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(Dimethyl sulfide)trihydroboron

(Dimethyl sulfide)trihydroboron structure

CAS No:
13292-87-0
Formula:
C2H9BS
Chemical Name:
(Dimethyl sulfide)trihydroboron
Synonyms:
Boron,trihydro[thiobis[methane]]-,(T-4)-;Methyl sulfide,compd. with borane (1:1);Borane,compd. with thiobis[methane] (1:1);Methyl sulfide,compd. with BH3;Borine,compd. with Me2S;Borane,compd. with methyl sulfide (1:1);Methane,thiobis-,compd. with borane (1:1);Methane,thiobis-,boron complex;(T-4)-Trihydro[thiobis[methane]]boron;Dimethylsulfane compd. with borane (1:1);BMS;Borane-dimethyl sulfide (1:1);Borane-dimethyl sulfide complex (1:1);(Dimethyl sulfide)borane;(Dimethyl sulfide)trihydroboron;Trihydrido(dimethyl sulfide)boron;Trihydro(dimethyl sulfide)boron;Borane-dimethylsulfide complex;Dimethylsulfide trihydroborane;12070-92-7;153096-90-3;163858-17-1;168641-59-6;172146-69-9;664339-46-2;856617-77-1;1037067-65-4;1262951-71-2;1315334-90-7;1628073-40-4
Categories:
Chemical Reagents > Organic Reagents

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Description

clear colorless to light yellow solution

(Dimethyl sulfide)trihydroboron Basic Attributes

Molecular Weight：

75.97

Exact Mass：

76.051804

BRN：

3663489

EC Number：

236-313-6

DSSTox ID：

DTXSID3051672

HScode：

29309090

Characteristics

PSA：

25.3

XLogP3：

-0.47240

Appearance：

Colorless to pale yellow Solution

Density：

1.287 g/mL at 25 °C

Melting Point：

-40--37°C

Boiling Point：

~34 °C

Flash Point：

65 °F

Refractive Index：

1.457

Water Solubility：

Solubility in water: reaction.Miscible with ethyl ether, tetrahydrofurane, dichloromethane, benzene, xylene, hexane, diglyme, dimethyl ether, ethyl acetate, toluene, methylene chloride and other aprotic solvents.

Storage Conditions：

2-8°C

Safety Information

Packing level：

Hazard category：

4.3

Transport codes：

UN 3399 4.3/PG 1

wgk germany：

hazard class code：

12-14/15-19-20/22-37/38-41-67-65-63-48/20-38-11-22-14-40-36-21-36/37/38-37

safety instructions：

36/37-62-36/39-33-26-23-16-36-24/25-7/8-43-39-36/37/39

RTECS Number：

PV5080000

Marks：

F+,Xn,F,Xi

Precautionary statement(s)：

P210-P223-P231 + P232-P280-P370 + P378-P422

Hazard Statements：

H225-H260-H302-H318

GHS Classification：

|Danger|H225 (95.71%): Highly Flammable liquid and vapor [Danger Flammable liquids]|P201, P202, P210, P223, P231+P232, P233, P240, P241, P242, P243, P261, P264, P270, P271, P273, P280, P281, P301+P310, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P308+P313, P310, P312, P321, P322, P330, P332+P313, P335+P334, P361, P362, P363, P370+P378, P402+P404, P403+P233, P403+P235, P405, and P501|Aggregated GHS information provided by 164 companies from 16 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

(Dimethyl sulfide)trihydroboron Use and Manufacturing

Uses

It is used in the asymmetric reduction of indone and tetralone with L-pyrrolidone supported by dendrimer. The conversion of ferrocenyl-1,3-dione to chiral 1,3-diol is catalyzed by CBS asymmetric reduction. Highly asymmetric reduction of ketone catalyzed by C3-symmetric three-legged hydroxylamide. The reactant is used as a specifically selected reducing agent.The reactant participates in: Hydroboration/synthesis of cage compounds.

Manufacturing Info：

Boron, trihydro[thiobis[methane]]-, (T-4)-: ACTIVE

Computed Properties

Molecular Weight:72.95
Hydrogen Bond Acceptor Count:1
Exact Mass:73.0283265
Monoisotopic Mass:73.0283265
Topological Polar Surface Area:25.3
Heavy Atom Count:4
Complexity:2.8
Covalently-Bonded Unit Count:2
Compound Is Canonicalized:Yes

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Guide of (Dimethyl sulfide)trihydroboron

Description
Basic Attributes
Characteristics
Safety Information
Use and Manufacturing
Computed Properties
Recommended Suppliers
Latest News
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(Dimethyl sulfide)trihydroboron

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