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Potassium oxalate monohydrate

Potassium oxalate monohydrate structure

Potassium oxalate monohydrate 

structure
  • CAS No:

    6487-48-5

  • Formula:

    C2H2O4.H2O.2K

  • Chemical Name:

    Potassium oxalate monohydrate

  • Synonyms:

    Ethanedioic acid,potassium salt,hydrate (1:2:1);Oxalic acid,dipotassium salt,monohydrate;Ethanedioic acid,dipotassium salt,monohydrate;Potassium oxalate monohydrate;Dipotassium oxalate monohydrate;Potassium oxalate (K2(C2O4)) monohydrate

  • Categories:

    Organic Chemistry  >  Organometallic Compounds

Description

Potassium oxalate, K2C204, H20, is odorless, effiorescent, water-soluble, colorless crystals that decompose when heated.Usedin analytical chemistry and photography, and as a bleach and oxalic acid source, The monohydrate, K2C2O4·H20, mol wt 184.24,is produced as a colorless crystalline material or a white powder.


Potassium oxalate is an odorless white solid. Sinks in and mixes slowly with water. (USCG, 1999)


Potassium oxalate is an odorless white solid. Sinks in and mixes slowly with water. (USCG, 1999)|A strong dicarboxylic acid occurring in many plants and vegetables. It is produced in the body by metabolism of glyoxylic acid or ascorbic acid. It is not metabolized but excreted in the urine. It is used as an analytical reagent and general reducing agent.

Potassium oxalate monohydrate Basic Attributes

184.23

183.917633

3752576

209-506-8

LC7F2W7I5B

2928

DTXSID6060393

2917119000

Characteristics

89.49000

White Crystals or Flakes

2.127

356 °C

365.1ºC at 760 mmHg

188.8ºC

H2O: 364 g/L (20 ºC)

Store at RT.

<0.1 hPa (20 °C)

LD50 orally in Rabbit: 660 mg/kg

Water soluble.

Salts, Basic

POTASSIUM OXALATE gives basic aqueous solutions. Reacts as a base to neutralize acids in reactions that generate heat, but less than is generated by neutralization of the bases in reactivity group 10. Can serve as a reducing agent in reactions that generate carbon dioxide.

Safety Information

III

6.1

3282

1

21/22

24/25

RO2885000

Xn

Stable. Incompatible with strong oxidizing agents. Protect from moisture.

P280-P301 + P312 + P330

H302 + H312

Behavior in Fire: Loses water at about 160° and decomposes to carbonate with no charring. The reaction is not hazardous. (USCG, 1999)

|Warning|H302 (99.39%): Harmful if swallowed [Warning Acute toxicity, oral]|P264, P270, P280, P301+P312, P302+P352, P305+P351+P338, P312, P322, P330, P337+P313, P363, and P501|Aggregated GHS information provided by 163 companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.|Danger|H302: Harmful if swallowed [Warning Acute toxicity, oral]|P260, P261, P264, P270, P271, P280, P301+P312, P302+P352, P304+P340, P305+P351+P338, P310, P312, P314, P321, P322, P330, P332+P313, P362, P363, P403+P233, P405, and P501|P264, P270, P301+P312, P330, and P501

Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]: SMALL FIRE: Dry chemical, CO2 or water spray. LARGE FIRE: Dry chemical, CO2, alcohol-resistant foam or water spray. Move containers from fire area if you can do it without risk. Dike fire-control water for later disposal; do not scatter the material. FIRE INVOLVING TANKS OR CAR/TRAILER LOADS: Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Do not get water inside containers. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks engulfed in fire. (ERG, 2016)

Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]: As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. SPILL: Increase, in the downwind direction, as necessary, the isolation distance shown above. FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2016)

Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]: ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. Prevent entry into waterways, sewers, basements or confined areas. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. DO NOT GET WATER INSIDE CONTAINERS. (ERG, 2016)

Approved dust respirator; chemical goggles; rubber or plastic-coated gloves (USCG, 1999)

Drug Information

Materials that add an electron to an element or compound, that is, decrease the positiveness of its valence. (From McGraw-Hill Dictionary of Scientific and Technical Terms, 5th ed) (See all compounds classified as Reducing Agents.)

Inhalation of dust can cause systemic poisoning. Ingestion causes burning pain in throat, esophagus, and stomach; exposed areas of mucous membrane turn white; vomiting, severe purging, weak pulse, and cardiovascular collapse may result; if death is delayed, neuromuscular symptoms develop. Contact with eyes or skin causes irritation. (USCG, 1999)

Act promptly! INHALATION: remove victim to fresh air; if exposure to dust is severe, get medical attention. INGESTION: call physician immediately; have victim drink dilute calcium lactate, lime water, chalk soln., or even milk; large amounts of calcium are required; administer gastric lavage with dilute lime water; watch for edema of the glottis and delayed constriction of esophagus. EYES: flush with water and seek medical attention. SKIN: flush with water. (USCG, 1999)

Acid, Oxalic

Potassium oxalate monohydrate Use and Manufacturing

Uses

Used as analytical reagent, also used to prevent blood coagulation, pharmaceutical industry and film printing

Ethanedioic acid, potassium salt (1:2): ACTIVE

Cosmetics -> Chelating

Computed Properties

Molecular Weight:166.22
Hydrogen Bond Acceptor Count:4
Exact Mass:165.90707145
Monoisotopic Mass:165.90707145
Topological Polar Surface Area:80.3
Heavy Atom Count:8
Complexity:60.5
Covalently-Bonded Unit Count:3
Compound Is Canonicalized:Yes

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