Sulfallate

223.79

223.79

205-701-7

7U7BI7173J

16085

3082|2991

DTXSID7021289

C44448

Amber oil|Amber liquid

2930200016

60.6

3.15 (est)

Sulfallate is an amber to dark amber liquid. (NTP, 1992)

1.088 g/cm³ @ Temp: 25 °C

25°C

128-130 °C

>100 °C

1.561

soluble in most organic solvents.

APPROX 4°C

2.2X10-3 mm Hg at 20 deg C

Oral-Rat  LD50: 850 mg/kg

Combustion produces toxic nitrogen oxides, sulfur oxides and chloride gases

Henry's Law constant = 6.48X10-6 atm-cu m/mol at 25 °C (est)

Decomposition temperature: 150 dec C; noncorrosive to metals|Hydrolyzed in alkali solution, half-life at pH 5 47 days, at pH 8, 30 days|Hydroxyl radical reaction rate constant = 1.03X10-10 cu cm/molecule-sec at 25 °C (est)

Insoluble in water. Thio and dithiocarbamates slowly decompose in aqueous solution to form carbon disulfide and methylamine or other amines. Such decompositions are accelerated by acids.

Thiocarbamate Esters and Salts/Dithiocarbamate Esters and Salts

SULFALLATE is incompatible with strong oxidizing agents .Also incompatible with alkalis. (NTP, 1992).

UN30829/PG3

45-22-50/53

53-45-60-61

EZ5075000

T,N

Warehouse ventilated, low temperature and dry

Stable. Incompatible with alkalies, strong oxidizing agents.

P201-P273-P308 + P313-P501

H302-H350-H410

SRP: The most favorable course of action is to use an alternative chemical product with less inherent propensity for occupational harm/injury/toxicity or environmental contamination. Recycle any unused portion of the material for its approved use or return it to the manufacturer or supplier. Ultimate disposal of the chemical must consider: the material's impact on air quality; potential migration in soil or water; effects on animal and plant life; and conformance with environmental and public health regulations.|SRP: Wastewater from contaminant suppression, cleaning of protective clothing/equipment, or contaminated sites should be contained and evaluated for subject chemical or decomposition product concentrations. Concentrations shall be lower than applicable environmental discharge or disposal criteria. Alternatively, pretreatment and/or discharge to a permitted wastewater treatment facility is acceptable only after review by the governing authority and assurance that "pass through" violations will not occur. Due consideration shall be given to remediation worker exposure (inhalation, dermal and ingestion) as well as fate during treatment, transfer and disposal. If it is not practicable to manage the chemical in this fashion, it must be evaluated in accordance with EPA 40 CFR Part 261, specifically Subpart B, in order to determine the appropriate local, state and federal requirements for disposal.|SRP: At the time of review, criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.|Hydrolysis: Sulfallate is hydrolyzed very slowly in either very weak acid, pH 5, or very weak base, pH 8. It is hydrolyzed rapidly in boiling caustic and is completely decomposed by strong oxidizing agents. Recommendable method: Incineration. Peer-review: Large amt should be incinerated in a unit with effluent gas scrubbing. (Peer-review conclusions of an IRPTC expert consultation (May 1985))|For more Disposal Methods (Complete) data for SULFALLATE (14 total), please visit the HSDB record page.

Strong oxidizers

DHEW/NCI; Bioassay of Sulfallate for Possible Carcinogenicity (1978) Technical Rpt Series No. 115 DHEW Pub No. (NIH) 78-1370|U.S. Department of Health & Human Services/National Toxicology Program; Twelfth Report on Carcinogens (2011). The Report on Carcinogens is an informational scientific and public health document that identifies and discusses substances (including agents, mixtures, or exposure circumstances) that may pose a carcinogenic hazard to human health. Sulfallate (95-06-7) is listed as reasonably anticipated to be a human carcinogen. First listed in the Third Annual Report on Carcinogens (1983).[Available from, as of March 1, 2012: http://ntp.niehs.nih.gov/?objectid=03C9AF75-E1BF-FF40-DBA9EC0928DF8B15]

