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Home > Encyclopedia > 4-Isopropoxydiphenylamine

4-Isopropoxydiphenylamine

4-Isopropoxydiphenylamine structure

4-Isopropoxydiphenylamine 

structure
  • CAS No:

    101-73-5

  • Formula:

    C15H17NO

  • Chemical Name:

    4-Isopropoxydiphenylamine

  • Synonyms:

    Benzenamine,4-(1-methylethoxy)-N-phenyl-;Diphenylamine,4-isopropoxy-;4-(1-Methylethoxy)-N-phenylbenzenamine;AgeRite ISO;p-Hydroxydiphenylamine isopropyl ether;p-Isopropoxydiphenylamine;Isopropoxyphenyl-4-aniline;4-Isopropoxydiphenylamine;4-(Isopropyloxy)diphenylamine;4-Isopropoxy-N-phenylaniline;NSC 3050;NSC 404958

Description

PHYSICAL DESCRIPTION: Dark gray flakes or flaky black solid. (NTP, 1992)


P-isopropoxydiphenylamine appears as dark gray flakes or flaky black solid. (NTP, 1992)


P-isopropoxydiphenylamine appears as dark gray flakes or flaky black solid. (NTP, 1992)

4-Isopropoxydiphenylamine Basic Attributes

227.30200

227.30

202-970-2

259SIX2B44

404958|3050

DTXSID2020763

DARK GRAY FLAKES

2922299090

Characteristics

21.26000

4.29040

P-isopropoxydiphenylamine appears as dark gray flakes or flaky black solid. (NTP, 1992)

1.10 g/cm3

78 - 80ºC

357.1ºC at 760mmHg

147.4ºC

1.586

INSOL IN WATER; SOL IN ACETONE, BENZENE, GASOLINE, ETHYL ALCOHOL

Insoluble in water.

Amines, Phosphines, and Pyridines

Amines are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides.

Safety Information

P261, P264, P271, P273, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, P501

H315

Flash point data for this chemical are not available; however, it is probably combustible. (NTP, 1992)

|Warning|H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]|P261, P264, P271, P273, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, and P501|Aggregated GHS information provided by 38 companies from 1 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Fires involving this material can be controlled with a dry chemical, carbon dioxide or Halon extinguisher. (NTP, 1992)

SMALL SPILLS AND LEAKAGE: Should a spill occur while you are handling this chemical, FIRST REMOVE ALL SOURCES OF IGNITION, then you should dampen the solid spill material with 60-70% ethanol and transfer the dampened material to a suitable container. Use absorbent paper dampened with 60-70% ethanol to pick up any remaining material. Seal the absorbent paper, and any of your clothes, which may be contaminated, in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with 60-70% ethanol followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned. STORAGE PRECAUTIONS: You should keep this material in a tightly closed container under an inert atmosphere, and store it at refrigerated temperatures. (NTP, 1992)

RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)

Drug Information

ACUTE/CHRONIC HAZARDS: When heated to decomposition this compound emits toxic fumes of nitrogen oxides. (NTP, 1992)

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment. INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing. INGESTION: DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)

TOXICOLOGICAL & DERMATOLOGICAL HAZARDS FROM RUBBERS & ANTIOXIDANTS ... USED IN CABLE INDUST ARE DISCUSSED.|LOW TOXICITY.

4-Isopropoxydiphenylamine Use and Manufacturing

Methods of Manufacturing

REACTION OF 4-HYDROXYDIPHENYLAMINE WITH PROPYLENE IN THE PRESENCE OF SULFURIC, PHOSPHORIC OR HYDROFLUORIC ACID

Uses

RUBBER ANTIOXIDANT

Production

(1973) PROBABLY GREATER THAN 4.54X10+5 GRAMS|(1975) PROBABLY GREATER THAN 4.54X10+5 GRAMS

ESSENTIALLY 100% AS RUBBER ANTIOXIDANT

Benzenamine, 4-(1-methylethoxy)-N-phenyl-: ACTIVE|PURITY 92% (MIN); ASH 0.10% (MAX).

Computed Properties

Molecular Weight:227.30
XLogP3:3.9
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:4
Exact Mass:227.131014166
Monoisotopic Mass:227.131014166
Topological Polar Surface Area:21.3
Heavy Atom Count:17
Complexity:203
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes

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