silanizing reagent, especially suitable for the synthesis of alcohols and acyl imidazoles, protecting the hydroxyl group in the presence of amino groups. Antibiotic intermediates. It is an important intermediate for the synthesis of various acylimidazoles, and also an important intermediate for the synthesis of pyrveramide; under the condition of amine functionalization, a silylation reagent that protects the hydroxyl group; a powerful silylation reagent, especially for alcohols; acylimidazole Synthesis of morpholino

Manufacturing Info：

1H-Imidazole, 1-(trimethylsilyl)-: ACTIVE

Computed Properties

Molecular Weight:140.26
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:1
Exact Mass:140.076974926
Monoisotopic Mass:140.076974926
Topological Polar Surface Area:17.8
Heavy Atom Count:9
Complexity:97.7
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes

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Guide of (Trimethylsilyl)imidazole

Description
Basic Attributes
Characteristics
Safety Information
Drug Information
Use and Manufacturing
Computed Properties
Recommended Suppliers
Latest News
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(Trimethylsilyl)imidazole

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