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Home > Encyclopedia > 2-(4-Aminophenyl)-6-methylbenzothiazole

2-(4-Aminophenyl)-6-methylbenzothiazole

2-(4-Aminophenyl)-6-methylbenzothiazole structure

2-(4-Aminophenyl)-6-methylbenzothiazole 

structure
  • CAS No:

    92-36-4

  • Formula:

    C14H12N2S

  • Chemical Name:

    2-(4-Aminophenyl)-6-methylbenzothiazole

  • Synonyms:

    Benzenamine,4-(6-methyl-2-benzothiazolyl)-;Benzothiazole,2-(p-aminophenyl)-6-methyl-;Benzothiazole,1-(p-aminophenyl)-5-methyl-;4-(6-Methyl-2-benzothiazolyl)benzenamine;2-(4-Aminophenyl)-6-methylbenzothiazole;Dehydrothio-p-toluidine;4-(6-Methyl-2-benzothiazolyl)aniline;2-(p-Aminophenyl)-6-methylbenzothiazole;NSC 15370;NSC 57678;4-(6-Methylbenzo[d]thiazol-2-yl)aniline

  • Categories:

    Organic Chemistry  >  Amides

Description

PHYSICAL DESCRIPTION: Light tan or light orange powder. Solutions have a violet-blue fluorescence. (NTP, 1992)


2-(4-aminophenyl)-6-methylbenzothiazole appears as light tan or light orange powder. Solutions have a violet-blue fluorescence. (NTP, 1992)


2-(4-aminophenyl)-6-methylbenzothiazole appears as light tan or light orange powder. Solutions have a violet-blue fluorescence. (NTP, 1992)

2-(4-Aminophenyl)-6-methylbenzothiazole Basic Attributes

240.32

240.32

202-150-4

69UN466K3Z

57678|15370

DTXSID5024502

2934999090

Characteristics

67.2

3.9

2-(4-aminophenyl)-6-methylbenzothiazole appears as light tan or light orange powder. Solutions have a violet-blue fluorescence. (NTP, 1992)

1.264 g/cm3

194.8 °C

434 °C

217.3ºC

1.709

H2O: <0.1 g/100 mL at 20 ºC

Keep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition sources and untrained individuals. Secure and label area. Protect containers/cylinders from physical damage.

Insoluble in water.

Sulfides, Organic

2-(4-AMINOPHENYL)-6-METHYLBENZOTHIAZOLE is incompatible with strong oxidizing agents, acid chlorides and acid anhydrides. (NTP, 1992)

Safety Information

IRRITANT

NONH for all modes of transport

R36/37/38

S26;S36

DL2820000

Xi

P261-P305 + P351 + P338

H315-H319-H335

Flash point data for this chemical are not available; however, it is probably combustible. (NTP, 1992)

|Warning|H315 (98.99%): Causes skin irritation [Warning Skin corrosion/irritation]|P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, and P501|Aggregated GHS information provided by 198 companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Fires involving this material can be controlled with a dry chemical, carbon dioxide or Halon extinguisher. A water spray may also be used. (NTP, 1992)

SMALL SPILLS AND LEAKAGE: If a spill of this chemical occurs, FIRST REMOVE ALL SOURCES OF IGNITION, then you should dampen the solid spill material with acetone and transfer the dampened material to a suitable container. Use absorbent paper dampened with acetone to pick up any remaining material. Seal your contaminated clothing and the absorbent paper in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with acetone followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned. STORAGE PRECAUTIONS: You should protect this chemical from exposure to light and store it at ambient temperatures. (NTP, 1992)

RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)

Drug Information

SYMPTOMS: Symptoms of exposure to this compound include irritation of the eyes, skin, mucous membranes and upper respiratory tract. ACUTE/CHRONIC HAZARDS: This compound may be harmful by inhalation or ingestion. It is an irritant of the eyes, skin, mucous membranes and upper respiratory tract. When heated to decomposition it emits toxic fumes of carbon monoxide, carbon dioxide and nitrogen oxides. (NTP, 1992)

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment. INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing. INGESTION: DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)

dehydrothio-4-toluidine

2-(4-Aminophenyl)-6-methylbenzothiazole Use and Manufacturing

Uses

It is an important intermediate for synthetic paper dyes.

Benzenamine, 4-(6-methyl-2-benzothiazolyl)-: ACTIVE

Computed Properties

Molecular Weight:240.33
XLogP3:3.9
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:1
Exact Mass:240.07211956
Monoisotopic Mass:240.07211956
Topological Polar Surface Area:67.2
Heavy Atom Count:17
Complexity:263
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes

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