Iron(III) acetylacetonate
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Iron(III) acetylacetonate
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CAS No:
14024-18-1
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Formula:
C15H21FeO6
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Chemical Name:
Iron(III) acetylacetonate
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Synonyms:
Iron,tris(2,4-pentanedionato-κO2,κO4)-,(OC-6-11)-;Iron,tris(2,4-pentanedionato)-;Iron,tris(2,4-pentanedionato-O,O′)-,(OC-6-11)-;Iron,tris(2,4-pentanedionato-κO,κO′)-,(OC-6-11)-;(OC-6-11)-Tris(2,4-pentanedionato-κO2,κO4)iron;Ferric acetylacetonate;Iron(III) acetylacetonate;Ferric tris(acetylacetonate);Iron tris(acetylacetonate);Tris(acetylacetonato)iron;Iron acetylacetonate;Iron triacetylacetonate;Tris(2,4-pentanedionato)iron;Iron tris(acetoacetonate);Tris(acetylacetone)iron;(Acetylacetonato)iron(III);Iron(3+) acetylacetonate;Ferric tris(acetoacetonate);Iron tris(2,4-pentanedionate);Acetope Fe(II);Nacem Iron;NSC 43622;Iron(III) tris(2,4-pentanedionate);Nacem Ferric Iron;Nacem Ferric;Nasem Ferric Iron;38335-93-2;75042-68-1;2226524-30-5
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CAS No:
Characteristics
102.42000
1.66100
dark red powder
1.360 g/cm3
176-179 °C (decomp)
100ºC(9.7513 torr)
43.1ºC
H2O: 2 g/L (20 ºC)
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
0.174mmHg at 25°C
Safety Information
NONH for all modes of transport
3
R22; R36
S26-S37/39
NO8960000
Xn
Stable. Incompatible with strong bases, strong oxidizing agents.
P305 + P351 + P338
H302-H319
|Danger|H302+H312+H332 (13.54%): Harmful if swallowed, in contact with skin or if inhaled [Warning Acute toxicity, oral; acute toxicity, dermal; acute toxicity, inhalation]|P261, P264, P270, P271, P280, P301+P312, P302+P352, P304+P312, P304+P340, P305+P351+P338, P310, P312, P321, P322, P330, P332+P313, P337+P313, P362, P363, and P501|Aggregated GHS information provided by 207 companies from 11 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Iron(III) acetylacetonate Use and Manufacturing
General procedure: A metal solution of 0.15 mmol Fe(NO3)3 9H2O, was buffered with 0.45 mmol CH3COONa*3H2O (dissolved in 10 ml water). Ethanol was added to this solution, to produce an 1:1 volume ratio water:ethanol solution. 0.53 mmol of the relevant β-diketone was added [if the β-diketone was a liquid (Htfaa and Hhfaa), it was added as is, while the solid β-diketone (Hacac and Hdbm) was dissolved in 10 ml dichloromethane (DCM), before addition]. The resulting solution was stirred for 30 min, and left to stand overnight (in a fume hood), allowing slow evaporation of the solvent. The precipitate was collected by filtration and washing with water.
Tris(acetylacetonato) iron(III), often abbreviated Fe(acac)3, is a ferric coordination complex featuring acetylacetonate (acac) ligands, making it one of a family of metal acetylacetonates. It is a red air-stable solid that dissolves in nonpolar organic solvents.
Iron, tris(2,4-pentanedionato-.kappa.O2,.kappa.O4)-, (OC-6-11)-: ACTIVE
Computed Properties
Molecular Weight:353.17
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:3
Exact Mass:353.068749
Monoisotopic Mass:353.068749
Topological Polar Surface Area:120
Heavy Atom Count:22
Complexity:90.4
Undefined Bond Stereocenter Count:3
Covalently-Bonded Unit Count:4
Compound Is Canonicalized:Yes
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