Ethylenebis[dithiocarbamic acid]

212.37972

212.38

205-547-0

IO46B19O1Q

3077|2992

DTXSID5043972

Unstable liquid

2930909090

165.84000

1.37680

Nabam is a colorless to light amber solid with a a slight odor. Mixes with water. (USCG, 1999)

1.413g/cm3

Decomposes on heating without melting

308.2ºC at 760mmHg

140.2ºC

In water, 1.14X10+5 mg/L at 25 deg C (est)

7.50X10-8 mm Hg at 20 deg C

Henry's Law constant = 5.6X10-7 atm-cu m/mol at 25 °C (est)

pKa = 5.11 (thiol) (est)

Hydroxyl radical reaction rate constant = 2.12X10-10 cu cm/molec-sec at 25 °C (est)

Thio and dithiocarbamates slowly decompose in aqueous solution to form carbon disulfide and methylamine or other amines. Such decompositions are accelerated by acids.

Thiocarbamate Esters and Salts/Dithiocarbamate Esters and Salts

ETHYLENEBISDITHIOCARBAMIC ACID, SALTS & ESTERS are dithiocarbamic acid derivatives. Flammable gases are generated by the combination of thiocarbamates and dithiocarbamates with aldehydes, nitrides, and hydrides. Thiocarbamates and dithiocarbamates are incompatible with acids, peroxides, and acid halides.

2588

Ethylene bisdithiocarbamates (EBDCs) are generally unstable in the presence of moisture, oxygen, or biological systems, and decompose rapidly in water.

P261, P264, P270, P271, P272, P273, P280, P301+P312, P302+P352, P304+P340, P312, P321, P330, P333+P313, P363, P391, P403+P233, P405, P501

H302

Generators of waste (equal to or greater than 100 kg/mo) containing this contaminant, EPA hazardous waste number U114, must conform with USEPA regulations in storage, transportation, treatment and disposal of waste.|A potential candidate for liquid injection incineration at a temperature range of 650 to 1,600 °C and a residence time of 0.1 to 2 seconds. A potential candidate for rotary kiln incineration at a temperature range of 820 to 1,600 °C and residence times of seconds for liquids and gases, and hours for solids. A potential candidate for fluidized bed incineration at a temperature range of 450 to 980 °C and residence times of seconds for liquids and gases, and longer for solids. /Ethylenebisdithiocarbamate/

WHO; Environmental Health Criteria 78: Dithiocarbamate Pesticides, Ethylenethiourea and Propylenethiourea (1988). EHC documents are designed for scientists and administrators responsible for the establishment of safety standards and regulations and provide basic scientific risk evaluations of a wide range of chemicals and groups of chemicals.[Available from, as of March 4, 2010: http://www.inchem.org/documents/ehc/ehc/ehc78.htm]

Excerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]: Some may burn but none ignite readily. Containers may explode when heated. Some may be transported hot. For UN3508, be aware of possible short circuiting as this product is transported in a charged state. (ERG, 2016)

Excerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]: SMALL FIRE: Dry chemical, CO2, water spray or regular foam. LARGE FIRE: Water spray, fog or regular foam. Do not scatter spilled material with high-pressure water streams. Move containers from fire area if you can do it without risk. Dike fire-control water for later disposal. FIRE INVOLVING TANKS: Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks engulfed in fire. (ERG, 2016)

Excerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]: As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. SPILL: Increase, in the downwind direction, as necessary, the isolation distance shown above. FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2016)

Excerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]: Do not touch or walk through spilled material. Stop leak if you can do it without risk. Prevent dust cloud. Avoid inhalation of asbestos dust. SMALL DRY SPILL: With clean shovel, place material into clean, dry container and cover loosely; move containers from spill area. SMALL SPILL: Pick up with sand or other non-combustible absorbent material and place into containers for later disposal. LARGE SPILL: Dike far ahead of liquid spill for later disposal. Cover powder spill with plastic sheet or tarp to minimize spreading. Prevent entry into waterways, sewers, basements or confined areas. (ERG, 2016)

Excerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]: Wear positive pressure self-contained breathing apparatus (SCBA). Structural firefighters' protective clothing will only provide limited protection. (ERG, 2016)