This chemical is probably combustible. (NTP, 1992)|Carcinogens, Flammable - 2nd degree

|Danger|H302: Harmful if swallowed [Warning Acute toxicity, oral]|P201, P202, P264, P270, P273, P281, P301+P312, P308+P313, P330, P391, P405, and P501|H302 (100%): Harmful if swallowed [Warning Acute toxicity, oral]|Aggregated GHS information provided by 197 companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.|Warning|P201, P202, P260, P264, P270, P280, P281, P301+P312, P302+P352, P305+P351+P338, P308+P313, P312, P314, P321, P330, P332+P313, P337+P313, P362, P405, and P501

Excerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]: As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. SPILL: Increase, in the downwind direction, as necessary, the isolation distance shown above. FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2016)

SMALL SPILLS AND LEAKAGE: If you spill this chemical, FIRST REMOVE ALL SOURCES OF IGNITION. Then, use absorbent paper to pick up all liquid spill material. Your contaminated clothing and absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with 60-70% ethanol followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned. STORAGE PRECAUTIONS: You should store this material in a refrigerator away from oxidizing materials, acids, and bases. (NTP, 1992)

MINIMUM PROTECTIVE CLOTHING: If Tyvek-type disposable protective clothing is not worn during handling of this chemical, wear disposable Tyvek-type sleeves taped to your gloves. RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with a combination filter cartridge, i.e. organic vapor/acid gas/HEPA (specific for organic vapors, HCl, acid gas, SO2 and a high efficiency particulate filter). (NTP, 1992)|PRECAUTIONS FOR "CARCINOGENS": ... Dispensers of liq detergent /should be available./ ... Safety pipettes should be used for all pipetting. ... In animal laboratory, personnel should ... wear protective suits (preferably disposable, one-piece & close-fitting at ankles & wrists), gloves, hair covering & overshoes. ... In chemical laboratory, gloves & gowns should always be worn ... however, gloves should not be assumed to provide full protection. Carefully fitted masks or respirators may be necessary when working with particulates or gases, & disposable plastic aprons might provide addnl protection. ... Gowns ... /should be/ of distinctive color, this is a reminder that they are not to be worn outside the laboratory. /Chemical Carcinogens/|Respirator selection, upper limit devices recommended by NIOSH. For concn up to 50 mg/cu m, use any supplied air respirator; or any self-contained breathing apparatus. For concn up to 125 mg/cu m, use any supplied-air respirator operated in a continuous flow mode. For concn up to 250 mg/cu m, use any self-contained breathing apparatus with a full facepiece; or any supplied-air respirator with a full facepiece. For concn up to 600 mg/cu m, use any supplied-air respirator with a half-mask and operated in a pressure-demand or other positive pressure mode. For emergency or planned entry into unknown concentration or IDLH conditions, use any self-contained breathing apparatus with a full facepiece and operated in a pressure-demand or other positive pressure mode; or any supplied-air respirator with a full facepiece and operated in a pressure-demand or other positive pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive pressure mode. Escape conditions use, any air-purifying full facepiece respirator (gas mask) with a chin-style or front- or back-mounted organic vapor canister having a high-efficiency particulate filter; or any appropriate escape-type self-contained breathing apparatus. /Carbaryl/|Employees should be provided with and required to use impervious clothing, gloves, face shields (eight-inch minimum), and other appropriate protective clothing necessary to prevent repeated or prolonged skin contact with carbaryl or liquids containing carbaryl. /Carbaryl/

/Wear/ self-contained breathing apparatus with a full facepiece operated in pressure-demand or other positive pressure mode /when fighting fire/. /Carbaryl/

Vapors may travel long distances to ignition sources and flashback. Vapors in confined areas may explode in fire.

