2,4,6-Trimethyl-1,3-phenylenediamine
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2,4,6-Trimethyl-1,3-phenylenediamine
structure -
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CAS No:
3102-70-3
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Formula:
C9H14N2
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Chemical Name:
2,4,6-Trimethyl-1,3-phenylenediamine
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Synonyms:
1,3-Benzenediamine,2,4,6-trimethyl-;2,4-Mesitylenediamine;2,4,6-Trimethyl-1,3-benzenediamine;2,4,6-Trimethyl-m-phenylenediamine;1,3,5-Trimethyl-2,6-benzenediamine;2,4,6-Trimethyl-1,3-phenylenediamine;NSC 10392;1,3-Diamino-2,4,6-trimethylbenzene;2,4-Diaminomesitylene;858865-47-1;159549-85-6
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CAS No:
2,4,6-Trimethyl-1,3-phenylenediamine Basic Attributes
150.22
150.22
221-456-9
9K3JRF5932
10392
DTXSID40184994
2921519090
Safety Information
II
6.1(a)
2811
3
20/21/22-36/37/38
26-36
CZ1607000
Xn
P261-P280-P305 + P351 + P338
H302 + H312 + H332-H315-H319-H335
|Warning|H302 (100%): Harmful if swallowed [Warning Acute toxicity, oral]|P261, P264, P270, P271, P280, P301+P312, P302+P352, P304+P312, P304+P340, P305+P351+P338, P312, P321, P322, P330, P332+P313, P337+P313, P362, P363, P403+P233, P405, and P501|Aggregated GHS information provided by 43 companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
2,4,6-Trimethyl-1,3-phenylenediamine Use and Manufacturing
In a 1000 L coil-cooled nitration kettle, 114 kg of mesitylene was added and the mixture was stirred and mixed with the acid700 kg (mixed acid is H2SO4 and HNO3 mixed acid, H2SO4 and HNO3 weight ratio of 75:25)The reaction temperature was controlled at 20 ° C, the dropping was continued for 35 minutes, the temperature was raised to 90 ° C, maintained for 35 minutes, Layer, waste acid to apply the next batch of nitrification. The organic layer was charged with 500 kg of water and 2 kg of a caustic soda, and the mixture was stirred for 1 hourStanding layered, then add 500kg of water, washed 2, 4, 6-trimethyl-m-dinitrobenzene.The above-mentioned 2, 4, 6-trimethyl-m-dinitrobenzene was added to a 1000 L-liter autoclave followed by Ni-catalysis10 kg of methanol and 320 kg of methanol, and the mixture was replaced with nitrogen and hydrogen. Open to 65 ° C stirring, start hydrogenation, controlHydrogenation pressure of 4MPa, temperature of 80 , the end of hydrogenation for 1 hour, hydrogen discharge, discharge, remove methanol, Cooling crystallization, filtered to 2, 4, 6-trimethyl-m-phenylenediamine, was dried to 135kg, purity of 99.7percentYield 94.7percent.
2,4,6-Trimethyl-1,3-benzenediamine is a compound used in the synthesis of various polymers.
Computed Properties
Molecular Weight:150.22
XLogP3:1.7
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:2
Exact Mass:150.115698455
Monoisotopic Mass:150.115698455
Topological Polar Surface Area:52
Heavy Atom Count:11
Complexity:122
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes
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2,4,6-Trimethyl-1,3-phenylenediamine
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