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Dess-Martin periodinane

Dess-Martin periodinane structure

CAS No:
87413-09-0
Formula:
C13H13IO8
Chemical Name:
Dess-Martin periodinane
Synonyms:
Acetic acid,1,1′,1′′-(3-oxo-1λ5-1,2-benziodoxol-1(3H)-ylidyne) ester;1,2-Benziodoxol-3(1H)-one,1,1,1-tris(acetyloxy)-1,1-dihydro-;Dess-Martin periodinane;Martin's reagent;Dess-Martin reagent;Reagents,Martin's;Triacetoxyperiodinane;1,1,1-Tris(acetyloxy)-1,1-dihydro-1,2-benziodoxol-3(1H)-one;1,1,1-Triacetoxy-1,1-dihydro-1,2-benziodoxol-3(1H)-one;(1,1-Diacetoxy-3-oxo-1,2-benziodoxol-1-yl) acetate;134362-98-4;1331748-44-7
Categories:
Catalyst and Auxiliary > Precious Metal Catalysts

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Description

White Crystalline powder

Dess-Martin periodinane Basic Attributes

Molecular Weight：

424.14

Exact Mass：

424.14

BRN：

4548207

EC Number：

200-009-0

UNII：

336B74JK56

DSSTox ID：

DTXSID30236335

HScode：

29349990

Characteristics

PSA：

105.20000

XLogP3：

1.95370

Appearance：

Colorless to light yellow Liquid

Density：

1.369 g/mL at 25 °C

Melting Point：

134 °C

Boiling Point：

40 °C

Flash Point：

>221 °F

Water Solubility：

soluble in chloroform, acetone, acetonitrile and methylene chloride. Slightly soluble in ether and hexane.

Storage Conditions：

0-6°C

Safety Information

Hazard category：

5.1

Transport codes：

UN 1593 6.1/PG 3

wgk germany：

hazard class code：

22-36/37/38-40-8-20/21/22-44

safety instructions：

26-36-36/37-24/25-23-17-45-36/37/39

Marks：

Xn,O,Xi

Hazard note：

Harmful/Light sensitive

Precautionary statement(s)：

P220; P261; P280; P305 + P351 + P338

Hazard Statements：

H272; H302 + H312 + H332; H315; H319; H335

GHS Classification：

|Warning|H272 (10.42%): May intensify fire; oxidizer [Danger Oxidizing liquids; Oxidizing solids]|P210, P220, P221, P261, P264, P270, P271, P280, P301+P312, P302+P352, P304+P312, P304+P340, P305+P351+P338, P312, P321, P322, P330, P332+P313, P337+P313, P362, P363, P370+P378, P403+P233, P405, and P501|Aggregated GHS information provided by 48 companies from 6 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Drug Information

MeSH Entry Terms：

1,1,1-triacetoxy-1,1-dihydro-1,2-benziodoxol-3(1H)-one

Dess-Martin periodinane Use and Manufacturing

Important oxidizing reagent; milder oxidizing agent, mostly used in the total synthesis of natural products. Oxidant used to oxidize 1° and 2° alcohols to aldehydes and ketones; used to oxidize hydroxychlorin to chlorin-α-diketone and tetraketone; oxidant used to oxidize hydroxychlorin (Hydroxychlorins) generate chlorin-α-diones and tetraketones. It is also used to oxidize alcohols into aldehydes and ketones.

Computed Properties

Molecular Weight:424.14
XLogP3:2.7
Hydrogen Bond Acceptor Count:8
Rotatable Bond Count:6
Exact Mass:423.96551
Monoisotopic Mass:423.96551
Topological Polar Surface Area:105
Heavy Atom Count:22
Complexity:499
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes

Material

Acetic acid

Downstream Products

Acetic acid

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