SRP: Wastewater from contaminant suppression, cleaning of protective clothing/equipment, or contaminated sites should be contained and evaluated for subject chemical or decomposition product concentrations. Concentrations shall be lower than applicable environmental discharge or disposal criteria. Alternatively, pretreatment and/or discharge to a permitted wastewater treatment facility is acceptable only after review by the governing authority and assurance that "pass through" violations will not occur. Due consideration shall be given to remediation worker exposure (inhalation, dermal and ingestion) as well as fate during treatment, transfer and disposal. If it is not practicable to manage the chemical in this fashion, it must be evaluated in accordance with EPA 40 CFR Part 261, specifically Subpart B, in order to determine the appropriate local, state and federal requirements for disposal.

SRP: The scientific literature for the use of contact lenses by industrial workers is inconsistent. The benefits or detrimental effects of wearing contact lenses depend not only upon the substance, but also on factors including the form of the substance, characteristics and duration of the exposure, the uses of other eye protection equipment, and the hygiene of the lenses. However, there may be individual substances whose irritating or corrosive properties are such that the wearing of contact lenses would be harmful to the eye. In those specific cases, contact lenses should not be worn. In any event, the usual eye protection equipment should be worn even when contact lenses are in place.|SRP: Contaminated protective clothing should be segregated in a manner that results in no direct personal contact by personnel who handle, dispose of, or clean the clothing. Quality assurance procedures to confirm the efficacy of the cleaning procedures should be implemented prior to the decontaminated protective clothing being returned for reuse by the workers. Contaminated clothing (including shoes/socks) should not be taken home at end of shift, but should remain at employee's place of work for cleaning.

No person may /transport,/ offer or accept a hazardous material for transportation in commerce unless that person is registered in conformance ... and the hazardous material is properly classed, described, packaged, marked, labeled, and in condition for shipment as required or authorized by ... /the hazardous materials regulations (49 CFR 171-177)./|The International Air Transport Association (IATA) Dangerous Goods Regulations are published by the IATA Dangerous Goods Board pursuant to IATA Resolutions 618 and 619 and constitute a manual of industry carrier regulations to be followed by all IATA Member airlines when transporting hazardous materials.|The International Maritime Dangerous Goods Code lays down basic principles for transporting hazardous chemicals. Detailed recommendations for individual substances and a number of recommendations for good practice are included in the classes dealing with such substances. A general index of technical names has also been compiled. This index should always be consulted when attempting to locate the appropriate procedures to be used when shipping any substance or article.

/Ethylene bis dithiocarbamates/ may cause irritation of the skin, respiratory tract, and eyes. /Ethylene bis dithiocarbamates/

U114; A toxic waste when a discarded commercial chemical product or manufacturing chemical intermediate or an off-specification commercial chemical product or manufacturing chemical intermediate. /Ethylenebisdithiocarbamic acid, salts & esters/

Persons in charge of vessels or facilities are required to notify the National Response Center (NRC) immediately, when there is a release of this designated hazardous substance, in an amount equal to or greater than its reportable quantity of 5000 lb or 2270 kg. The toll free number of the NRC is (800) 424-8802. The rule for determining when notification is required is stated in 40 CFR 302.4 (section IV. D.3.b). /Ethylenebisdithiocarbamic acid, salts & esters/

U114; As stipulated in 40 CFR 261.33, when ethylenebisdithiocarbamic acid, as a commercial chemical product or manufacturing chemical intermediate or an off-specification commercial chemical product or a manufacturing chemical intermediate, becomes a waste, it must be managed according to Federal and/or State hazardous waste regulations. Also defined as a hazardous waste is any residue, contaminated soil, water, or other debris resulting from the cleanup of a spill, into water or on dry land, of this waste. Generators of small quantities of this waste may qualify for partial exclusion from hazardous waste regulations (40 CFR 261.5). /Ethylenebisdithiocarbamic acid, salts & esters/

