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Trimethylsilyl triflate

Trimethylsilyl triflate structure

Trimethylsilyl triflate 

structure
  • CAS No:

    27607-77-8

  • Formula:

    C4H9F3O3SSi

  • Chemical Name:

    Trimethylsilyl triflate

  • Synonyms:

    Methanesulfonic acid,1,1,1-trifluoro-,trimethylsilyl ester;Methanesulfonic acid,trifluoro-,trimethylsilyl ester;Silanol,trimethyl-,trifluoromethanesulfonate;Trimethylsilyl trifluoromethanesulfonate;Trimethylsilyl trifluoromethylsulfonate;Trimethylsilyl triflate;Trimethylsilanol trifluoromethanesulfonate;Trifluoromethanesulfonic acid trimethylsilyl ester;Trimethylsilyl trfluoromethanesulfonate;TMSOTf;88188-06-1

  • Categories:

    Chemical Reagents  >  Organic Reagents

Description

clear colourless to light brown fuming liquid

Trimethylsilyl triflate Basic Attributes

222.26

222.26

1868911

248-565-4

Z84V0CBH9J

DTXSID2067325

29310095

Characteristics

51.75000

2.54

Clear colorless to light brown Fuming Liquid

1.225 g/cm3

<25 °C

140 °C

78 °F

1.379

Solubility in water: reaction

2-8°C

4.7 hPa (20 °C)

Safety Information

III

3

UN 2920 8/PG 2

3

10-14-34

16-26-36/37/39-45-8

C,F

Corrosive/Flammable

P280-P305 + P351 + P338-P310

H226-H314

|Danger|H226 (98.18%): Flammable liquid and vapor [Warning Flammable liquids]|P210, P233, P240, P241, P242, P243, P260, P264, P280, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P363, P370+P378, P403+P235, P405, and P501|Aggregated GHS information provided by 59 companies from 10 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Drug Information

TMS-TFMS

Trimethylsilyl triflate Use and Manufacturing

Uses

Catalyst and silylating agent for organic syntheses.

Methanesulfonic acid, 1,1,1-trifluoro-, trimethylsilyl ester: ACTIVE

Computed Properties

Molecular Weight:222.26
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:2
Exact Mass:221.99937634
Monoisotopic Mass:221.99937634
Topological Polar Surface Area:51.8
Heavy Atom Count:12
Complexity:244
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes

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