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DIKEGULAC DIHYDRAT

DIKEGULAC DIHYDRAT structure

DIKEGULAC DIHYDRAT 

structure
  • CAS No:

    18467-77-1

  • Formula:

    C12H18O7

  • Chemical Name:

    DIKEGULAC DIHYDRAT

  • Synonyms:

    DIKEGULAC DIHYDRAT;DIKEGULAC DIHYDRATE;2,3:4,6-bis-o-(1-methylethylidene)-alpha-l-xylo-2-hexulofuranosonicaci;L-Diacetoneketogulonic acid monohydrate (DAKS);DIKEGULAC MONOHYDRATE PESTANAL 250 MG;2,3:4,6-di-o-isopropyliden-2-oxo-l-gulonic acid;dikegulac hydrate;DIACETONE-2-KETOGULONICACID

Description

Dikegulac is a member of dioxanes.


Dissolve -DAG in Et2O, filter, dry (MgSO4) it, filter it again and evaporate to give a yellow oil. Addition of one drop of H2O induces crystallisation to the monohydrate, which also forms rhombic crystals on recrystallisation from 95% EtOH/H2O at room temperature. [Flatt et al. Synthesis 815 1979, Reichstein & Grussner Helv Chim Acta 17 311 1934, Takagi & Jeffrey Acta Crystallogr Sect B 34 2932 1978, cf Org Synth 55 80 1976, Beilstein 19/12 V 520.]

DIKEGULAC DIHYDRAT Basic Attributes

274.27

274.27

242-348-8

3981541LXD

TSCA listed

DTXSID0047454

29329990

Characteristics

101.91000

0.34050

1.281

88-90 °C(lit.)

375℃

140ºC

1.482

2-8ºC

1.16E-06mmHg at 25°C

1.77±0.60(Predicted)

5.2×1010mol/(m3Pa) at 25℃, HSDB (2015)

2-8°C

Safety Information

3

22-24/25

DIKEGULAC DIHYDRAT Use and Manufacturing

.alpha.-L-xylo-2-Hexulofuranosonic acid, 2,3:4,6-bis-O-(1-methylethylidene)-: ACTIVE

Agrochemicals -> Plant Growth Regulators

Computed Properties

Molecular Weight:274.27
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:7
Rotatable Bond Count:1
Exact Mass:274.10525291
Monoisotopic Mass:274.10525291
Topological Polar Surface Area:83.4
Heavy Atom Count:19
Complexity:418
Defined Atom Stereocenter Count:4
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes

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