/BIRDS and MAMMALS/ In birds, paralysis and muscular and peripheral nerve atrophy have ... been observed. /Dithiocarbamates/|/AQUATIC SPECIES/ Dithiocarbamates have an LC50 of less than 1 mg/L for invertebrates (Daphnia) and between 1 and 4 mg/L for algae (Chlorella). The acute toxicity of dithiocarbamates for fish is rather high. In general, the acute LC50 of dialkyldithiocarbamates for fish is less than 1 mg/L, and that of EBDCs is in the range 1-8 mg/L water. The sac fry and early fry stages of the rainbow trout have a higher sensitivity than other early life stages, and embryotoxic and teratogenic effects are induced by certain dithiocarbamates. However, bioaccumulation is low (bioconcentration factor < 100). The toxicity of /ethylenethiourea/ (ETU) and /ethyleneurea/ (EU) for fish, Daphnia, Chlorella, and two bacteria species is very low, of the order of g/L. /Dithiocarbamates/|/AQUATIC SPECIES/ ... The 60-day toxicity for early life stages was tested on S. gairdneri using a number of dialkyldithiocarbamates, EBDCs, and breakdown products. The LC50s ranged from approx 1 to 9 ug/L for dialkyldithiocarbamates and 211-2100 ug/L for EBDCs, but /ethylene thiourea/ (ETU) and /ethyleneurea/ (EU) were not toxic, even at levels exceeding 1000 mg/L.|/AQUATIC SPECIES/ Embryotoxic and teratogenic effects were also observed for all the /dithiocarbamate/ compounds studied, and there was an overlap between the responses for skeletal malformations and lethality over a wide concentration range. The teratogenic effects in rainbow trout proved to be in agreement with those observed in mammals. Exposure of rainbow trout during embryo-larval development revealed that malformations induced by dithiocarbamates were almost exclusively confined to the notochord, which increased considerably in both length and diameter. As a result, the notochord became twisted and distorted. Ectopic osteogenesis was observed in almost every affected notochord. Other effects, such as the disruption of the integrity of myomeres and organ dislocations, were closely related to the notochordal anomalies. Also, compression and fusion of vertebrae and "waviness" of various skeletal elements were found. Concentration-related changes in the liver were observed in short-term exposure of juvenile rainbow trout, while at high levels proliferation of bile duct epithelial cells and necrosis of hepatocytes were seen. /Dithiocarbamates/|/AQUATIC SPECIES/ Short-term toxicity studies using /dithiocarbamate/ compounds ... were carried out to investigate the effects of prolonged exposure (21-day) on survival, fecundity, and growth of Daphnia magna. Growth and reproduction were not specifically inhibited, since effects on these characteristics were generally detected at levels comparable with the 21-day LC50s. For dialkyldithiocarbamates, the 21-day LC50s ranged from approx 10 to 30 ug/L, for EBDCs, from 80 to 110 ug/L, and, for ETU /(ethylenethiourea)/ and EU /(ethyeleneurea)/, the levels were 18 and 3200 mg/L, respectively ... /Dithiocarbamates/

Ethylene bis(dithiocarbamic acid)'s production may result in its release to the environment through various waste streams; its use in the heavy metal salt form as a fungicide(1) will result in the acid's direct release to the environment(SRC).

TERRESTRIAL FATE: Based on a classification scheme(1), an estimated Koc value of 600(SRC), determined from a structure estimation method(2), indicates that ethylene bis(dithiocarbamic acid) is expected to have low mobility in soil(SRC). The estimated pKa of ethylene bis(dithiocarbamic acid) is 5.11(3), indicating that this compound will exist almost entirely in anion form in the environment and anions generally do not adsorb more strongly to soils containing organic carbon and clay than their neutral counterparts(4). Volatilization of ethylene bis(dithiocarbamic acid from moist soil surfaces is not expected to be an important fate process(SRC) given its pKa(3). Ethylene bis(dithiocarbamic acid) is not expected to volatilize from dry soil surfaces(SRC) based upon a vapor pressure of 7.5X10-8 mm Hg(2). No biodegradation data are available(SRC, 2010).|AQUATIC FATE: Based on a classification scheme(1), an estimated Koc value of 600(SRC), determined from a structure estimation method(2), indicates that ethylene bis(dithiocarbamic acid) is expected to adsorb to suspended solids and sediment(SRC). An estimated pKa of 5.11(3) indicates ethylene bis(dithiocarbamic acid) will exist almost entirely in the anion form at pH values of 5 to 9 and therefore volatilization from water surfaces is not expected to be an important fate process(4). According to a classification scheme(5), an estimated BCF of 3(SRC), from its log Kow of -2.7(6) and a regression-derived equation(7), suggests the potential for bioconcentration in aquatic organisms is low(SRC). The hydrolysis half-life of ethylene bis(dithiocarbamic acid) was reported as 69 hours at pH 7(8). No biodegradation data are available(SRC, 2010).|ATMOSPHERIC FATE: According to a model of gas/particle partitioning of semivolatile organic compounds in the atmosphere(1), ethylene bis(dithiocarbamic acid), which has a vapor pressure of 7.5X10-8 mm Hg at 20 °C(2) will exist solely in the particulate phase in the ambient atmosphere. Particulate-phase ethylene bis(dithiocarbamic acid) may be removed from the air by wet or dry deposition(SRC). Ethylene bis(dithiocarbamic acid) contains chromophores that absorb at wavelengths >290 nm(3) and therefore may be susceptible to direct photolysis by sunlight(SRC).

