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Phenanthridine

Phenanthridine structure

Phenanthridine 

structure
  • CAS No:

    229-87-8

  • Formula:

    C13H9N

  • Chemical Name:

    Phenanthridine

  • Synonyms:

    Phenanthridine;Benzo[c]quinoline;3,4-Benzoquinoline;9-Azaphenanthrene;3,4-Benzoisoquinoline;5-Azaphenanthrene;NSC 338473;NSC 73482;NSC 93336

Description

white to beige powder


Phenanthridine appears as crystalline needles. Mutagenic.


Phenanthridine appears as crystalline needles. Mutagenic.|Phenanthridine is an azaarene that is the 9-aza derivative of phenanthrene. The parent of the class of phenanthridines. It is a mancude organic heterotricyclic parent, a polycyclic heteroarene, a member of phenanthridines and an azaarene.

Phenanthridine Basic Attributes

179.222

179.22

205-934-4

62QGS7CPS6

73482

2811

DTXSID3074288

2933990090

Characteristics

12.9

3.32

Phenanthridine appears as crystalline needles. Mutagenic.

1.2±0.1 g/cm3

107.4 °C

349 °C

155.9±11.9 °C

1.727

0.3g/L(20 ºC)

2.08e-05 mmHg

mic-bac-sat 50 mg/plate 50NNAZ7,73,83

Sparingly soluble in water.

Amines, Phosphines, and Pyridines

PHENANTHRIDINE neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.

Safety Information

UN 2811 6.1/PG 3

3

R40

S26-S39

SF7928000

Xn: Harmful;

P261-P280-P301 + P310-P305 + P351 + P338

H301-H315-H318-H335

Flash point data are not available for this chemical, but is probably combustible. (NTP, 1992)

Fires involving this compound should be controlled by using a dry chemical carbon dioxide, and/or Halon extinguishers. (NTP, 1992)

Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]: As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. SPILL: Increase, in the downwind direction, as necessary, the isolation distance shown above. FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2016)

STORAGE PRECAUTIONS: You should store this material in a refrigerator. (NTP, 1992)

RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)

Drug Information

Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]: TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution. (ERG, 2016)

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment. INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing. INGESTION: DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)

Phenanthridine Use and Manufacturing

Used in the study of ecotoxicity. 1 Used in rotational spectroscopic investigations and radio astronomical searches. 2 Used as a dye in biological and chemical sensors. 3

Computed Properties

Molecular Weight:179.22
XLogP3:3.5
Hydrogen Bond Acceptor Count:1
Exact Mass:179.073499291
Monoisotopic Mass:179.073499291
Topological Polar Surface Area:12.9
Heavy Atom Count:14
Complexity:201
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes

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