PRECAUTIONS FOR "CARCINOGENS": A high-efficiency particulate arrestor (HEPA) or charcoal filters can be used to minimize amt of carcinogen in exhausted air ventilated safety cabinets, lab hoods, glove boxes or animal rooms ... Filter housing that is designed so that used filters can be transferred into plastic bag without contaminating maintenance staff is avail commercially. Filters should be placed in plastic bags immediately after removal ... The plastic bag should be sealed immediately ... The sealed bag should be labelled properly ... Waste liquids ... should be placed or collected in proper containers for disposal. The lid should be secured & the bottles properly labelled. Once filled, bottles should be placed in plastic bag, so that outer surface ... is not contaminated ... The plastic bag should also be sealed & labelled. ... Broken glassware ... should be decontaminated by solvent extraction, by chemical destruction, or in specially designed incinerators. /Chemical Carcinogens/|A system for removing pesticides from the wash water produced by pesticide applicators as they clean their equipment has been developed. The first step is the flocculation/coagulation and sedimentation of the pesticide-contaminated wash water. The supernatant from the first step is then passed through activated carbon columns. /Pesticides/

SRP: Contaminated protective clothing should be segregated in such a manner so that there is no direct personal contact by personnel who handle, dispose, or clean the clothing. The completeness of the cleaning procedures should be considered before the decontaminated protective clothing is returned for reuse by the workers. Contaminated clothing should not be taken home at the end of shift, but should remain at employee's place of work for cleaning.|PRECAUTIONS FOR "CARCINOGENS": Smoking, drinking, eating, storage of food or of food & beverage containers or utensils, & the application of cosmetics should be prohibited in any laboratory. All personnel should remove gloves, if worn, after completion of procedures in which carcinogens have been used. They should ... wash ... hands, preferably using dispensers of liq detergent, & rinse ... thoroughly. Consideration should be given to appropriate methods for cleaning the skin, depending on nature of the contaminant. No standard procedure can be recommended, but the use of organic solvents should be avoided. Safety pipettes should be used for all pipetting. /Chemical Carcinogens/|PRECAUTIONS FOR "CARCINOGENS": In animal laboratory, personnel should remove their outdoor clothes & wear protective suits (preferably disposable, one-piece & close-fitting at ankles & wrists), gloves, hair covering & overshoes. ... Clothing should be changed daily but ... discarded immediately if obvious contamination occurs ... /also,/ workers should shower immediately. In chemical laboratory, gloves & gowns should always be worn ... however, gloves should not be assumed to provide full protection. Carefully fitted masks or respirators may be necessary when working with particulates or gases, & disposable plastic aprons might provide addnl protection. If gowns are of distinctive color, this is a reminder that they should not be worn outside of lab. /Chemical Carcinogens/|PRECAUTIONS FOR "CARCINOGENS": ... Operations connected with synth & purification ... should be carried out under well-ventilated hood. Analytical procedures ... should be carried out with care & vapors evolved during ... procedures should be removed. ... Expert advice should be obtained before existing fume cupboards are used ... & when new fume cupboards are installed. It is desirable that there be means for decreasing the rate of air extraction, so that carcinogenic powders can be handled without ... powder being blown around the hood. Glove boxes should be kept under negative air pressure. Air changes should be adequate, so that concn of vapors of volatile carcinogens will not occur. /Chemical Carcinogens/|For more Preventive Measures (Complete) data for SULFALLATE (11 total), please visit the HSDB record page.

PRECAUTIONS FOR "CARCINOGENS": Procurement ... of unduly large amt ... should be avoided. To avoid spilling, carcinogens should be transported in securely sealed glass bottles or ampoules, which should themselves be placed inside strong screw-cap or snap-top container that will not open when dropped & will resist attack from the carcinogen. Both bottle & the outside container should be appropriately labelled. ... National post offices, railway companies, road haulage companies & airlines have regulations governing transport of hazardous materials. These authorities should be consulted before ... material is shipped. /Chemical Carcinogens/|PRECAUTIONS FOR "CARCINOGENS": When no regulations exist, the following procedure must be adopted. The carcinogen should be enclosed in a securely sealed, watertight container (primary container), which should be enclosed in a second, unbreakable, leakproof container that will withstand chem attack from the carcinogen (secondary container). The space between primary & secondary container should be filled with absorbent material, which would withstand chem attack from the carcinogen & is sufficient to absorb the entire contents of the primary container in the event of breakage or leakage. Each secondary container should then be enclosed in a strong outer box. The space between the secondary container & the outer box should be filled with an appropriate quantity of shock-absorbent material. Sender should use fastest & most secure form of transport & notify recipient of its departure. If parcel is not received when expected, carrier should be informed so that immediate effort can be made to find it. Traffic schedules should be consulted to avoid ... arrival on weekend or holiday ... /Chemical Carcinogens/

Prolonged contact with skin and eyes may cause moderate irritation.