The rate constant for the vapor-phase reaction of ethylene bis(dithiocarbamic acid) with photochemically-produced hydroxyl radicals has been estimated as 2.1X10-10 cu cm/molecule-sec at 25 °C(SRC) using a structure estimation method(1). This corresponds to an atmospheric half-life of about 2 hours at an atmospheric concentration of 5X10+5 hydroxyl radicals per cu cm(1). The hydrolysis half-life of ethylene bis(dithiocarbamic acid) was reported as 69 hours at pH 7(2). Ethylene bis(dithiocarbamic acid) contains chromophores that absorb at wavelengths >290 nm(3) and therefore may be susceptible to direct photolysis by sunlight(SRC).

An estimated BCF of 3 was calculated in fish for ethylene bis(dithiocarbamic acid)(SRC), using a log Kow of -2.7(1) and a regression-derived equation(2). According to a classification scheme(3), this BCF suggests the potential for bioconcentration in aquatic organisms is low(SRC).

549.54 L/kg|Using a structure estimation method based on molecular connectivity indices(1), the Koc of ethylene bis(dithiocarbamic acid) can be estimated to be 600(SRC). According to a classification scheme(2), this estimated Koc value suggests that ethylene bis(dithiocarbamic acid) is expected to have low mobility in soil.

An estimated pKa of 5.11(1) indicates ethylene bis(dithiocarbamic acid) will exist almost entirely in the anion form at pH values of 5 to 9 and therefore volatilization from water surfaces and moist soil is not expected to be an important fate process(2). Ethylene bis(dithiocarbamic acid) is not expected to volatilize from dry soil surfaces(SRC) based upon a vapor pressure of 7.5X10-8 mm Hg(3).

Ethylene bis(dithiocarbamic acid) was detected in 10 domestic food products in the US at a max concn of 3 ppm(1). In 282 samples of 22 food commodities, 0.7-4.8 ppm of ethylene bis(dithiocarbamic acid) were detected(2).

Occupational exposure to ethylene bis(dithiocarbamic acid) may occur through inhalation and dermal contact with this compound at workplaces where ethylene bis(dithiocarbamic acid) is produced or used. Monitoring data indicate that the general population may be exposed to ethylene bis(dithiocarbamic acid) via ingestion of food containing residual fungicide. (SRC)

Dithiocarbamates have ... been used to control various dermatophytes ... For example, tetramethylthiuram disulfide, incorporated in various soaps and lotions, has been used since 1942 for the treatment of scabies and other parasitic diseases of the skin in veterinary and human medicine ... Dithiocarbamates also have considerable biocidal activity against a number of protozoa. /Dithiocarbamates/

As a general rule, dithiocarbamates can be absorbed by the organism via the skin, mucous membranes, and the respiratory and gastrointestinal tracts. /Dithiocarbamates/

