Dicyclohexyl carbonate

Into a SUS316 tube reactor (volume: 8 ml; outer diameter: 12.7 mm; wall thickness: 2.1 mm) equipped with a SUS316 conduit and a valve were charged 0.86 g of the above-obtained liquid containing an organometal compound, 1.0 g of cyclohexanol and a SUS316 ball (which was for use in stirring the contents of the reactor). The inside of the reactor was cooled to about -68 °C with a dry ice/ethanol mixture. Then, from a carbon dioxide gas bomb, 2.0 g of a high purity carbon dioxide gas, the pressure of which was lowered to about 2 MPa by means of a pressure regulator connected to the carbon dioxide gas bomb, was gently introduced into the reactor. The reactor was placed in an oil bath which was maintained at 130 °C, and shaken for 14 hours. After that period, the inside of the reactor was cooled to 20 °C, and the internal pressure of the reactor was returned to atmospheric pressure by gently purging an excess amount of the carbon dioxide gas, thereby obtaining a transparent reaction mixture. The obtained transparent reaction mixture was analyzed. As a result, it was found that dicyclohexyl carbonate was obtained in a yield of 40 percent.Example 18: Synthesis of dicyclohexyl carbonate from cyclohexanol, C0

Molecular Weight:226.31
XLogP3:4.1
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:4
Exact Mass:226.15689456
Monoisotopic Mass:226.15689456
Topological Polar Surface Area:35.5
Heavy Atom Count:16
Complexity:193
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes