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Home > Encyclopedia > 2,2'-[methylenebis(phenyleneoxymethylene)]bisoxirane

2,2'-[methylenebis(phenyleneoxymethylene)]bisoxirane

2,2'-[methylenebis(phenyleneoxymethylene)]bisoxirane structure

2,2'-[methylenebis(phenyleneoxymethylene)]bisoxirane 

structure
  • CAS No:

    39817-09-9

  • Formula:

    C19H20O4

  • Chemical Name:

    2,2'-[methylenebis(phenyleneoxymethylene)]bisoxirane

  • Synonyms:

    2,2'-[methylenebis(phenyleneoxymethylene)]bisoxirane;Oxirane, 2,2-methylenebis(phenyleneoxymethylene)bis-;BISPHENOLFOFDIGLYCIDYLETHER;methylene bis(phenyleneoxymethylene)bisoxirane;Bis[(2,3-epoxypropoxy)phenyl] methane

Description

Methylene bis(phenyleneoxymethylene)bisoxirane is a colorless liquid resin.|Liquid


Methylene bis(phenyleneoxymethylene)bisoxirane is a colorless liquid resin.


Colorless liquid resin.

2,2'-[methylenebis(phenyleneoxymethylene)]bisoxirane Basic Attributes

312.3597

312.13615911 g/mol

254-641-8

TSCA listed

Characteristics

43.5 Ų

No rapid reaction with air. No rapid reaction with water.

Ethers

2,2'-[methylenebis(phenyleneoxymethylene)]bisoxirane is incompatible with strong oxidizers.

2-8°C

Safety Information

WGK 3

Flash point data for 2,2'-[methylenebis(phenyleneoxymethylene)]bisoxirane are not available. 2,2'-[methylenebis(phenyleneoxymethylene)]bisoxirane is probably combustible.

|Warning|H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]|P261, P264, P272, P280, P302+P352, P305+P351+P338, P321, P332+P313, P333+P313, P337+P313, P362, P363, and P501|Aggregated GHS information provided by 26 companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.|P261, P264, P272, P273, P280, P302+P352, P305+P351+P338, P321, P332+P313, P333+P313, P337+P313, P362, P363, P391, and P501|Aggregated GHS information provided by 40 companies from 1 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.|H317: May cause an allergic skin reaction [Warning Sensitization, Skin]|P201, P202, P261, P272, P280, P281, P302+P352, P308+P313, P321, P333+P313, P363, P405, and P501

Fires involving this material can be controlled with a dry chemical, carbon dioxide or Halon extinguisher. (NTP, 1992)

STORAGE PRECAUTIONS: You should store this material in a refrigerator. (NTP, 1992)

RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)

Epoxy resins based on Bisphenol F, also called phenolic Novolac, contain bisphenol F diglycidyl ether, which has three sensitizing isomers. DGEBF has a greater resistance than DGEBA. Contact allergy to bisphenol-F-based epoxy resins is rarer than that due to bisphenol-A-based resins and is frequently acquired with flooring materials and putty.

Drug Information

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment. INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing. INGESTION: DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)

2,2'-[methylenebis(phenyleneoxymethylene)]bisoxirane Use and Manufacturing

Uses

Adhesives and sealant chemicals


Adhesives and sealants


This certified reference material (CRM) is produced and certified in accordance withISO/IEC 17025andISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.Download your certificate at: http://www.sigma aldrich.com

Production

25,000 - 100,000 lb

Transportation equipment manufacturing|Oxirane, 2,2'-[methylenebis(2,1-phenyleneoxymethylene)]bis-: ACTIVE|TP - indicates a substance that is the subject of a proposed TSCA section 4 test rule.

Computed Properties

Molecular Weight:312.4
XLogP3:3.2
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:8
Exact Mass:312.13615911
Monoisotopic Mass:312.13615911
Topological Polar Surface Area:43.5
Heavy Atom Count:23
Complexity:340
Undefined Atom Stereocenter Count:2
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes

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