Dithiocarbamates may decompose under certain circumstances into a number of compounds, such as sulfur, 5,6-dihydro-3 H-imidazol [2,1-C]-1,2,4-dithiazole-3-thione, ethylenethiourea (ETU), and ethylenediamine (EDA). ETU is fairly stable, has a high water solubility, and is of particular importance because of its specific toxicity. /Dithiocarbamates/|The metabolic decomposition of EBDCs in mammals is complex and results in the formation of carbon disulfide, /ethylene diamine/ (EDA), a few ethylene bisthiuram disulfides, hydrogen sulfide, ethylene bisthiocyanate, and /ethylene thiourea/ (ETU). The latter is further broken down to moieties that are incorporated into compounds such as oxalic acid, glycine, urea, and lactose. Dithiocarbamates and their metabolic products are found in certain organs, such as the liver, kidneys, and, especially, the thyroid gland, but accumulation of these compounds does not take place because of their rapid metabolism. After treating plants with dithiocarbamates, a large number of metabolites are found, including ETU, /ethylene urea/ (EU), imidazole derivatives, diisothiocyanates, diamines, disulfides, and other metabolites, that are still unknown. /Dithiocarbamates/

Ethylenethiourea contents of ethylenebisdithiocarbamate formulations (carcinogenic and teratogenic fungicides) were determined by reversed phase chromatography. The method was simple, rapid (25 min) and allowed control of analysis time to minimize ethylenethiourea formation from intermediary degradation products in soln. Analyzed products contained less than 0.2% ethylenethiourea except for greater than 3 yr old formulations. /Ethylenebisdithiocarbamate formulations/

Excerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]: Inhalation of material may be harmful. Contact may cause burns to skin and eyes. Inhalation of Asbestos dust may have a damaging effect on the lungs. Fire may produce irritating, corrosive and/or toxic gases. Some liquids produce vapors that may cause dizziness or suffocation. Runoff from fire control may cause pollution. (ERG, 2016)

Excerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]: Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Move victim to fresh air. Call 911 or emergency medical service. Give artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult. Remove and isolate contaminated clothing and shoes. In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes. (ERG, 2016)

/SRP:/ Immediate first aid: Remove patient from contact with the material. Ensure that adequate decontamination has been carried out. If patient is not breathing, start artificial respiration, preferably with a demand-valve resuscitator, bag-valve-mask device, or pocket mask, as trained. Perform CPR as necessary. Immediately flush contaminated eyes with gently flowing water. Do not induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain an open airway and prevent aspiration. Keep patient quiet and maintain normal body temperature. Obtain medical attention. /Dithiocarbamates and Related Compounds/|/SRP:/ Basic treatment: Establish a patent airway (oropharyngeal or nasopharyngeal airway, if needed). Suction if necessary. Watch for signs of respiratory insufficiency and assist ventilations if necessary. Administer oxygen by nonrebreather mask at 10 to 15 L/min. Monitor for shock and treat if necessary ... . Anticipate seizures and treat if necessary ... . For eye contamination, flush eyes immediately with water. Irrigate each eye continuously with 0.9% saline (NS) during transport ... . Do not use emetics. For ingestion, rinse mouth and administer 5 ml/kg up to 200 ml of water for dilution if the patient can swallow, has a strong gag reflex, and does not drool. Administer activated charcoal ... . /Dithiocarbamates and Related Compounds/|/SRP:/ Advanced treatment: Consider orotracheal or nasotracheal intubation for airway control in the patient who is unconscious or is in severe respiratory distress. Use moderate hyperventilation (rate of 20 respirations per minute) if signs of cerebral edema are present. Monitor cardiac rhythm and treat arrhythmias if necessary ... . Start IV administration of D5W /SRP: "To keep open", minimal flow rate/. Use 0.9% saline (NS) or lactated Ringer's (LR) if signs of hypovolemia are present. For hypotension with signs of hypovolemia, administer fluid cautiously. Consider vasopressors if patient is hypotensive with a normal fluid volume. Watch for signs of fluid overload ... . Treat seizures with diazepam or lorazepam ... . Use proparacaine hydrochloride to assist eye irrigation ... . /Dithiocarbamates and Related Compounds/|Gastrointestinal decontamination. If a large amount of the fungicide has been ingested in the last few hours, and if copious vomiting has not already occurred, it may be reasonable to consider GI decontamination. Activated charcoal can be used along with the addition of the cathartic sorbitol to the charcoal slurry. If sorbitol is given separately, it should be diluted with an equal volume of water before administration. No more than one dose of sorbitol is recommended and it should be used with caution in children and the elderly. If contact with the toxicant has been minimal (for example, oral contamination only, promptly flushed out of the mouth), administration of charcoal without a cathartic, followed by careful observation of the patient, probably represents optimal management. /Ethylene bis dithiocarbamates (EBDC compounds)/|For more Antidote and Emergency Treatment (Complete) data for Ethylenebisdithiocarbamic acid (6 total), please visit the HSDB record page.

