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Home > Encyclopedia > 1,2-Epoxyhexadecane

1,2-Epoxyhexadecane

1,2-Epoxyhexadecane structure

1,2-Epoxyhexadecane 

structure
  • CAS No:

    7320-37-8

  • Formula:

    C16H32O

  • Chemical Name:

    1,2-Epoxyhexadecane

  • Synonyms:

    Oxirane,2-tetradecyl-;Hexadecane,1,2-epoxy-;Oxirane,tetradecyl-;2-Tetradecyloxirane;1,2-Epoxyhexadecane;Hexadecylene oxide;1,2-Hexadecene epoxide;Tetradecyloxirane;Vikolox 16;1,2-Hexadecylene oxide;1,2-Epoxyhexadecene;Cyracure UVR 6216;1-Hexadecene oxide;UVR 6216;151284-10-5

  • Categories:

    Organic Chemistry  >  Hydrocarbons and Derivatives

Description

Liquid


1,2-epoxyhexadecane appears as white waxy solid or clear colorless liquid. Faint pleasant odor. (NTP, 1992)|Liquid


1,2-epoxyhexadecane appears as white waxy solid or clear colorless liquid. Faint pleasant odor. (NTP, 1992)|1,2-Epoxyhexadecane is an epoxide.

1,2-Epoxyhexadecane Basic Attributes

240.42

240.42

230-786-2

DTXSID9025245

Characteristics

12.5

5.47640

1,2-epoxyhexadecane appears as white waxy solid or clear colorless liquid. Faint pleasant odor. (NTP, 1992)

0.8457 g/cm3 @ Temp: 20 °C

21-22 °C

175-180 °C @ Press: 12 Torr

93 °C

n20/D 1.446(lit.)

Reaction (NTP, 1992)

2-8°C

Moisture sensitive. Insoluble in water.

Epoxides

Polymerizable

The neat compound, 1,2-EPOXYHEXADECANE, is sensitive to prolonged exposure to heat. It is also moisture sensitive. This material reacts with inorganic acids, thiosulfate, carboxylic acids, hydrogen cyanide, water, amines, aldehydes, alcohols, and caustics. It will also react with amino, hydroxyl and carboxyl groups. (NTP, 1992)

Safety Information

NONH for all modes of transport

1

36/37/38

26-36/37

ML9450000

Xi

P261-P305 + P351 + P338

H315-H319-H335-H413

Flash point data are not available for this chemical, but it is probably combustible. (NTP, 1992)

|Warning|H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]|P201, P202, P261, P264, P272, P280, P281, P302+P352, P305+P351+P338, P308+P313, P321, P332+P313, P333+P313, P337+P313, P362, P363, P405, and P501|Aggregated GHS information provided by 581 companies from 8 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.|H315: Causes skin irritation [Warning Skin corrosion/irritation]|P261, P264, P272, P280, P302+P352, P321, P332+P313, P333+P313, P362, P363, and P501

Fires involving this compound should be controlled using a dry chemical, carbon dioxide or Halon extinguisher. (NTP, 1992)

SMALL SPILLS AND LEAKAGE: If a spill of this chemical occurs, FIRST REMOVE ALL SOURCES OF IGNITION, then you should dampen the solid spill material with acetone and transfer the dampened material to a suitable container. Use absorbent paper dampened with acetone to pick up any remaining material. Seal your contaminated clothing and the absorbent paper in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with acetone followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned. STORAGE PRECAUTIONS: You should store this chemical under refrigerated temperatures, and protect it from moisture. (NTP, 1992)

RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)

Drug Information

1-HEXADECENE IS METABOLIZED TO 1,2-DIHYDROXYHEXADECANE VIA 1,2-EPOXYHEXADECANE BY HEPATIC MICROSOMES.

SYMPTOMS: Exposure to this compound may result in skin irritation which is characterized by localized lesions, redness, swelling and itching. Chronic symptoms include loss of body weight, gastric irritation and moderate liver damage. Prolonged inhalation may cause acute pulmonary edema or chemical pneumonia. It also causes sensitization. ACUTE/CHRONIC HAZARDS: This material can cause skin, eye and mucous membrane irritation. When heated to decomposition it emits acrid smoke and fumes. (NTP, 1992)

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment. INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing. INGESTION: DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)

1,2-epoxyhexadecane

1,2-Epoxyhexadecane Use and Manufacturing

Methods of Manufacturing

EPOXIDATION OF 1-HEXADECENE WITH PERACETIC ACID

Uses

Lubricants and lubricant additives


Lubricants and greases

Production

(1975) PROBABLY GREATER THAN 2.27X10+6 GRAMS|(1979) No Data

All other chemical product and preparation manufacturing|Oxirane, 2-tetradecyl-: ACTIVE

Computed Properties

Molecular Weight:240.42
XLogP3:7.3
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:13
Exact Mass:240.245315640
Monoisotopic Mass:240.245315640
Topological Polar Surface Area:12.5
Heavy Atom Count:17
Complexity:156
Undefined Atom Stereocenter Count:1
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes

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