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2-Nitrobiphenyl

2-Nitrobiphenyl structure

2-Nitrobiphenyl 

structure
  • CAS No:

    86-00-0

  • Formula:

    C12H9NO2

  • Chemical Name:

    2-Nitrobiphenyl

  • Synonyms:

    1,1′-Biphenyl,2-nitro-;Biphenyl,2-nitro-;2-Nitro-1,1′-biphenyl;o-Nitrobiphenyl;2-Nitrobiphenyl;o-Nitrodiphenyl;ONB;2-Phenylnitrobenzene;NSC 5532;2′-Nitrobiphenyl;o-Nitrophenyl benzene

  • Categories:

    Chemical Reagents  >  Organic Reagents

Description

CLEAR YELLOW LIQUID AFTER MELTING


Gold to tan crystals or brown solid. (NTP, 1992)


Gold to tan crystals or brown solid. (NTP, 1992)

2-Nitrobiphenyl Basic Attributes

199.21

199.21

201-646-8

8R1N47E4DT

5532

DTXSID9025746

2904209090

Characteristics

45.8

3.52

Gold to tan crystals or brown solid. (NTP, 1992)

1.203 at 77° F (NTP, 1992)

37.2 °C

320 °C

>230 °F

1.605

H2O: Insoluble

2 mm Hg ( 140 °C)

5.9 (vs air)

Insoluble in water.

Hydrocarbons, Aromatic

Aromatic nitro compounds, such as 2-NITRO-1,1'-BIPHENYL, range from slight to strong oxidizing agents. If mixed with reducing agents, including hydrides, sulfides and nitrides, they may begin a vigorous reaction that culminates in a detonation. The aromatic nitro compounds may explode in the presence of a base such as sodium hydroxide or potassium hydroxide even in the presence of water or organic solvents. The explosive tendencies of aromatic nitro compounds are increased by the presence of multiple nitro groups.

356 °F (NTP, 1992)

Safety Information

3

20/21/22-40-68-22

2-7-36-45-36/37

DV5530000

Xn

P201, P202, P261, P264, P270, P271, P280, P281, P301+P312, P302+P352, P304+P312, P304+P340, P308+P313, P312, P322, P330, P363, P405, P501

H302

This compound is combustible. (NTP, 1992)

|Warning|H302 (100%): Harmful if swallowed [Warning Acute toxicity, oral]|P201, P202, P261, P264, P270, P271, P280, P281, P301+P312, P302+P352, P304+P312, P304+P340, P308+P313, P312, P322, P330, P363, P405, and P501|Aggregated GHS information provided by 39 companies from 2 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Fires involving this compound can be controlled using a dry chemical, carbon dioxide or Halon extinguisher. (NTP, 1992)

SMALL SPILLS AND LEAKAGE: Should a spill occur while you are handling this chemical, FIRST REMOVE ALL SOURCES OF IGNITION, then you should dampen the solid spill material with 60-70% ethanol and transfer the dampened material to a suitable container. Use absorbent paper dampened with 60-70% ethanol to pick up any remaining material. Seal the absorbent paper, and any of your clothes, which may be contaminated, in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with 60-70% ethanol followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned. STORAGE PRECAUTIONS: You should store this material in a refrigerator. (NTP, 1992)

RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)

Drug Information

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment. INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing. INGESTION: DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)

2-Nitrobiphenyl Use and Manufacturing

Plasticizer for resins, cellulose acetate and nitrate, polystyrenes; fungicide for textiles; wood preservative; dye intermediate.

Computed Properties

Molecular Weight:199.20
XLogP3:3.7
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:1
Exact Mass:199.063328530
Monoisotopic Mass:199.063328530
Topological Polar Surface Area:45.8
Heavy Atom Count:15
Complexity:218
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes

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