SOURCE DOMINATED: Sulfallate has been reported to be present in the air emissions from sulfallate manufacture at a level of 0.5 kg/1000 kg pesticide produced.

moderately toxic

N,N-DIALLYL-ALPHA,ALPHA-DICHLOROACETAMIDE REDUCED TOXICITY OF SULFALLATE TO CORN (ZEA MAYS).

LD50 Rabbit skin 2200 mg/kg|LD50 Rat oral 850 mg/kg body wt

A bioassay for possible carcinogenicity of sulfallate was conducted using B6C3Fl mice. Sulfallate was administered in the feed, at either of two concentrations, to groups of 50 male and 50 female mice. Twenty mice each sex were placed on test as controls for the bioassay. The time-weighted average high and low dietary concentrations of sulfallate were, respectively, 1897 and 949 ppm for male mice, and 1815 and 908 ppm for female mice. After the 78 week period of chemical administration, there was an additional observation period of 12 to 13 weeks for dosed and control mice. There were significant positive associations between increased sulfallate concentration and accelerated mortality in ... female mice. However, adequate numbers of animals in all groups survived sufficiently long to be at risk from late-developing tumors. Statistical analyses of the ... combined alveolar/bronchiolar carcinomas and alveolar/ bronchiolar adenomas in male mice, and adenocarcinomas of the mammary gland in female mice revealed a significant positive association between dosage and incidence. These associations were all supported by at least one significant Fisher exact comparison. The incidence of toxic tubular nephropathy observed in ... mice (both sexes)increased with the concentration of the compound administered. This nonneoplastic lesion was not observed in control animals. Under the conditions of this bioassay dietary administration of sulfallate was carcinogenic to B6C3Fl mice, inducing mammary gland tumors in females, ... and lung tumors in male mice.|A bioassay for possible carcinogenicity of sulfallate was conducted using Osborne-Mendel rats. Sulfallate was administered in the feed, at either of two concentrations, to groups of 50 male and 50 female rats. Fifty rats of each sex were placed on test as controls for the bioassay. The time-weighted average high and low dietary concentrations of sulfallate were, respectively, 410 and 250 ppm for male rats, 404 and 250 ppm for female rats. After the 78 week period of chemical administration, there was an additional observation period of 25 to 26 weeks for dosed rats, 33 weeks for control rats. There were significant positive associations between increased sulfallate concentration and accelerated mortality in both sexes of rats. However, adequate numbers of animals in all groups survived sufficiently long to be at risk from late developing tumors. Statistical analyses of the incidences of mammary adenocarcinomas in female rats, stomach neoplasms (i.e., combination of papillomas NOS, squamous cell papillomas, and squamous-cell carcinomas) in male rats ... revealed a significant positive association between dosage and incidence. These associations were all supported by at least one significant Fisher exact comparison. The incidence of toxic tubular nephropathy observed in male rats and in mice of both sexes increased with the concentration of the compound administered. This nonneoplastic lesion was not observed in control animals. Under the conditions of this bioassay dietary administration of sulfallate was carcinogenic to Osborne-Mendel rats ... inducing ... tumors of the forestomach in male rats.

Sulfallate is not known to occur as a natural product.

Sulfallate's former US production may have resulted in its release to the environment through various waste streams; its former use as a herbicide(1) resulted in its direct release to the environment(SRC).

