2,3,4-Trichloro-1-butene

159.44100

159.44

219-397-9

0587

2322

DTXSID6027474

2903299090

0

2.58510

COLOURLESS LIQUID.

1.3430 g/cm³ @ Temp: 20 °C

-52°C

60 °C @ Press: 20 Torr

91.7ºC

1.47

Solubility in water, g/100ml at 20°C: 0.06

1.88 mmHg

LD50 orl-rat: 341 mg/kg GISAAA 46(1),92,81

II

6.1(a)

UN 2322

22-23-36/37/38-40-50/53

36/37-45-60-61

EM9046000

T: Toxic;N: Dangerous for the environment;

Provision to contain effluent from fire extinguishing. Separated from incompatible materials. See Chemical Dangers. Well closed.

P201, P202, P261, P264, P270, P271, P273, P280, P281, P301+P312, P302+P352, P304+P340, P305+P351+P338, P308+P313, P311, P312, P321, P330, P332+P313, P337+P313, P362, P391, P403+P233, P405, P501

H302

Combustible. Gives off irritating or toxic fumes (or gases) in a fire. Above 63 °C explosive vapour/air mixtures may be formed.

|Danger|H302: Harmful if swallowed [Warning Acute toxicity, oral]|P201, P202, P261, P264, P270, P271, P273, P280, P281, P301+P312, P302+P352, P304+P340, P305+P351+P338, P308+P313, P311, P312, P321, P330, P332+P313, P337+P313, P362, P391, P403+P233, P405, and P501|H302 (100%): Harmful if swallowed [Warning Acute toxicity, oral]|Aggregated GHS information provided by 36 companies from 2 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.|H227: Combustible liquid [Warning Flammable liquids]|P201, P202, P210, P260, P261, P264, P270, P271, P280, P281, P284, P301+P312, P302+P352, P304+P340, P305+P351+P338, P308+P313, P310, P312, P314, P320, P321, P330, P332+P313, P337+P313, P362, P370+P378, P403+P233, P403+P235, P405, and P501

Use water spray, powder, foam, carbon dioxide.

/GUIDE 152: SUBSTANCES - TOXIC (COMBUSTIBLE)/ Health: Highly toxic, may be fatal if inhaled, swallowed or absorbed through skin. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution. /Trichlorobutene/|/GUIDE 152: SUBSTANCES - TOXIC (COMBUSTIBLE)/ Fire or Explosion: Combustible material: may burn but does not ignite readily. Containers may explode when heated. Runoff may pollute waterways. Substance may be transported in a molten form. /Trichlorobutene/|/GUIDE 152: SUBSTANCES - TOXIC (COMBUSTIBLE)/ Public Safety: CALL Emergency Response Telephone Number ... . As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. Keep unauthorized personnel away. Stay upwind. Keep out of low areas. /Trichlorobutene/|/GUIDE 152: SUBSTANCES - TOXIC (COMBUSTIBLE)/ Protective Clothing: Wear positive pressure self-contained breathing apparatus (SCBA). Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct contact with the substance is possible. /Trichlorobutene/|For more DOT Emergency Guidelines (Complete) data for 2,3,4-TRICHLORO-1-BUTENE (8 total), please visit the HSDB record page.

No person may /transport,/ offer or accept a hazardous material for transportation in commerce unless that person is registered in conformance ... and the hazardous material is properly classed, described, packaged, marked, labeled, and in condition for shipment as required or authorized by ... /the hazardous materials regulations (49 CFR 171-177)./|The International Maritime Dangerous Goods Code lays down basic principles for transporting hazardous chemicals. Detailed recommendations for individual substances and a number of recommendations for good practice are included in the classes dealing with such substances. A general index of technical names has also been compiled. This index should always be consulted when attempting to locate the appropriate procedures to be used when shipping any substance or article.

Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Remove all ignition sources. Do NOT let this chemical enter the environment. Cover the spilled material with plastic sheet. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.

Provision to contain effluent from fire extinguishing. Separated from incompatible materials. See Chemical Dangers. Well closed.

A harmful contamination of the air can be reached very quickly on evaporation of this substance at 20 °C.

The vapour is irritating to the eyes, skin and respiratory tract.

The substance may have effects on the respiratory tract. This may result in tissue lesions.

NO open flames. Above 63 °C use a closed system, ventilation and explosion-proof electrical equipment.

AVOID ALL CONTACT!

Use closed system.

Protective gloves. Protective clothing.

Wear face shield or eye protection in combination with breathing protection.

Fresh air, rest. Refer for medical attention.

Rinse skin with plenty of water or shower.

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

2,3,4-trichloro-1-butene

The substance can be absorbed into the body by inhalation of its vapour and by ingestion.

Cough. Sore throat. Lethargy. Nausea.

Redness. Pain.

Redness. Pain.

1-Butene, 2,3,4-trichloro-: ACTIVE