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Home > Encyclopedia > Benzoic acid, 5-[2-[4′-[2-(7-amino-1-hydroxy-3-sulfo-2-naphthalenyl)diazenyl][1,1′-biphenyl]-4-yl]diazenyl]-2-hydroxy-, sodium salt (1:2)

Benzoic acid, 5-[2-[4′-[2-(7-amino-1-hydroxy-3-sulfo-2-naphthalenyl)diazenyl][1,1′-biphenyl]-4-yl]diazenyl]-2-hydroxy-, sodium salt (1:2)

Benzoic acid, 5-[2-[4′-[2-(7-amino-1-hydroxy-3-sulfo-2-naphthalenyl)diazenyl][1,1′-biphenyl]-4-yl]diazenyl]-2-hydroxy-, sodium salt (1:2) structure

Benzoic acid, 5-[2-[4′-[2-(7-amino-1-hydroxy-3-sulfo-2-naphthalenyl)diazenyl][1,1′-biphenyl]-4-yl]diazenyl]-2-hydroxy-, sodium salt (1:2) 

structure
  • CAS No:

    2429-82-5

  • Formula:

    C29H21N5O7S.2Na

  • Chemical Name:

    Benzoic acid, 5-[2-[4′-[2-(7-amino-1-hydroxy-3-sulfo-2-naphthalenyl)diazenyl][1,1′-biphenyl]-4-yl]diazenyl]-2-hydroxy-, sodium salt (1:2)

  • Synonyms:

    Benzoic acid,5-[2-[4′-[2-(7-amino-1-hydroxy-3-sulfo-2-naphthalenyl)diazenyl][1,1′-biphenyl]-4-yl]diazenyl]-2-hydroxy-,sodium salt (1:2);C.I. Direct Brown 2,disodium salt;C.I. Direct Brown 2;Direct Brown M;Benzoic acid,5-[[4′-[(7-amino-1-hydroxy-3-sulfo-2-naphthalenyl)azo][1,1′-biphenyl]-4-yl]azo]-2-hydroxy-,disodium salt;C.I. 22311;Airedale Brown MD;Aizen Direct Brown MH;Amanil Brown MR;Atlantic Brown M;Atul Direct Brown MR;Atul Direct Brown MY;Azine Brown M;Azocard Brown M;Azomine Brown M;Belamine Fast Brown M;Bencidal Fast Brown M;Benzanil Brown M;Benzanol Brown M;Benzo Brown M;Benzo Brown MC;Brasilamina Fast Brown 3RA;Brown M;Calcomine Brown MCW;Chloramine Brown M;Chloramine Brown 2ME;Chloramine Brown 2R;Chloramine Brown MR;Chlorazol Brown M;Chlorazol Brown MP;Chrome Leather Brown M;Columbia Brown M;Cresotine Brown RC;Cutamin Brown CM;Diacotton Brown M;Diamine Brown M;Diamine Brown MBA-CF;Diamine Brown MR;Diamine Brown MRC;Diaphtamine Brown M;Diazine Brown M;Diazine Brown MWR;Diazo Brown MC;Diazol Brown M;Diphenyl Brown V;Diphenyl Brown BVV;Diphenyl Brown 3RB;Diphenyl Fast Brown M;Diphenyl Fast Brown MD;Direct Brown 3RB;Direct Brown MB;Direct Brown MR;Direct Brown RC;Direct Brown RMR;Direct Fast Brown M;Direct Fast Brown MM;Direct Fast Brown V;Direct Fast Brown VR;Enianil Fast Brown M;Erie Fast Brown 3RB;Erie Fast Brown 3RBD;Fenamin Brown M;Fixanol Brown M;1092061-31-8

  • Categories:

    Dyes and Pigments  >  Dye

Description

reddish-brown powder


Reddish-brown solid or dark brown powder. (NTP, 1992)


Reddish-brown solid or dark brown powder. (NTP, 1992)

Benzoic acid, 5-[2-[4′-[2-(7-amino-1-hydroxy-3-sulfo-2-naphthalenyl)diazenyl][1,1′-biphenyl]-4-yl]diazenyl]-2-hydroxy-, sodium salt (1:2) Basic Attributes

627.53

627.080078

219-391-6

35C7Y2E3X5

DTXSID6025199

Characteristics

221.63000

7.26060

Reddish-brown solid or dark brown powder. (NTP, 1992)

1.54g/cm3

1.733

1 to 10 mg/mL at 68° F (NTP, 1992)

Azo dyes can be explosive when suspended in air at specific concentrations. Slightly soluble in water.

