2-Butyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
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2-Butyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
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CAS No:
69190-62-1
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Formula:
C10H21BO2
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Chemical Name:
2-Butyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
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Synonyms:
1,3,2-Dioxaborolane,2-butyl-4,4,5,5-tetramethyl-;2-Butyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
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CAS No:
2-Butyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane Basic Attributes
184.08
184.08
614-932-6
DTXSID20378596
2934999090
Safety Information
UN19933/PG3
3
36/37/38
26-36/37/39-24/25
Xi
P261, P264, P270, P271, P280, P301+P312, P302+P352, P304+P312, P304+P340, P305+P351+P338, P312, P321, P322, P330, P332+P313, P337+P313, P362, P363, P403+P233, P405, P501
H302
|Warning|H302 (100%): Harmful if swallowed [Warning Acute toxicity, oral]|P261, P264, P270, P271, P280, P301+P312, P302+P352, P304+P312, P304+P340, P305+P351+P338, P312, P321, P322, P330, P332+P313, P337+P313, P362, P363, P403+P233, P405, and P501|The GHS information provided by 1 company from 1 notification to the ECHA C&L Inventory.
2-Butyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane Use and Manufacturing
Under argon, equipped with a 100 mL reaction flask was added 500mL of tetrahydrofuran 17. lg (0 · 10 mol) PinB (DMA), the temperature of the system was reduced to 0 ~ 5 ° C, dropping 44.3ml 2 · 5Μ positive butyllithium (0 · 11 mol), stirred at 0 ~ 5 ° C for 30 minutes, warmed to room temperature, stirring was continued for 2 hours, 200mL 1Μ KH2P04 buffer was added dropwise and the reaction was quenched with 150mL ethyl acetate three times. The combined organic phase was dried over anhydrous sodium sulfate, concentrating the organic phase, 40g of n-hexane to play with the public, and filtered to give a white solid:. 12 9g, yield: 70percent, GC> 97percent. 4 NMR, nB NMR and IR spectra consistent with the standard.
Computed Properties
Molecular Weight:184.09
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:3
Exact Mass:184.1634601
Monoisotopic Mass:184.1634601
Topological Polar Surface Area:18.5
Heavy Atom Count:13
Complexity:162
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes
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2-Butyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
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