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Home > Encyclopedia > Bis(O,O-diisodecyl phosphorodithioato-κS,κS′)zinc

Bis(O,O-diisodecyl phosphorodithioato-κS,κS′)zinc

Bis(O,O-diisodecyl phosphorodithioato-κS,κS′)zinc structure

Bis(O,O-diisodecyl phosphorodithioato-κS,κS′)zinc 

structure
  • CAS No:

    25103-54-2

  • Formula:

    C40H84O4P2S4Zn

  • Chemical Name:

    Bis(O,O-diisodecyl phosphorodithioato-κS,κS′)zinc

  • Synonyms:

    Zinc,bis(O,O-diisodecyl phosphorodithioato-κS,κS′)-;Phosphorodithioic acid,O,O-diisodecyl ester,zinc salt;Zinc,bis(O,O-diisodecyl phosphorodithioato-S,S′)-;Isodecyl alcohol,O,O-diester with phosphorodithioic acid zinc salt;Phosphorodithioic acid,O,O-diisodecyl ester,zinc complex;Bis(O,O-diisodecyl phosphorodithioato-κS,κS′)zinc;Isodecanol,hydrogen phosphorodithioate,zinc salt;65045-91-2

Bis(O,O-diisodecyl phosphorodithioato-κS,κS′)zinc Basic Attributes

884.7 g/mol

882.401912 g/mol

246-618-6

228LEB82RN

DTXSID6027842

Straw Yellow

Characteristics

103 Ų

1.06 g/cm3 @ Temp: 15 °C

280 °F, open cup, 120 min.

Negligible solubility in water.|Soluble in oil and grease.

Sweet Odor

Phosphorus, % Wt 6.7; sulfur, % wt 13.8; zinc, % wt 7.2.

Safety Information

Can be heated to 110 °F (43 °C) for unloading and transfer, but store for extended periods at 100 °F (30 °C) or below.

Burn under controlled methods or bury in an approved site.

Chemically incompatible with bromine, chlorine, chromic acid and hydrogen peroxide.

ITC/USEPA; Information Review #353 (Draft) Zinc O,O-Diisoalkyl Dithiophosphates (1983)

|Warning|H400 (100%): Very toxic to aquatic life [Warning Hazardous to the aquatic environment, acute hazard]|P273, P391, and P501|Aggregated GHS information provided by 2 companies from 1 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Wear protective goggles and clothing.

Extinguishing media: carbon dioxide, dry chemical or foam. Evacuate areas down wind from fire. Use self-contained breathing apparatus.

Remove potential source of ignition, soak up with absorbent or treat as oil spill.

Severe skin and eye irritant./Zinc O,O-Diisoalkyl Dithiophosphates/|ZDPP mixtures are primary skin irritants. /Zinc O,O-Diisoalkyl Dithiophosphates/

Permissible Exposure Limit: Table Z-1 8-hr Time Weighted Avg: 5 mg/cu m. /Mineral oil mist/

Toxicity

LD50 Rat oral 2.31 mg/kg

Zinc O,O-diisoalkyl dithiophosphates enter the environment through improper disposal of motor oils, greases and hydraulic fluids. They could also enter the environment from engine leaks, hydraulic pumps, gear boxes and torque converters if present in the fluids associated with these uses. /Zinc O,O-Diisoalkyl Dithiophosphates/

Aquatic: Once the compounds enter the aquatic environment, whether sorbed or dissolved at low concn, the zinc dialkyl dithiophosphates will probably dissociate./Zinc O,O-Diisoalkyl Dithiophosphates/

ZDDPs do not exist in used motor oils since they are broken down by engine action. ZDDPs were not detected in motor oils used for more than 3,000 miles./Zinc O,O-Diisoalkyl Dithiophosphates/

Cmpds may bioconcentrate unless metabolism is rapid. /Zinc O,O-Diisoalkyl Dithiophosphates/

These cmpds are expected to partition to the organic phase. They will probably sorb to humic matter and clay in the environ. The zinc is subject to exchange with other metals in natural water./Zinc O,O-Diisoalkyl Dithiophosphates/

Dermal exposure is likely to individuals handling lubricating oils and hydraulic fluids. /Zinc O,O-Diisoalkyl Dithiophosphates/|Consumers performing automobile oil changes may be exposed through use of lubricating oil. Automobile and other machinery mechanics will also be exposed./Zinc O,O-Diisoalkyl Dithiophosphates/

Drug Information

Wash skin or eyes with copious amt of water-see a physician.

Bis(O,O-diisodecyl phosphorodithioato-κS,κS′)zinc Use and Manufacturing

Methods of Manufacturing

Produced from long chain alcohols, can be blended with mechanical equipment at temperatures below 125 °F (50 °C)|ZDDPs are prepared by reacting an alcoholic mixture (C3-8) with P2S5 followed by treating the resulting dialkyl dithiphosphoric with excess ZnO. /Zinc O,O-Diisoalkyl Dithiophosphates/|REACTION OF ISODECYL ALCOHOL WITH PHOSPHORUS PENTASULFIDE & ZINC OXIDE

Uses

Industrial gear oils and greases|Antiwear, antioxidant, and corrosion inhibitor additives in lubricating oils, greases, and hydraulic fluids. /dialkyl ZDDPs/|EXTREME PRESSURE LUBRICANT ADDITIVE

Production

(1981) 28,487,000 lb /dialkyldithiophosphates/|(1977) AT LEAST 4.54X10+8 GRAMS|(1982) PROBABLY GREATER THAN 2.27X10+6 GRAMS

Zinc, bis(O,O-diisodecyl phosphorodithioato-.kappa.S,.kappa.S')-: ACTIVE|Recommended for use at 0.5-1.5% volume to inhibit oxidation and as an anti-wear agent for industrial hydraulic oils, engine oils and tractor fluids.|Manufacturing is carried out with a batch process in a closed system. The plant is equipped with fume covers over all reaction vessels, storage tanks and filters. /Zinc O,O-Diisoalkyl Dithiophosphates/

Negative ion mass spectra were obtained from dialkyl dithiophosphates. Sensitivity of the method was such that detection of 1 ug of cmpd could be accomplished by selected ion monitoring, and 50-100 ug of cmpd was sufficient for scanning mass spectra. /Dialkyl Dithiophosphates/

Computed Properties

Molecular Weight:884.7
Hydrogen Bond Acceptor Count:8
Rotatable Bond Count:36
Exact Mass:882.401912
Monoisotopic Mass:882.401912
Topological Polar Surface Area:103
Heavy Atom Count:51
Complexity:299
Covalently-Bonded Unit Count:3
Compound Is Canonicalized:Yes

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