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Home > Encyclopedia > Dicopper chloride trihydroxide

Dicopper chloride trihydroxide

Dicopper chloride trihydroxide structure

Dicopper chloride trihydroxide 

structure
  • CAS No:

    1306-85-0

  • Formula:

    ClCu2H3O3

  • Chemical Name:

    Dicopper chloride trihydroxide

  • Synonyms:

    Dicopper chloride trihydroxide;UNII-76712031PG;76712031PG;Copper(II) oxychloride;Aviocaffaro;Cuprocaffaro;Cuprovinol;Devicopper;Rhodiacuivre;Chempar

Dicopper chloride trihydroxide Basic Attributes

211.836266

215-572-9

76712031PG

GREEN, ORTHORHOMBIC CRYSTALS|Green to bluish green powder

Characteristics

3.76-3.78

Practically insol in water; less than 0.00001 mg/l (pH 7 at 20 °C); insoluble in organic solvents, soluble in dilute acids, forming copper(II) salts, soluble in ammonium hydroxide, forming complex ion.|Soluble in acids, ammonia; insoluble in water

CORROSIVE TO METAL CONTAINERS.

Decomposes on heating above 220 °C, with the formation of copper oxides, and loss of hydrogen chloride

STRONGLY CORROSIVE TO IRON & GALVANIZED IRON.|Corrosive to metal containers.

Safety Information

SRP: At the time of review, criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.

Solutions of sodium hypobromite are decomposed by powerful catalytic action of cupric ions, even as impurities. /Cupric salts/

|Danger|H301: Toxic if swallowed [Danger Acute toxicity, oral]|P261, P264, P270, P271, P273, P301+P310, P304+P312, P304+P340, P312, P321, P330, P391, P405, and P501|H301 (27.39%): Toxic if swallowed [Danger Acute toxicity, oral]|P260, P261, P264, P270, P271, P273, P280, P301+P310, P301+P312, P301+P330+P331, P303+P361+P353, P304+P312, P304+P340, P305+P351+P338, P310, P312, P321, P330, P363, P391, P405, and P501|Aggregated GHS information provided by 398 companies from 13 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Recommended Exposure Limit: 10 Hr Time-Weighted Avg: 1 mg/cu m. /Copper (dusts and mists)/

Toxicity

LD50 Rat oral 1440 mg/kg|LD50 Rat oral 700-800 mg/kg body weight /from table/

Drug Information

Basic treatment: Establish a patent airway. Suction if necessary. Watch for signs of respiratory insufficiency and assist ventilations if necessary. Administer oxygen by nonrebreather mask at 10 to 15 L/min. Monitor for shock and treat if necessary ... . For eye contamination, flush eyes immediately with water. Irrigate each eye continuously with normal saline during transport ... . Do not use emetics. For ingestion, rinse mouth and administer 5 ml/kg up to 200 ml of water for dilution if the patient can swallow, has a strong gag reflex, and does not drool. Administer activated charcoal ... . /Copper and related compounds/|Advanced treatment: Consider orotracheal or nasotracheal intubation for airway control in the patient who is unconscious. Start an IV with lactated Ringer's /SRP: "To keep open", minimal flow rate/. Watch for signs of fluid overload. For hypotension with signs of hypovolemia, administer fluid cautiously. Consider vasopressors if hypotensive with a normal fluid volume. Watch for signs of fluid overload ... . Use proparacaine, hydrochloride to assist eye irrigation ... . /Copper and related compounds/

Blitox

Dicopper chloride trihydroxide Use and Manufacturing

Methods of Manufacturing

Cuprous chloride + copper (air oxidation); copper oxide ores + sodium chloride, natural (ore roasting/water leaching)|Copper(II) oxychloride prepared commercially by air oxidation of copper(I) chloride solution; for this purpose, a concentrated sodium chloride solution containing about 50 g/l copper(II) is contacted with copper metal to produce a solution containing about 100 g/l copper(I). The copper(I) chloride-sodium chloride solution, with or without the copper metal, is then heated to 60-90 °C and aerated to effect oxidation. The mother liquor is separated from the precipitate and recycled into the process. Copper(II) oxychloride can also be prepared by reaction of copper(II) chloride solution with sodium hydroxide or by reaction of a copper(II) chloride solution with freshly precipitated, hydrated copper(II) oxide. Copper(II) oxychloride has also been produced as a byproduct in the electrolytic production of copper(I) chloride

Uses

For Copper chloride hydroxide (USEPA/OPP Pesticide Code: 023501) ACTIVE products with label matches. /SRP: Registered for use in the U.S. but approved pesticide uses may change periodically and so federal, state and local authorities must be consulted for currently approved uses./|Fungicide|Protective fungicide|PROCESS CHEM IN THE CUPRAMMONIUM PROCESS FOR RAYON PRODUCTION.|For more Uses (Complete) data for COPPER CHLORIDE HYDROXIDE (7 total), please visit the HSDB record page.

(1978) 4.09X10+8 G CONSUMPTION AS A FUNGICIDE

USEPA/OPP Pesticide Code 023501; Trade Names: Brava, component of.|Formulation types: WP; WG; PA; DP; SC.|Wettable powder, water dispersible granules|Oxy COC; Wettable powder; 50% basic copper chloride.

Introduced as fungicide in the early 1900's|The composition varies with the conditions of manufacture, but commercial preparations usually approach the formula 3Cu(OH)2.CuCl2.

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