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Allyltributyltin

Allyltributyltin structure

CAS No:
24850-33-7
Formula:
C15H32Sn
Chemical Name:
Allyltributyltin
Synonyms:
Stannane,tributyl-2-propen-1-yl-;Stannane,allyltributyl-;Stannane,tributyl-2-propenyl-;Tin,allyltributyl-;Tributyl-2-propen-1-ylstannane;Allyltributyltin;Allyltributylstannane;Tributylallylstannane;Tributylallyltin;3-Tributylstannyl-1-propene;Allyltri-n-butylstannane;Allyltri-n-butyltin;3-(Tributyltin)-1-propene;Tributyl(2-propenyl)stannane;2-Propenyltributylstannane;(Propen-2-yl)tributyltin;Tri(n-butyl)allylstannane
Categories:
Pharmaceutical Intermediates > Bulk Drug Intermediates

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Description

CLEAR COLOURLESS LIQUID

Allyltributyltin Basic Attributes

Molecular Weight：

331.12

Exact Mass：

331.12

BRN：

3588340

EC Number：

246-494-3

UNII：

AOR8OD4103

DSSTox ID：

DTXSID50179553

HScode：

29319019

Characteristics

PSA：

XLogP3：

9.10

Appearance：

Clear colorless Liquid

Density：

1.068 g/cm³

Melting Point：

134-135 °C

Boiling Point：

88-92 °C @ Press: 0.2 Torr

Flash Point：

>230 °F

Refractive Index：

n20/D 1.486(lit.)

Water Solubility：

Immiscible with water.

Storage Conditions：

2-8°C

Vapor Pressure：

0.00098mmHg at 25°C

Safety Information

Packing level：

Hazard category：

6.1

Transport codes：

UN 2788 6.1/PG 2

wgk germany：

hazard class code：

21-25-36/38-48/23/25-50/53-23/24/25

safety instructions：

35-36/37/39-45-60-61-28-27-26

Marks：

T,N

Stability/Shelf Life：

Stable at room temperature in closed containers under normal storage and handling conditions.

Precautionary statement(s)：

Missing Phrase - N15.00950417-P260-P280-P305 + P351 + P338

Hazard Statements：

H301-H312-H315-H319-H372-H410

GHS Classification：

|Danger|H301 (100%): Toxic if swallowed [Danger Acute toxicity, oral]|P260, P264, P270, P273, P280, P301+P310, P302+P352, P305+P351+P338, P312, P314, P321, P322, P330, P332+P313, P337+P313, P362, P363, P391, P405, and P501|Aggregated GHS information provided by 45 companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Allyltributyltin Use and Manufacturing

Allylation reagent for aldehydes catalyzed by chiral Lewis acids1,2 and ytterbium(III) trifluoromethanesulfonate (cat. no. 430595).3 Undergoes tetrakis(triphenylphosphine)palladium(0) (cat. no. 216666) catalyzed coupling with iodoquinones4 and allyl acetates.5,6Efficient allylation of aldehydes leading to homoallylic alcohols with trichloro-1,3,5-triazene.7

Computed Properties

Molecular Weight:331.12
Rotatable Bond Count:11
Exact Mass:332.152604
Monoisotopic Mass:332.152604
Heavy Atom Count:16
Complexity:141
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes

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