TERRESTRIAL FATE: Based on a classification scheme(1), an estimated Koc value of 2000(SRC), determined from a structure estimation method(2), indicates that sulfallate is expected to have moderate mobility in soil(SRC). Volatilization of sulfallate from moist soil surfaces is expected to be an important fate process(SRC) based upon an estimated Henry's Law constant of 6.5X10-6 atm-cu m/mole(SRC), derived from its vapor pressure, 2.2X10-3 mm Hg(3), and water solubility, 100 mg/L(4). However, adsorption to soil is expected to attenuate volatilization(SRC). Sulfallate is expected to volatilize from dry soil surfaces(SRC) based upon its vapor pressure(3). It persists in soil for 21 to 42 days(5).|TERRESTRIAL FATE: Resultant average persistence at recommended rates: generally 3-6 weeks, on sandy soils with heavy rainfall, CDEC will persist 3-4 weeks, and 5-6 weeks on loams or clay soils with moderate precipitation|TERRESTRIAL FATE: At commercially recommended rates of 4 lb/gal, the average persistence of sulfallate in soil is 3 to 6 weeks.|AQUATIC FATE: Based on a classification scheme(1), an estimated Koc value of 2000(SRC), determined from a structure estimation method(2), indicates that sulfallate is expected to adsorb to suspended solids and sediment(SRC). Volatilization from water surfaces is expected(3) based upon an estimated Henry's Law constant of 6.7X10-6 atm-cu m/mole(SRC), derived from its vapor pressure, 2.2X10-3 mm Hg(4), and water solubility, 100 mg/L(5). Using this Henry's Law constant and an estimation method(3), volatilization half-lives for a model river and model lake are 9 and 67 days, respectively(SRC). According to a classification scheme(6), an estimated BCF of 60(SRC), from an estimated log Kow of 3.15(7) and a regression-derived equation(2), suggests the potential for bioconcentration in aquatic organisms is moderate(SRC). Biodegradation data in water were not available(SRC, 2012).|ATMOSPHERIC FATE: According to a model of gas/particle partitioning of semivolatile organic compounds in the atmosphere(1), sulfallate, which has a vapor pressure of 2.2X10-3 mm Hg at 20 °C(2), is expected to exist solely as a vapor in the ambient atmosphere. Vapor-phase sulfallate is degraded in the atmosphere by reaction with photochemically-produced hydroxyl radicals(SRC); the half-life for this reaction in air is estimated to be 1.2 hours(SRC), calculated from its rate constant of 1.0X10-10 cu cm/molecule-sec at 25 °C(SRC) that was derived using a structure estimation method(3). Sulfallate absorbs light at wavelengths >290 nm(4), and therefore may be susceptible to direct photolysis by sunlight(SRC).

The rate constant for the vapor-phase reaction of sulfallate with photochemically-produced hydroxyl radicals has been estimated as 1.0X10-10 cu cm/molecule-sec at 25 °C(SRC) using a structure estimation method(1). This corresponds to an atmospheric half-life of about 1.2 hours at an atmospheric concentration of 5X10+5 hydroxyl radicals per cu cm(1). The rate constant for the vapor-phase reaction of sulfallate with ozone has been estimated as 1.6X10-18 cu cm/molecule-sec at 25 °C(SRC) that was derived using a structure estimation method(1). This corresponds to an atmospheric half-life of about 7 days at an atmospheric concentration of 7X10+11 ozone molecules per cu cm(2). Sulfallate is hydrolyzed by alkali, with half-lives of 57 days at pH 5 and 30 days at pH 8 being reported(3). Sulfallate absorbs light at wavelengths >290 nm(4), and therefore may be susceptible to direct photolysis by sunlight; the kinetics of this potential reaction are unknown(SRC). Sulfallate persists in soil for 21 to 42 days(3).

An estimated BCF of 60 was calculated in fish for sulfallate(SRC), using an estimated log Kow of 3.15(1) and a regression-derived equation(2). According to a classification scheme(3), this BCF suggests the potential for bioconcentration in aquatic organisms is moderate(SRC).

Using a structure estimation method based on molecular connectivity indices(1), the Koc of sulfallate can be estimated to be 2000(SRC). According to a classification scheme(2), this estimated Koc value suggests that sulfallate is expected to have low mobility in soil.

