(+)-3-Bromocamphor
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(+)-3-Bromocamphor
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CAS No:
10293-06-8
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Formula:
C10H15BrO
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Chemical Name:
(+)-3-Bromocamphor
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Synonyms:
Bicyclo[2.2.1]heptan-2-one,3-bromo-1,7,7-trimethyl-,(1R,3S,4S)-;2-Bornanone,3-bromo-,(1R,3S,4S)-(+)-;Bicyclo[2.2.1]heptan-2-one,3-bromo-1,7,7-trimethyl-,(1R-endo)-;Camphor,3α-bromo-,(+)-;(1R,3S,4S)-3-Bromo-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one;endo-(+)-3-Bromo-2-bornanone;(+)-3-Bromocamphor;(+)-endo-3-Bromocamphor;(1R-endo)-(+)-3-Bromocamphor;(1R)-endo-3-Bromocamphor;(1R-endo)-3-Bromo-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one
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CAS No:
Characteristics
17.07000
2.42
White Crystalline
1.4±0.1 g/cm3
76 °C
274 °C
35.8±9.9 °C
1.529
2-8°C
0.028mmHg at 25°C
130 º (c=5, CH3OH)
Safety Information
NONH for all modes of transport
3
36/37/38
26-36-37/39
ED6750000
Xi
Stable under normal temperatures and pressures.
P261-P305 + P351 + P338
H315-H319-H335
(+)-3-Bromocamphor Use and Manufacturing
Put camphor and a small amount of chloroform into the reaction pot, slowly add bromine below 90°C. After the addition, the temperature is increased to 115°C and kept at 115-130°C for nearly 3h. cool down. Crush to obtain α-bromocamphor.
Used as organic synthesis intermediate, pharmaceutical intermediate, and chiral structural unit
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