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Home > Encyclopedia > (3R,10S,13S)-3-((tert-butyldimethylsilyl)oxy)-10,13-dimethylhexadecahydro-17H-cyclopenta[a]phenanthren-17-one

(3R,10S,13S)-3-((tert-butyldimethylsilyl)oxy)-10,13-dimethylhexadecahydro-17H-cyclopenta[a]phenanthren-17-one

(3R,10S,13S)-3-((tert-butyldimethylsilyl)oxy)-10,13-dimethylhexadecahydro-17H-cyclopenta[a]phenanthren-17-one structure

(3R,10S,13S)-3-((tert-butyldimethylsilyl)oxy)-10,13-dimethylhexadecahydro-17H-cyclopenta[a]phenanthren-17-one 

structure
  • CAS No:

    57711-45-2

  • Formula:

    C25H44O2Si

  • Chemical Name:

    (3R,10S,13S)-3-((tert-butyldimethylsilyl)oxy)-10,13-dimethylhexadecahydro-17H-cyclopenta[a]phenanthren-17-one

  • Synonyms:

    3-O-(tert-butyldimethylsilyl)androsterone;Androsteron-tert-butyldimethylsilylether;Androsterone-dimethyl-tert.-butylsilyl-ether;(3R,5S,8R,9S,10S,13S,14S)-3-(tert-Butyl-dimethyl-silanyloxy)-10,13-dimethyl-hexadecahydro-cyclopenta[a]phenanthren-17-one;(3α,5α)-3-{[tert-butyl(dimethyl)silyl]oxy}androstan-17-one;3α-t-Butyl-dimethylsilyloxy-5α-androstan-17-on;3α-(t-butyldimethylsiloxy)-5α-androstan-17-one;

(3R,10S,13S)-3-((tert-butyldimethylsilyl)oxy)-10,13-dimethylhexadecahydro-17H-cyclopenta[a]phenanthren-17-one Basic Attributes

404.7

404.311

Characteristics

26.3

6.9886

164 - 166 °C (water)

Analysis Methods

Name Column Shape Active Phase(℃) Retention index Temperature Control Method Comments Reference
Kovats' RI, non-polar column, isothermal Packed OV-1 2702. 230. isothermal Gas Chrom Q; Column length: 1. m Quilliam, M.A.Westmore, J.B.Sterically crowded trialkylsilyl derivatives for chromatography and mass spectrometry of biologically-important compoundsAnal. Chem.1978, 50, 1, 59-68.
Kovats' RI, non-polar column, isothermal Packed OV-1 2740. 260. isothermal Gas Chrom Q; Column length: 1. m Quilliam, M.A.Westmore, J.B.Sterically crowded trialkylsilyl derivatives for chromatography and mass spectrometry of biologically-important compoundsAnal. Chem.1978, 50, 1, 59-68.
Kovats' RI, non-polar column, isothermal Capillary VF-5MS 2788.8 custom temperature program 30. m/0.25 mm/0.25 μm, He; Program: Multi-step temperature program; T(initial)=60C; T(final)=270C Tret'yakov, K.V.Retention Data. NIST Mass Spectrometry Data Center.NIST Mass Spectrometry Data Center, 2007.
Guide of (3R,10S,13S)-3-((tert-butyldimethylsilyl)oxy)-10,13-dimethylhexadecahydro-17H-cyclopenta[a]phenanthren-17-one

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