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Home > Encyclopedia > Ammonium gluconate

Ammonium gluconate

Ammonium gluconate structure

Ammonium gluconate 

structure
  • CAS No:

    19222-41-4

  • Formula:

    C6H12O7.H3N

  • Chemical Name:

    Ammonium gluconate

  • Synonyms:

    D-Gluconic acid,ammonium salt (1:1);Gluconic acid,monoammonium salt,D-;D-Gluconic acid,monoammonium salt;Ammonium gluconate;Glucamonix;Novammon;Gluconic acid ammonium salt;2554-04-3;882173-33-3;880259-18-7;894764-85-3

Description

White powder. Soluble in water, insoluble in alcohol. Optical rotation +11.6 (in water).White solid with a weak odor of ammonia. Sinks and mixes with water.


Ammonium gluconate is a white solid with a weak odor of ammonia. Sinks and mixes with water. (USCG, 1999)|Liquid|Colourless to light yellow, clear syrupy liquid|Solid|WHITE CRYSTALLINE POWDER.


Ammonium gluconate is a white solid with a weak odor of ammonia. Sinks and mixes with water. (USCG, 1999)|D-gluconic acid is a gluconic acid having D-configuration. It has a role as a chelator and a Penicillium metabolite. It is a conjugate acid of a D-gluconate. It is an enantiomer of a L-gluconic acid.|Commonly found in salts with sodium and calcium. Gluconic acid or gluconate is used to maintain the cation-anion balance on electrolyte solutions.|Gluconic Acid is the carboxylic acid formed by the oxidation of the first carbon of glucose with antiseptic and chelating properties. Gluconic acid, found abundantly in plant, honey and wine, can be prepared by fungal fermentation process commercially. This agent and its derivatives can used in formulation of pharmaceuticals, cosmetics and food products as additive or buffer salts. Aqueous gluconic acid solution contains cyclic ester glucono delta lactone structure, which chelates metal ions and forms very stable complexes. In alkaline solution, this agent exhibits strong chelating activities towards anions, i.e. calcium, iron, aluminium, copper, and other heavy metals.

Ammonium gluconate Basic Attributes

213.19

213.084852 g/mol

242-892-6

R4R8J0Q44B

1738

DTXSID8027169|DTXSID8042000

C61777

NEEDLES FROM ETHANOL & ETHER|CRYSTALS

Characteristics

139 Ų

-1.87 (estimated)

Ammonium gluconate is a white solid with a weak odor of ammonia. Sinks and mixes with water. (USCG, 1999)

greater than 1 at 68 °F (USCG, 1999)

154 °C (decomp)

Water soluble .

MAY BE STORED IN STAINLESS STEEL DRUMS. /COMMERCIAL PRODUCT/

SPECIFIC OPTICAL ROTATION: +11.6 DEG IN WATER

MILD ACID TASTE

K= 2.5X10-4 @ 25 °C

141.89 Ų [M+H]+ [CCS Type: DT, Method: stepped-field]|149.77 Ų [M+Na]+ [CCS Type: DT, Method: stepped-field]|135.16 Ų [M-H]- [CCS Type: DT, Method: stepped-field]|148 Ų [M+Na]+ [CCS Type: TW, Method: calibrated with polyalanine]|146.2 Ų [M+Na]+ [CCS Type: DT, Method: single field calibrated with ESI Low Concentration Tuning Mix (Agilent)]|146.3 Ų [M+Na]+ [CCS Type: DT, Method: single field calibrated with ESI Low Concentration Tuning Mix (Agilent)]|132.4 Ų [M-H]- [CCS Type: DT, Method: single field calibrated with ESI Low Concentration Tuning Mix (Agilent)]|132.6 Ų [M-H]- [CCS Type: DT, Method: single field calibrated with ESI Low Concentration Tuning Mix (Agilent)]|133.2 Ų [M-H]-

FAINT ODOR OF VINEGAR /COMMERCIAL PRODUCT/|IN WATER IT PARTIALLY CONVERTS INTO EQUILIBRIUM MIXT WITH GAMMA AND DELTA GLUCONOLACTONES|LIGHT AMBER COLOR /COMMERCIAL PRODUCT/|DECOMP IN HOT WATER

Water soluble.

Alcohols and Polyols

Salts, basic, such as AMMONIUM GLUCONATE, are generally soluble in water. The resulting solutions contain moderate concentrations of hydroxide ions and have pH's greater than 7.0. They react as bases to neutralize acids. These neutralizations generate heat, but less or far less than is generated by neutralization of the bases in reactivity group 10 (Bases) and the neutralization of amines. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible.

