Ethanol, 1,2-dichloro-, 1-acetate

157

157.00

233-398-1

1993

Water-white liquid

2915390090

26.3

1.5

Ethanol, 1,2-dichloro-, acetate is a water-white liquid. Density 1.23 g / cm3. Flash point 307°F. Low toxicity. Miscible with alcohol and ethyl ether. Insoluble in water. Used in organic synthesis.

1.3000 g/cm³ @ Temp: 20 °C

Freezing point: less than -32 deg C

32 °C @ Press: 10 Torr

307° F (EPA, 1998)

1.4446 (20ºC)

Miscible with alcohol and ethyl ether, immiscible with water

Keep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition sources and untrained individuals. Secure and label area. Protect containers/cylinders from physical damage.

1.07mmHg at 25°C

Inhalation-Rat LCL0: 16 PPM/4 hours

Open flame is flammable; high heat decomposes toxic chloride fumes

Boiling range: 58-65 °C at 13 mm Hg

Insoluble in water.

Esters, Sulfate Esters, Phosphate Esters, Thiophosphate Esters, and Borate Esters

ETHANOL, 1,2-DICHLORO-, ACETATE is a halogenated ester. React with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by interaction with caustic solutions. Flammable hydrogen is generated by mixing with alkali metals and hydrides.

1993

Treasury is ventilated at low temperature and dry; stored separately from oxidants and food additives

SRP: At the time of review, criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.

USEPA; Chemical Profile: Ethanol, 1,2-dichloro-, acetate (1985)

May be ignited by heat, sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode in heat of fire. Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. When heated to decomposition, it may emit highly toxic fumes of phosgene. Esters may explode on mixing with nitrates. (EPA, 1998)

Move container from fire area if you can do it without risk. Cool containers that are exposed to flames with water from the side until well after fire is out. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. Wear self-contained (positive pressure if available) breathing apparatus and full protective clothing. Isolate one-half mile in all directions if tank car or truck is involved in fire. To extinguish small fires: dry chemical, carbon dioxide, water spray or foam. Large fires: water spray, fog or foam. (EPA, 1998)

Excerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible)]: As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in all directions. LARGE SPILL: Consider initial downwind evacuation for at least 300 meters (1000 feet). FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2016)

Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas. Shut off ignition sources; no flares, smoking or flames in hazard area. Stop leak if you can do it without risk. Use water spray to reduce vapors. Small spills: take up with sand or other non-combustible absorbent material and place into containers for later disposal. Large spills: dike far ahead of spill for later disposal. (EPA, 1998)

For emergency situations, wear a positive pressure, pressure-demand, full facepiece self-contained breathing apparatus (SCBA) or pressure- demand supplied air respirator with escape SCBA and a fully-encapsulating, chemical resistant suit. (EPA, 1998)

... combustible ...

Releases of CERCLA hazardous substances are subject to the release reporting requirement of CERCLA section 103, codified at 40 CFR part 302, in addition to the requirements of 40 CFR part 355. Ethanol, 1,2-dichloro-, acetate is an extremely hazardous substance (EHS) subject to reporting requirements when stored in amounts in excess of its threshold planning quantity (TPQ) of 1,000 lbs.

highly toxic

This material is toxic by inhalation. (EPA, 1998)

Inhalation is a route of entry.Move victim to fresh air; call emergency medical care. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. In case of contact with material, immediately flush eyes with running water for at least 15 minutes. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site. (EPA, 1998)