Azo, Diazo, Azido, Hydrazine, and Azide Compounds

Explosive

DIRECT BROWN 2 is an azo compound. Azo, diazo, azido compounds can detonate. This applies in particular to organic azides that have been sensitized by the addition of metal salts or strong acids. Toxic gases are formed by mixing materials of this class with acids, aldehydes, amides, carbamates, cyanides, inorganic fluorides, halogenated organics, isocyanates, ketones, metals, nitrides, peroxides, phenols, epoxides, acyl halides, and strong oxidizing or reducing agents. Flammable gases are formed by mixing materials in this group with alkali metals. Explosive combination can occur with strong oxidizing agents, metal salts, peroxides, and sulfides.

Safety Information

DM2800435

Stable. Incompatible with strong oxidizing agents.

Flash point data for this chemical are not available, however, it is probably combustible. (NTP, 1992)

|Danger|H302 (100%): Harmful if swallowed [Warning Acute toxicity, oral]|P201, P202, P264, P270, P273, P281, P301+P312, P308+P313, P330, P391, P405, and P501|Aggregated GHS information provided by 38 companies from 1 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.|H350: May cause cancer [Danger Carcinogenicity]|P201, P202, P281, P308+P313, P405, and P501

Fires involving this compound can be controlled with a dry chemical, carbon dioxide or Halon extinguisher. (NTP, 1992)

SMALL SPILLS AND LEAKAGE: If you spill this chemical, you should dampen the solid spill material with water, then transfer the dampened material to a suitable container. Use absorbent paper dampened with water to pick up any remaining material. Seal your contaminated clothing and the absorbent paper in a vapor-tight plastic bag for eventual disposal. Wash all contaminated surfaces with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned. STORAGE PRECAUTIONS: You should store this material in a refrigerator. (NTP, 1992)

RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)

Drug Information

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment. INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing. INGESTION: DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)

direct brown KX

Benzoic acid, 5-[2-[4′-[2-(7-amino-1-hydroxy-3-sulfo-2-naphthalenyl)diazenyl][1,1′-biphenyl]-4-yl]diazenyl]-2-hydroxy-, sodium salt (1:2) Use and Manufacturing

Methods of Manufacturing

COUPLING OF TETRAZOTIZED BENZIDINE WITH SALICYCLIC ACID, THEN COUPLING WITH GAMMA ACID UNDER ALKALINE CONDITIONS

Uses

Mainly used for dyeing cotton, hemp, viscose and other fabrics, but also for dyeing silk, nylon, pulp, leather

Production

(1978) 1.26X10+7 GRAMS|(1979) PROBABLY GREATER THAN 2.27X10+6 GRAMS

ESSENTIALLY 100% AS A DYE

Benzoic acid, 5-[2-[4'-[2-(7-amino-1-hydroxy-3-sulfo-2-naphthalenyl)diazenyl][1,1'-biphenyl]-4-yl]diazenyl]-2-hydroxy-, sodium salt (1:2): INACTIVE|S - indicates a substance that is identified in a final Significant New Use Rule.|SOL DYE TAKEN UP DIRECTLY BY FIBERS, PRESUMABLY DUE TO SELECTIVE ADSORPTION. USUALLY APPLIED TO COTTON OR...(COTTON-WOOL MIXT). DYING ASSISTANTS...SODIUM CHLORIDE OR SODIUM SULFATE ARE USED TO OBTAIN HIGHER CONCN OF DYE ON FIBERS. /DIRECT DYE/

Computed Properties

Molecular Weight:627.5
Hydrogen Bond Donor Count:3
Hydrogen Bond Acceptor Count:12
Rotatable Bond Count:5
Exact Mass:627.08005770
Monoisotopic Mass:627.08005770
Topological Polar Surface Area:222
Heavy Atom Count:44
Complexity:1070
Covalently-Bonded Unit Count:3
Compound Is Canonicalized:Yes

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