Safety Information

TURNS YELLOW ON EXPOSURE TO LIGHT

SRP: At the time of review, criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.

Special Hazards of Combustion Products: Toxic oxides of nitrogen may form in fires. (USCG, 1999)|Combustible.

|Warning|H315 (85.35%): Causes skin irritation [Warning Skin corrosion/irritation]|P264, P280, P302+P352, P305+P351+P338, P321, P332+P313, P337+P313, and P362|Aggregated GHS information provided by 784 companies from 7 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Fire Extinguishing Agents: Water (USCG, 1999)|Use powder, alcohol-resistant foam, water spray, carbon dioxide.

Respirator for nuisance dust (USCG, 1999)

Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Sweep spilled substance into covered containers. If appropriate, moisten first to prevent dusting. Wash away remainder with plenty of water.

Separated from strong oxidants.

Evaporation at 20 °C is negligible; a nuisance-causing concentration of airborne particles can, however, be reached quickly when dispersed.

NO open flames.

Use local exhaust or breathing protection.

Drug Information

For use as part of electrolyte supplementation in total parenteral nutrition.

Used as part of electrolyte salts to maintain cation-anion balance in solutions.

(99)TCM-LABELED GLUCONATE WAS ACCUMULATED RELATIVELY EARLY IN THE KIDNEY, AND ESP IN THE URINARY TRACT.

Inhalation of dust irritates nose and throat. Contact with eyes causes mild irritation. (USCG, 1999)

INHALATION: remove to fresh air. EYES or SKIN: flush with water. (USCG, 1999)


Fresh air, rest.


Rinse skin with plenty of water or shower.


Rinse with plenty of water (remove contact lenses if easily possible).

boron gluconate

Redness.

Ammonium gluconate Use and Manufacturing

Methods of Manufacturing

MAY BE PREPARED FROM GLUCOSE BY ELECTROLYTIC OXIDN IN ALKALINE MEDIUM; BY CHEM OXIDN WITH HYPOBROMITES|BY HYDROLYSIS OF ALPHA-D-GLUCOSE WITH BROMINE PLUS H2SO4; BY GAMMA-IRRADIATION OF D-GLUCOSE;|AT PRESENT PRODUCED IN COMMERCIAL QUANTITIES BY FERMENTATIVE OXIDN OF ALDEHYDE GROUP IN GLUCOSE FROM CORN USING ASPERGILLUS NIGER, ASPERGILLUS FUMARICUS, ACETOBACTER ACETI, PENICILLIUM CHRYSOGENUM, & OTHER PENICILLIA.|CANNIZZARO REACTION ON GLUCOSE UNDER ALKALINE CONDITIONS FORMS SORBITOL AND GLUCONIC ACID|For more Methods of Manufacturing (Complete) data for GLUCONIC ACID (6 total), please visit the HSDB record page.

Uses

Emulsifying agent for cheese and salad dressings.


Corrosion inhibitors and anti-scaling agents


Agricultural products (non-pesticidal)

Production

1,000,000 - 10,000,000 lb

BECAUSE OF DIFFICULTIES OF PREPARING SOLID CRYSTAL PRODUCT, GLUCONIC ACID OF COMMERCE IS 50% AQ SOLN...|GRADES: TECHNICAL, 50% SOLN.

All other basic inorganic chemical manufacturing|D-Gluconic acid: ACTIVE|IT IS CHIEF ACID IN HONEY.

The enzyme gluconate kinase is useful to determine gluconic acid.

EPA Safer Chemical Functional Use Classes -> Chelating Agents;Processing Aids and Additives|Safer Chemical Classes -> Green circle - The chemical has been verified to be of low concern|Food additives|Food Additives -> ACID; ACIDITY_REGULATOR; RAISING_AGENT; SEQUESTRANT; -> JECFA Functional Classes|Cosmetics -> Buffering; Humectant; Solvent

Food Additives -> ACID; ACIDITY_REGULATOR; RAISING_AGENT; SEQUESTRANT;

Computed Properties

Molecular Weight:196.16
XLogP3:-3.4
Hydrogen Bond Donor Count:6
Hydrogen Bond Acceptor Count:7
Rotatable Bond Count:5
Exact Mass:196.05830272
Monoisotopic Mass:196.05830272
Topological Polar Surface Area:138
Heavy Atom Count:13
Complexity:170
Defined Atom Stereocenter Count:4
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes

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