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Glycol monohexyl ether

Glycol monohexyl ether structure

CAS No:
112-25-4
Formula:
C8H18O2
Chemical Name:
Glycol monohexyl ether
Synonyms:
Ethanol,2-(hexyloxy)-;2-(Hexyloxy)ethanol;Ethylene glycol n-hexyl ether;Ethylene glycol monohexyl ether;Glycol monohexyl ether;n-Hexyl Cellosolve;Hexyl cellosolve;3-Oxa-1-nonanol;Ethylene glycol mono-n-hexyl ether;Ethylene glycol hexyl ether;Hexyl glycol;2-(Hexyloxy)ethan-1-ol
Categories:
Cosmetic Ingredient > Dissolving Agent

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Description

Colorless liquid

Liquid|COLOURLESS LIQUID WITH CHARACTERISTIC ODOUR.

Glycol monohexyl ether Basic Attributes

Molecular Weight：

146.23

Exact Mass：

146.23

EC Number：

500-077-5

UNII：

7P0O8282NR

ICSC Number：

1571

DSSTox ID：

DTXSID1026908

Color/Form：

WATER-WHITE LIQ

HScode：

29091990

Characteristics

PSA：

29.46000

XLogP3：

1.86

Appearance：

Liquid

Density：

0.8894 g/cm³ @ Temp: 20 °C

Melting Point：

-45.1 °C

Boiling Point：

208 °C @ Press: 760 Torr

Flash Point：

98-99°C/0.15mm

Refractive Index：

n 20/D 1.431

Water Solubility：

soluble in alcohol and ether, water (9.46 g/L ).

Vapor Pressure：

0.05 MM HG @ 20 DEG C

Explosive limit：

Explosive limits , vol% in air: 1.2-8.1

Experimental Properties：

7.4 LB/GAL @ 20 °C|1 PPM IS EQUIV TO 5.98 MG/CU M; 1 MG/L IS EQUIV TO 168 PPM @ 25 °C, 760 MM HG

Autoignition Temperature：

220 °C

Physical Dangers：

The vapour is heavier than air.

Safety Information

Packing level：

III

Hazard category：

6.1

Transport codes：

UN 2922 8/PG 3

wgk germany：

hazard class code：

R21/22

safety instructions：

26-36/37/39-45

RTECS Number：

KL2450000

Marks：

Storage features：

Separated from strong oxidants.

Precautionary statement(s)：

P280-P305 + P351 + P338-P310

Hazard Statements：

H302-H311-H314

Fire Hazards：

Combustible. Above 81.7 °C explosive vapour/air mixtures may be formed.

GHS Classification：

|Danger|H302: Harmful if swallowed [Warning Acute toxicity, oral]|P260, P264, P270, P280, P301+P312, P301+P330+P331, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P310, P312, P321, P322, P330, P363, P405, and P501|H302 (99.76%): Harmful if swallowed [Warning Acute toxicity, oral]|P260, P264, P270, P280, P301+P312, P301+P330+P331, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P310, P312, P321, P322, P330, P361, P363, P405, and P501|Aggregated GHS information provided by 418 companies from 9 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.|H302 (78.52%): Harmful if swallowed [Warning Acute toxicity, oral]|P264, P270, P280, P301+P312, P302+P352, P305+P351+P338, P310, P321, P330, P332+P313, P337+P313, P362, and P501|Aggregated GHS information provided by 256 companies from 8 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.|Warning|H315: Causes skin irritation [Warning Skin corrosion/irritation]|P264, P280, P302+P352, P305+P351+P338, P321, P332+P313, P337+P313, and P362

Fire Fighting：

Use water spray, powder, foam, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water.

Explosive Limits and Potential：

Explosive limits , vol% in air: 1.2-8.1

Spillage Disposal：

Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Ventilation. Collect leaking and spilled liquid in sealable containers as far as possible.

Safe Storage：

Separated from strong oxidants.