The Henry's Law constant for sulfallate is estimated as 6.5X10-6 atm-cu m/mole(SRC) derived from its vapor pressure, 2.2X10-3 mm Hg(1), and water solubility, 100 mg/L(2). This Henry's Law constant indicates that sulfallate is expected to volatilize from water surfaces(3). Based on this Henry's Law constant, the volatilization half-life from a model river (1 m deep, flowing 1 m/sec, wind velocity of 3 m/sec)(3) is estimated as 9 days(SRC). The volatilization half-life from a model lake (1 m deep, flowing 0.05 m/sec, wind velocity of 0.5 m/sec)(3) is estimated as 67 days(SRC). Sulfallate's estimated Henry's Law constant indicates that volatilization from moist soil surfaces may occur(SRC). Sulfallate is not expected to volatilize from dry soil surfaces(SRC) based upon its vapor pressure(1).

SURFACE WATER: Sulfallate was detected in surface water from the Comunitat Valenciana, Spain at a concentration of 2.247 ug/mL(1).

Sulfallate was identified, not quantified, in vegetables during the 1978-1982 pesticide monitoring program by the US FDA(1) and in the 1988-1989 monitoring program(2). Sulfallate was identified, not quantified in domestic and imported tomatoes(3).

A potential for exposure exists during the manufacture and application of the herbicide. Agricultural workers have the greatest risk of sulfallate exposure, and rural residents of agricultural communities may be exposed to airborne residues of sulfallate after spraying operations. ... The general population may be exposed through ingestion of residues in food crops.|Occupational exposure and general population exposure should be low or non-existent since sulfallate is no longer produced or used in the US (2012). The general population may have been exposed to sulfallate via ingestion of vegetables grown in fields treated with sulfallate to control certain annual grasses and broadleaf weeds. (SRC)

... S-alkyl and S-(chloroallyl) thiocarbamate herbicides ... sulfallate ... undergo sequential liberation of the thiocarbamic acid and then S-methylation, forming the S-methyl thiocarbamates which are new metabolites and potential aldehyde dehydrogenase inhibitors. ...|2-CHLOROACROLEIN IS FORMED FROM SULFALLATE WHEN IT IS INCUBATED WITH RAT LIVER MICROSOMES.|TOLERANT CROP SPECIES COMPLETELY DEGRADE CDEC OR ITS INTERMEDIATE, DIETHYLAMINE.|The proposed metabolites of diallate, triallate, and sulfallate were identified and quantitated by HPLC and GLC headspace analysis as chloroacroleins and chloroallylthiols. The quantitative relationships indicate that the thiocarbamates yield chloroacroleins on metabolic activation with the mixed function oxidase system alone, while the intermediate S-oxidation products were detoxified on diversion to chloroallylthiols when the glutathione/glutathione-S-transferase system was also present. The major mouse microsomal mixed function oxidase metabolites of three cmpd were identified by HPLC cochromatography as the corresponding sulfoxides. It was concluded that the formation of mutagenic chloroacroleins involves primarily sulfoxidation of diallate followed by sigmatropic rearrangement-1,2-elimination reactions and S-methylene hydroxylation of triallate and sulfallate and then decomposition of their alpha-hydroxy intermediates. Competing glutathione-S-transferase catalyzed conjugations with glutathione divert the sulfoxidized intermediates from activation involving chloroacrolein formation to detoxification on chloroallylthiol liberation.

SYMPTOMS: Symptoms of exposure to this compound may include irritation of the skin and eyes. It can cause erythema. Other symptoms may include headache, weakness, fatigue, central nervous system depression, peripheral neuropathy, toxic psychosis, toxic hepatitis, burns of the mucous membranes and reproductive effects. Exposure to this type of compound may cause impotence. ACUTE/CHRONIC HAZARDS: This compound is moderately toxic by ingestion and skin contact. When heated to decomposition it emits very toxic fumes of chlorine, oxides of nitrogen and oxides of sulfur. (NTP, 1992)

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. IMMEDIATELY call a hospital or poison control center even if no symptoms (such as redness or irritation) develop. IMMEDIATELY transport the victim to a hospital for treatment after washing the affected areas. INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. IMMEDIATELY call a physician and be prepared to transport the victim to a hospital even if no symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing. INGESTION: DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. OTHER: Since this chemical is a known or suspected carcinogen you should contact a physician for advice regarding the possible long term health effects and potential recommendation for medical monitoring. Recommendations from the physician will depend upon the specific compound, its chemical, physical and toxicity properties, the exposure level, length of exposure, and the route of exposure. (NTP, 1992)

