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3-Methoxybutyl acetate

3-Methoxybutyl acetate structure

3-Methoxybutyl acetate 

structure
  • CAS No:

    4435-53-4

  • Formula:

    C7H14O3

  • Chemical Name:

    3-Methoxybutyl acetate

  • Synonyms:

    1-Butanol,3-methoxy-,1-acetate;1-Butanol,3-methoxy-,acetate;Acetic acid 3-methoxybutyl ester;3-Methoxybutyl acetate;3-Methoxy-1-butyl acetate;3-Methoxy-n-butyl acetate;NSC 15638;Butoxyl;3-Methoxy-1-butanol acetate;MBA

  • Categories:

    Chemical Reagents  >  Organic Reagents

Description

BUTOXYL is a liquid with an acrid odor. Flash point near 140°F. Slightly less dense than water. Vapors much heavier than air. May irritate skin, eyes, and mucous membranes.


Butoxyl appears as a liquid with an acrid odor. Flash point near 140°F. Slightly less dense than water. Vapors much heavier than air. May irritate skin, eyes, and mucous membranes.


Butoxyl appears as a liquid with an acrid odor. Flash point near 140°F. Slightly less dense than water. Vapors much heavier than air. May irritate skin, eyes, and mucous membranes.

3-Methoxybutyl acetate Basic Attributes

146.18

146.18

224-644-9

15638

1993|2708

DTXSID2052106

2915390090

Characteristics

35.53000

0.75

Butoxyl appears as a liquid with an acrid odor. Flash point near 140°F. Slightly less dense than water. Vapors much heavier than air. May irritate skin, eyes, and mucous membranes.

0.9±0.1 g/cm3

172 °C

62°C

1.407

60.68g/L(20 ºC)

Oral-Rat  LD50: 4210  mg/kg

Combustible in case of open flame, high temperature and strong oxidant; burning emits irritating smoke

Flammable. Slightly soluble in water.

Esters, Sulfate Esters, Phosphate Esters, Thiophosphate Esters, and Borate Esters

When heated to decomposition, emits acrid smoke and irritating fumes (USCG, 1999).

3-Methoxy-1-butyl acetate|D: Other compounds that may form peroxides|Kelly

Safety Information

1993

36/37/38

26-36

EL4725000

Complete packaging, light loading and unloading; warehouse ventilated, away from open flame, high temperature, and stored separately from oxidant

Explosive when mixed with air

P261, P264, P271, P280, P304+P340, P305+P351+P338, P312, P337+P313, P403+P233, P405, P501

H319

Special Hazards of Combustion Products: When heated to decomposition, emits acrid smoke and irritating fumes. (USCG, 1999)|Flammable - 2nd degree, Reactive - 1st degree

|Warning|H319 (13.52%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]|P261, P264, P271, P280, P304+P340, P305+P351+P338, P312, P337+P313, P403+P233, P405, and P501|Aggregated GHS information provided by 579 companies from 6 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Excerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible)]: CAUTION: All these products have a very low flash point: Use of water spray when fighting fire may be inefficient. CAUTION: For mixtures containing alcohol or polar solvent, alcohol-resistant foam may be more effective. SMALL FIRE: Dry chemical, CO2, water spray or regular foam. LARGE FIRE: Water spray, fog or regular foam. Do not use straight streams. Move containers from fire area if you can do it without risk. FIRE INVOLVING TANKS OR CAR/TRAILER LOADS: Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks engulfed in fire. For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and let fire burn. (ERG, 2016)

Excerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible)]: As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in all directions. LARGE SPILL: Consider initial downwind evacuation for at least 300 meters (1000 feet). FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2016)

Excerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible)]: ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). All equipment used when handling the product must be grounded. Do not touch or walk through spilled material. Stop leak if you can do it without risk. Prevent entry into waterways, sewers, basements or confined areas. A vapor-suppressing foam may be used to reduce vapors. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Use clean, non-sparking tools to collect absorbed material. LARGE SPILL: Dike far ahead of liquid spill for later disposal. Water spray may reduce vapor, but may not prevent ignition in closed spaces. (ERG, 2016)

Self-contained breathing apparatus, rubber boots and heavy rubber gloves. (USCG, 1999)

Toxicity

practically nontoxic

Drug Information

Causes eye and skin irritation. Mildly toxic by ingestion. (USCG, 1999)

INHALATION: Call for medical aid. Remove the victim to fresh air. If breathing has stopped, give artificial respiration. If breathing is difficult, give oxygen. INGESTION: Immediately induce vomiting. EYES - OR - SKIN: Flush with copious amounts of water for at least 15 minutes. (USCG, 1999)

3-methoxybutyl acetate

3-Methoxybutyl acetate Use and Manufacturing

Production

< 25,000 lb

1-Butanol, 3-methoxy-, 1-acetate: ACTIVE

EPA Safer Chemical Functional Use Classes -> Solvents|Safer Chemical Classes -> Green circle - The chemical has been verified to be of low concern|Fire Hazards -> Flammable - 2nd degree, Reactive - 1st degree

Computed Properties

Molecular Weight:146.18
XLogP3:0.8
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:5
Exact Mass:146.094294304
Monoisotopic Mass:146.094294304
Topological Polar Surface Area:35.5
Heavy Atom Count:10
Complexity:101
Undefined Atom Stereocenter Count:1
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes

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