Inhalation Risk：

No indication can be given about the rate at which a harmful concentration of this substance in the air is reached on evaporation at 20 °C.

Effects of Short Term Exposure：

The substance is severely irritating to the eyes, skin and respiratory tract.

Effects of Long Term Exposure：

The substance may have effects on the blood.

Fire Prevention：

NO open flames. Above 81.7 °C use a closed system and ventilation.

Exposure Prevention：

STRICT HYGIENE!

Inhalation Prevention：

Use ventilation, local exhaust or breathing protection.

Skin Prevention：

Protective gloves. Protective clothing.

Eye Prevention：

Wear safety goggles.

Toxicity

Human Exposure：

...ETHYLENE GLYCOL-N-MONOHEXYL ETHER SHOULD BE HANDLED WITH GREAT CARE TO PREVENT EYE CONTACT & TO AVOID SKIN CONTACT BECAUSE OF ITS TOXICITY BY ABSORPTION. UNTIL MORE IS KNOWN IT WOULD SEEM WISE ALSO TO AVOID REPEATED EXPOSURE TO ITS VAPORS.

Drug Information

Reported Fatal Dose：

3. 3= MODERATELY TOXIC: PROBABLE ORAL LETHAL DOSE (HUMAN) 0.5-5 G/KG, BETWEEN 1 OZ AND 1 PINT (OR 1 LB) FOR 70 KG PERSON (150 LB). /CELLOSOLVES/

Absorption：

THESE ETHERS PENETRATE INTACT SKIN. /CELLOSOLVES/

First Aid：

Fresh air, rest. Refer for medical attention.

Remove contaminated clothes. Rinse skin with plenty of water or shower.

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

Human Toxicity Excerpts：

CENTRAL NERVOUS DEPRESSION AS WITH ETHYLENE GLYCOL, BUT THE ETHER DERIVATIVES PRODUCE MORE MARKED KIDNEY INJURY & HEMATURIA (APPARENTLY WITHOUT OXALIC ACID FORMATION OR CRYSTALLURIA). /CELLOSOLVES/|ACUTE TOXICITIES ARE SEVERAL TIMES GREATER THAN THAT OF ETHYLENE GLYCOL IN ANIMALS (CLINICAL DATA ARE INADEQUATE FOR VALID COMPARISONS). ETHER LINKAGE IS SUPPOSEDLY STABLE IN VIVO. /CELLOSOLVES/

MeSH Entry Terms：

EGHE

Exposure Routes：

The substance can be absorbed into the body by inhalation of its aerosol, through the skin and by ingestion.

Symptoms：

Cough. Sore throat. Burning sensation. Shortness of breath.

MAY BE ABSORBED! Redness. Pain.

Redness. Pain.

Glycol monohexyl ether Use and Manufacturing

Methods of Manufacturing

REACTION OF ETHYLENE OXIDE WITH 1-HEXANOL (PRODUCT IS ISOLATED FROM THE REACTION MIXT BY VACUUM DISTILLATION)

Uses

High-boiling solvent.

Solvents (which become part of product formulation or mixture)

Cleaning and furnishing care products

Production

10,000,000 - 50,000,000 lb|(1979) No Data|(1981) No Data

Manufacturing Info：

All other basic organic chemical manufacturing|Ethanol, 2-(hexyloxy)-: ACTIVE

Use Classification：

EPA Safer Chemical Functional Use Classes -> Surfactants|Safer Chemical Classes -> Green circle - The chemical has been verified to be of low concern

Computed Properties

Molecular Weight:146.23
XLogP3:1.9
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:7
Exact Mass:146.130679813
Monoisotopic Mass:146.130679813
Topological Polar Surface Area:29.5
Heavy Atom Count:10
Complexity:55.2
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes

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Guide of Glycol monohexyl ether

Description
Basic Attributes
Characteristics
Safety Information
Toxicity
Drug Information
Use and Manufacturing
Computed Properties
Recommended Suppliers
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Glycol monohexyl ether

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