/SRP:/ Immediate first aid: Ensure that adequate decontamination has been carried out. If patient is not breathing, start artificial respiration, preferably with a demand valve resuscitator, bag-valve-mask device, or pocket mask, as trained. Perform CPR if necessary. Immediately flush contaminated eyes with gently flowing water. Do not induce vomiting. If vomiting occurs, lean patient forward or place on the left side (head-down position, if possible) to maintain an open airway and prevent aspiration. Keep patient quiet and maintain normal body temperature. Obtain medical attention. /Poisons A and B/|/SRP:/ Basic treatment: Establish a patent airway (oropharyngeal or nasopharyngeal airway, if needed). Suction if necessary. Watch for signs of respiratory insufficiency and assist ventilations if needed. Administer oxygen by nonrebreather mask at 10 to 15 L/min. Monitor for pulmonary edema and treat if necessary ... . Monitor for shock and treat if necessary ... . Anticipate seizures and treat if necessary ... . For eye contamination, flush eyes immediately with water. Irrigate each eye continuously with 0.9% saline (NS) during transport ... . Do not use emetics. For ingestion, rinse mouth and administer 5 mL/kg up to 200 mL of water for dilution if the patient can swallow, has a strong gag reflex, and does not drool ... . Cover skin burns with dry sterile dressings after decontamination ... . /Poisons A and B/|/SRP:/ Advanced treatment: Consider orotracheal or nasotracheal intubation for airway control in the patient who is unconscious, has severe pulmonary edema, or is in severe respiratory distress. Positive-pressure ventilation techniques with a bag valve mask device may be beneficial. Consider drug therapy for pulmonary edema ... . Consider administering a beta agonist such as albuterol for severe bronchospasm ... . Monitor cardiac rhythm and treat arrhythmias as necessary ... . Start IV administration of D5W /SRP: "To keep open", minimal flow rate/. Use 0.9% saline (NS) or lactated Ringer's if signs of hypovolemia are present. For hypotension with signs of hypovolemia, administer fluid cautiously. Watch for signs of fluid overload ... . Treat seizures with diazepam or lorazepam ... . Use proparacaine hydrochloride to assist eye irrigation ... . /Poisons A and B/

/SIGNS AND SYMPTOMS/ Prolonged contact with skin and eyes may cause moderate irritation.

2-chloroallyl diethyldithiocarbamate

AS AN HERBICIDE, ESSENTIALLY 100% FOR VEGETABLES (1978)

Emulsifiable concentrate, granules.

The WHO Recommended Classification of Pesticides by Hazard identifies sulfallate as an active ingredient believed to be obsolete or discontinued for use as a pesticide.|All sulfallate products were discontinued by the manufacturer in the early 1990s.|In 2009, sulfallate was available from eight suppliers worldwide, including seven U.S. suppliers.|Commercial production of sulfallate in the United States was first reported in 1955.|Discontinued by Monsanto Agricultural Co.

Method: EPA-RCA 8270D; Procedure: gas chromatography/mass spectrometry; Analyte: sulfallate; Matrix: solid waste matrices, soils, air sampling media and water; Detection Limit: 10 ug/L.|Product analysis by gas liquid chromatography. Residues may be determined by gas liquid chromatography.|RESIDUE ANALYSIS OF VEGADEX BY GC METHOD APPLICABLE TO BEET TURNIPS, LETTUCE, CABBAGE, BROCCOLI & CHINESE CABBAGE, SENSITIVITY 0.01 PPM.|TECHNICAL SAMPLE DILUTED WITH METHANOL MAY BE DETERMINED WITH UV SPECTROSCOPY.|For more Analytic Laboratory Methods (Complete) data for SULFALLATE (7 total), please visit the HSDB record page.

Fire Hazards -> Carcinogens, Flammable - 2nd degree