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zirconium carbide

zirconium carbide structure

zirconium carbide 

structure
  • CAS No:

    12020-14-3

  • Formula:

    ErFeH2O

  • Chemical Name:

    zirconium carbide

  • Synonyms:

    Monozirconium monocarbide

Description

dark gray brittle solid; cub, a=0.46983 nm; it is not a fixed stoichiometric compound; hard, high melting carbide used in UC-fueled reactors; enthalpy of fusion 79.4kJ/mol; hardness 8+ Mohs; used as a hot pressed crucible to melt metals such as bismuth, cadmium, lead, tin and high melting point oxides such as ZrO2, and as a 99.5% pure sputtering target to produce wear-resistant and other films [KIR84] [HAW93] [CER91] [JAN71]


Zirconium carbide , nominally ZrC, is a dark gray brittle solid. It is made typically by a carbothermic reduction of zirconium oxide in a induction-heated vacuum furnace. Alternative production methods, especially for deposition on a substrate, consist of vapor-phase reaction of a volatile zirconium halide, usually ZrCl4, with a hydrocarbon in a hydrogen atmosphere at 900–1400 °C (1652–2552 °F).

zirconium carbide Basic Attributes

241.12

Gray

Characteristics

Dark gray brittle solid, soluble in HF solutions containing nitrate or peroxide ions. UC-nuclear power reactor, crucible container for handling molten metals such as Bi, Cd, Pb, Sn, Rb, and molten zirconia ZrO2. Corroded by liquid metals Mg, Al, Si, V, Nb, Ta, Cr, Mo, Mn, Fe, Co, Ni, and Zn. In air oxidizes rapidly above 500°C. Maximum operating temperature of 2350°C in helium.


Gray metallic solid; cubic structure; very hard, hardness > 8.0 Mohs; density 6.73 g/cm3; melts at 3,532°C; insoluble in water; slightly soluble in concentrated sulfuric acid; soluble in hydrofluoric acid and oxidizing acids, such as nitric and perchloric acids; attacked by oxidizers.

6.730

3532°C

5100℃ [STR93]

soluble HF solutions which contain NO3 or peroxide [KIR84]

zirconium carbide Use and Manufacturing

Zirconium carbide is a refractory material. It is used in making incandescent filaments, high temperature electrical conductors, and cutting tool components.

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