6-Bromopyridine-2-boronic acid pinacol ester
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6-Bromopyridine-2-boronic acid pinacol ester
structure -
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CAS No:
651358-83-7
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Formula:
C11H15BBrNO2
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Chemical Name:
6-Bromopyridine-2-boronic acid pinacol ester
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Synonyms:
2-BROMO-6-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)PYRIDINE;6-BROMOPYRIDINE-2-BORONIC ACID PINACOL ESTER;6-Bromopyridine-2-boronic...;2-Bromopyridine-6-boronic acid pinacol ester;2-broMo-6-(tetraMethyl-1,3,2-dioxaborolan-2-yl)pyridine;6-Bromopyridine-2-boronic acid picol ester
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CAS No:
6-Bromopyridine-2-boronic acid pinacol ester Basic Attributes
283.96
283.037903
DTXSID10479304
2934999090
Safety Information
36/37/38-36-25
26-36/37/39-45
T
P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, P501
H315
|Warning|H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]|P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, and P501|Aggregated GHS information provided by 5 companies from 2 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
6-Bromopyridine-2-boronic acid pinacol ester Use and Manufacturing
Scheme 11 illustrates hydrogenation and de-halogenation of an sp2-carbon 2-borylated-6-bromopyridine (e.g., which can be formed as illustrated above from a corresponding non-borylated substrate) using hydrogen with a rhodium-based catalyst (Rh/C) in ethanol (rt for 16 h) to form the corresponding hydrogenated, de-halogenated, 2-substituted sp3-carbon borylated piperidine product.
Computed Properties
Molecular Weight:283.96
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:1
Exact Mass:283.03792
Monoisotopic Mass:283.03792
Topological Polar Surface Area:31.4
Heavy Atom Count:16
Complexity:257
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes
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6-Bromopyridine-2-boronic acid pinacol ester
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