/SIGNS AND SYMPTOMS/ Local irritation of the respiratory tract occurs when dithiocarbamates are inhaled as dust, which can also induce eye and dermal irritation. /Dithiocarbamates/|/SIGNS AND SYMPTOMS/ Regular contact with dithiocarbamates can cause functional changes in the nervous and hepatobiliary systems. Skin contact with dithiocarbamates may induce contact dermatitis, and some of these compounds will induce sensitization. /Dithiocarbamates/|/EPIDEMIOLOGY STUDIES/ Epidemiological studies on workers exposed to dithiocarbamates or ETU did not show any increase in the incidence of thyroid tumors. However, only a relatively small number of workers was involved. /Dithiocarbamates/|/GENOTOXICITY/ There are indications that the mean incidence of chromosomal aberrations in lymphocytes is increased in workers exposed to certain dithiocarbamates. /Dithiocarbamates/

The WHO Recommended Classification of Pesticides by Hazard identifies Ethylenebisdithiocarbamic acid (technical grade) as Class III: slightly hazardous; Main Use: fungicide.|A 4 min preprocessing wash with diluted alkaline hydrochlorite followed by a 30 sec dip into diluted sodium sulfite reduced field residues of ethylenebis(dithiocarbamate) and ethylenethiourea on green beans and tomatoes to the limits of analytical significance. Subsequent processing of the washed tomatoes into juice did not raise levels of ethylenethiourea; boiling unwashed green beans resulted in significant ethylenethiourea residues on the beans and in the cooking water.|Nabam is disodium salt; Maneb is manganese salt; Zineb is zinc salt.

A number of procedures for the quantification of dithiocarbamates are based on high-pressure liquid chromatography. The limits of detection in water solutions for zineb, ziram, and thiram are 0.05, 0.01, and 0.01 mg/kg, respectively. /Dithiocarbamates/|TWENTY EIGHT ETHYLENEBISDITHIOCARBAMATE COMMERCIAL FORMULATIONS CONSISTING OF ZINEB, MANEB, FERBAM, THIURAM, AS WELL AS COORDINATING PRODUCTS OF MANGANESE (+2) AND ZINC (+2) WITH ETHYLENEBISDITHIOCARBAMATE ION, WERE ANALYZED FOR ETHYLENEBISTHIOUREA, A DEGRADATION PRODUCT OF ETHYLENEBISDITHIOCARBAMATE. ALL PRODUCTS EXCEPT FOR FERBAM & THIURAM FORMULATIONS CONTAINED ETHYLENETHIOUREA, WHICH WAS IDENTIFIED BY THIN LAYER & GAS LIQ CHROMATOGRAPHY, & INFRARED & MASS SPECTROPHOTOMETRY. COORDINATION PRODUCTS CONTAINED SIGNIFICANTLY LOWER AMT OF ETHYLENETHIOUREA THAN ZINEB & MANEB PREPN. /ETHYLENEBISDITHIOCARBAMATE FORMULATIONS/|ANALYSIS OF RESIDUES OF DEGRADATION PRODUCTS OF ETHYLENE BIS DITHIO CARBAMATES.|EPA Method 630. Analysis of a carbamate including ethylenebisdithiocarbamic acid, salts and esters in wastewater. The method detection limit is 1.6 ug/l as determined by EPA Office of Water's Industrial Technology Division.

LIQ CHROMATOGRAPHY WITH ULTRAVIOLET ABSORBANCE AND POLAROGRAPHIC DETECTION OF ETHYLENE THIO UREA AND RELATED SULFUR COMPOUNDS APPLICATION TO RAT URINE ANALYSIS. /ETHYLENE THIOUREA/

Environmental transformation -> Pesticides (parent, predecessor)

Mancozeb has known environmental transformation products that include ethylene bisisothiocyanate sulphide, ethylenethiourea, and ethyleneurea.