3-[(Benzyloxycarbonyl)amino]propionaldehyde
-
![3-[(Benzyloxycarbonyl)amino]propionaldehyde structure](https://file.echemi.com/fileManage/upload/canonicalSmiles/20220812/a21ebd455d1849ef80b18550c2cfff35.png "3-[(Benzyloxycarbonyl)amino]propionaldehyde")
3-[(Benzyloxycarbonyl)amino]propionaldehyde
structure -
-
CAS No:
65564-05-8
-
Formula:
C11H13NO3
-
Chemical Name:
3-[(Benzyloxycarbonyl)amino]propionaldehyde
-
Synonyms:
3-[(Benzyloxycarbonyl)aMino]propionaldehyde 95%;3-[(Carbobenzyloxy)amino]propionaldehyde;Benzyl N-(3-oxopropyl)carbamate;(3-Oxo-propyl)-carbamic acid benzyl ester;3-[(BENZYLOXYCARBONYL)AMINO]PROPIONALDEHYDE;3-[(BENZYLOXYCARBONYL)AMINO]-1-PROPANAL;N-Phenylmethoxycarbonyl-3-aminopropanol;N-Phenylmethoxycarbonyl-3-Aminopropanal
- Categories:
-
CAS No:
3-[(Benzyloxycarbonyl)amino]propionaldehyde Basic Attributes
207.23
207.089539
DTXSID90439249
29223900
Characteristics
55.4
0.9
White to yellow Crystalline Powder
1.1±0.1 g/cm3
52-57 °C(lit.)
370.057ºC at 760 mmHg
177.6±25.9 °C
1.521
2-8°C
3-[(Benzyloxycarbonyl)amino]propionaldehyde Use and Manufacturing
PCC (8.75g, 40.6mmol, 1.7 equiv.) and CeliteTo a solution of benzyl (3-hydroxypropyl)carbamate (1.0 g, 4.8 mmol) in DMSO (5 mL) was added Et3N (2.4 g, 24.0 mmol) and sulfur trioxide-pyridine complex (2.3 g, 14.4 mmol) at 0°C and the mixture was stirred at the same temperature for 1 h. The mixture wasthen diluted with DCM (20 mL), which was washed with 10percent Cu504 solution, saturated citric acid solution and brine (30 mL each). The organic layer was dried over Na2504, concentrated and the residue was purified by silica-gel column to give benzyl (3-oxopropyl)carbamate (200 mg, 20.2percent yield) as a white solid.General procedure: N-Cbz-3-aminopropanol (-OH), N-Cbz-3-aminopropanal (-CHO), and N-Cbz-3-aminopropanoic acid (-COOH) were incu-bated at maximum concentration (38, 17, and 11 mM, respectively)in 5 mL of 100 mM sodium acetate buffer (pH 5.0). The reaction wasallowed to take place under orbital agitation in a MultiThermTMdevice overnight for 19 h. Peroxide was continuously added to thereactor at 3 mM h−1General procedure: N-Cbz-3-aminopropanol (-OH), N-Cbz-3-aminopropanal (-CHO), and N-Cbz-3-aminopropanoic acid (-COOH) were incu-bated at maximum concentration (38, 17, and 11 mM, respectively)in 5 mL of 100 mM sodium acetate buffer (pH 5.0). The reaction wasallowed to take place under orbital agitation in a MultiThermTMdevice overnight for 19 h. Peroxide was continuously added to thereactor at 3 mM h−1
Computed Properties
Molecular Weight:207.23
XLogP3:0.9
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:6
Exact Mass:207.08954328
Monoisotopic Mass:207.08954328
Topological Polar Surface Area:55.4
Heavy Atom Count:15
Complexity:200
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes
Recommended Suppliers of 3-[(Benzyloxycarbonyl)amino]propionaldehyde
-
![China]()
CN
5 YRS
Business licensedTrader Supplier of PVC resin,pvc paste resin,melamineInquiryCAS No.: 65564-05-8Grade: Industrial GradeContent: 99% -
![China]()
CN
2 YRS
Business licensed Certified factoryManufactory Supplier of 4-(Pentafluorothio)aniline,Pentafluoro,Pentafluorothio,Pentafluorosulfur,[4-(bromomethyl)phenyl]-pentafluoro-lambda6-sulfane,[4-(pentafluoro-sulfanyl)phenyl]acetic acidInquiryCAS No.: 65564-05-8Grade: Industrial GradeContent: 95%
Learn More Other Chemicals
-
1-Boc-4-methoxypiperidine
188622-27-7
-
1,4,5,6-Tetrahydro-1,2-dimethylpyrimidine
4271-96-9
-
CITRIC-2,2,4,4-D4 ACID
147664-83-3
-
Quaternary ammonium compounds, bis(hydrogenated tallow alkyl)dimethyl, salts with bentonite Formula
68953-58-2
-
1-[(2,4-Dichlorophenyl)methyl]-1H-indazole-3-carboxylic acid hydrazide Formula
252025-52-8
-
Agaritine Formula
2757-90-6
-
4-Pyridinecarboxylic acid 2-[(2-carboxy-3,4-dimethoxyphenyl)methylene]hydrazide Structure
2779-55-7
-
3,4,5-Trimethoxybenzohydrazide Structure
3291-03-0
-
What is (1,1-Dimethylethyl)hydrazine
32064-67-8
-
What is Tosyl chloride
98-59-9
3-[(Benzyloxycarbonyl)amino]propionaldehyde
SDSRequest for Quotation