1,3-Naphthalenedisulfonic acid, 8-[2-[4′-[2-(4-ethoxyphenyl)diazenyl]-3,3′-dimethyl[1,1′-biphenyl]-4-yl]diazenyl]-7-hydroxy-, sodium salt (1:2)
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1,3-Naphthalenedisulfonic acid, 8-[2-[4′-[2-(4-ethoxyphenyl)diazenyl]-3,3′-dimethyl[1,1′-biphenyl]-4-yl]diazenyl]-7-hydroxy-, sodium salt (1:2)
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CAS No:
6358-29-8
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Formula:
C32H28N4O8S2.2Na
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Chemical Name:
1,3-Naphthalenedisulfonic acid, 8-[2-[4′-[2-(4-ethoxyphenyl)diazenyl]-3,3′-dimethyl[1,1′-biphenyl]-4-yl]diazenyl]-7-hydroxy-, sodium salt (1:2)
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Synonyms:
1,3-Naphthalenedisulfonic acid,8-[2-[4′-[2-(4-ethoxyphenyl)diazenyl]-3,3′-dimethyl[1,1′-biphenyl]-4-yl]diazenyl]-7-hydroxy-,sodium salt (1:2);C.I. Direct Red 39,disodium salt;1,3-Naphthalenedisulfonic acid,8-[[4′-[(4-ethoxyphenyl)azo]-3,3′-dimethyl[1,1′-biphenyl]-4-yl]azo]-7-hydroxy-,disodium salt;C.I. 23630;Airedale Scarlet 3BD;Amanil Fast Scarlet 3B;Atlantic Scarlet 3B;Benzanil Scarlet 3B;Benzanol Brilliant Scarlet 3B;Benzo Red 3B;Benzyl Scarlet 3BS;Calcomine Scarlet 3B;Chloramine Red 3B;Chrome Leather Scarlet 3BS;C.I. Direct Red 39;Diamine Scarlet 3BA-CF;Diaphtamine Fast Scarlet 3B;Diazol Scarlet 3B;Diphenyl Red 3BS;Diphenyl Scarlet 3BS;Direct Fast Scarlet 3B;Direct Scarlet 3BS;Erie Scarlet 3B;Fenamin Scarlet 3B;Kayaku Direct Scarlet 3B;Mitsui Direct Scarlet 3BX;Paper Scarlet 3BP;Paramine Fast Scarlet 3B;Phenamine Scarlet 3B;Pheno Fast Scarlet 4B;Pontamine Scarlet 3B;Shikiso Direct Scarlet 3B;Triazol Fast Scarlet 3B;Union Fast Scarlet 3B;Direct Red 39;Direct Fast Red 3B;NSC 57018
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CAS No:
Description
Direct red 39 is a dark red powder. (NTP, 1992)
Direct red 39 is a dark red powder. (NTP, 1992)
1,3-Naphthalenedisulfonic acid, 8-[2-[4′-[2-(4-ethoxyphenyl)diazenyl]-3,3′-dimethyl[1,1′-biphenyl]-4-yl]diazenyl]-7-hydroxy-, sodium salt (1:2) Basic Attributes
704.68000
704.09900
228-766-3
99D0BZC19R
DTXSID8025204
3204140000
Characteristics
210.06000
10.02850
Direct red 39 is a dark red powder. (NTP, 1992)
1.43g/cm3
545 °F (decomposes) (NTP, 1992)
1.674
less than 1 mg/mL at 64° F (NTP, 1992)
Azo dyes can be explosive when suspended in air at specific concentrations. Insoluble in water.
Azo, Diazo, Azido, Hydrazine, and Azide Compounds
Explosive
DIRECT RED 39 is an azo compound. Azo, diazo, azido compounds can detonate. This applies in particular to organic azides that have been sensitized by the addition of metal salts or strong acids. Toxic gases are formed by mixing materials of this class with acids, aldehydes, amides, carbamates, cyanides, inorganic fluorides, halogenated organics, isocyanates, ketones, metals, nitrides, peroxides, phenols, epoxides, acyl halides, and strong oxidizing or reducing agents. Flammable gases are formed by mixing materials in this group with alkali metals. Explosive combination can occur with strong oxidizing agents, metal salts, peroxides, and sulfides.
Safety Information
SRP: At the time of review, criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.
Flash point data for this chemical are not available. It is probably combustible. (NTP, 1992)
|Danger|H350 (100%): May cause cancer [Danger Carcinogenicity]|P201, P202, P281, P308+P313, P405, and P501|Aggregated GHS information provided by 38 companies from 1 notifications to the ECHA C&L Inventory.
Fires involving this material can be controlled with a dry chemical, carbon dioxide or Halon extinguisher. (NTP, 1992)
SMALL SPILLS AND LEAKAGE: If you spill this chemical, you should dampen the solid spill material with 5% acetic acid, then transfer the dampened material to a suitable container. Use absorbent paper dampened with 5% acetic acid to pick up any remaining material. Your contaminated clothing and the absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal. Wash all contaminated surfaces with 5% acetic acid followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned. STORAGE PRECAUTIONS: You should store this material under ambient temperatures. (NTP, 1992)
RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)
Drug Information
EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment. INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing. INGESTION: DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)
1,3-Naphthalenedisulfonic acid, 8-[2-[4′-[2-(4-ethoxyphenyl)diazenyl]-3,3′-dimethyl[1,1′-biphenyl]-4-yl]diazenyl]-7-hydroxy-, sodium salt (1:2) Use and Manufacturing
CONDENSATION OF TETRAZOTIZED O-TOLIDINE WITH 2-NAPHTHOL-6,8-DISULFONIC ACID, THEN PHENOL, FOLLOWED BY ETHYLATION OF THE (PHENOL)HYDROXY GROUP BY HEATING UNDER PRESSURE WITH ETHYL CHLORIDE
DYE FOR CELLULOSE, SILK, WOOL FIBERS, CONSUMER HOME DYES, LEATHER, PAPER, PRINTING ON CELLULOSE & NYLON
(1977) PROBABLY GREATER THAN 6.81X10+6 GRAMS|(1979) PROBABLY GREATER THAN 4.54X10+6 GRAMS|20 tons in 1975
ESSENTIALLY 100% AS A DYE
1,3-Naphthalenedisulfonic acid, 8-[2-[4'-[2-(4-ethoxyphenyl)diazenyl]-3,3'-dimethyl[1,1'-biphenyl]-4-yl]diazenyl]-7-hydroxy-, sodium salt (1:2): ACTIVE|Direct dye- A water-soluble dye taken up directly by fibers from an aqueous solution containing an electrolyte, presumably due to selective adsorption. Usually applied to cellulosic fibers. Dyeing assistants such as sodium chloride or sodium sulfate are used to obtain a high concentration of dye on the fibers. /Direct dye/
Computed Properties
Molecular Weight:704.7
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:12
Rotatable Bond Count:7
Exact Mass:704.09874471
Monoisotopic Mass:704.09874471
Topological Polar Surface Area:210
Heavy Atom Count:48
Complexity:1250
Covalently-Bonded Unit Count:3
Compound Is Canonicalized:Yes
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1,3-Naphthalenedisulfonic acid, 8-[2-[4′-[2-(4-ethoxyphenyl)diazenyl]-3,3′-dimethyl[1,1′-biphenyl]-4-yl]diazenyl]-7-hydroxy-, sodium salt (1:2)
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