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Home > Encyclopedia > 3,3-Dimethyl-1,5-dioxaspiro[5.5]undecan-9-one

3,3-Dimethyl-1,5-dioxaspiro[5.5]undecan-9-one

3,3-Dimethyl-1,5-dioxaspiro[5.5]undecan-9-one structure

3,3-Dimethyl-1,5-dioxaspiro[5.5]undecan-9-one 

structure
  • CAS No:

    69225-59-8

  • Formula:

    C11H18O3

  • Chemical Name:

    3,3-Dimethyl-1,5-dioxaspiro[5.5]undecan-9-one

  • Synonyms:

    1,5-Dioxaspiro[5.5]undecan-9-one,3,3-dimethyl-;3,3-Dimethyl-1,5-dioxaspiro[5.5]undecan-9-one;1,4-Cyclohexanedione mono(2,2-dimethyltrimethylene ketal)

  • Categories:

    Specialty Chemicals

Description

White to yellowish powder

3,3-Dimethyl-1,5-dioxaspiro[5.5]undecan-9-one Basic Attributes

198.26

198.26

273-918-4

DTXSID10219262

2932999099

Characteristics

35.5

1

White to yellowish powder

1.1±0.1 g/cm3

48-49.5 °C @ Solvent: Hexane

70 °C @ Press: 0.05 Torr

123.3±13.8 °C

1.484

Safety Information

NONH for all modes of transport

3

R36/37/38

S24/25

P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, P501

H315

|Warning|H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]|P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, and P501|Aggregated GHS information provided by 2 companies from 2 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

3,3-Dimethyl-1,5-dioxaspiro[5.5]undecan-9-one Use and Manufacturing

Methods of Manufacturing

6.1mg (0.02mmol) of sodiuim 2-iodobenzenesulfonate prepared by Preparation Example 4, 0.49g (0.8mmol) of powdered Oxone (registered trademark), 0.5g (3.5mol) of anhydrous sodium sulfate and 200mg (1mmol) of 3, 3-dimethyl-1, 5-dioxaspiro[5.5]undecan-9-ol were added to 5ml of ethyl acetate, and the mixture was heated at 70 °C while being stirred under a nitrogen for eight hours. 3, 3-Dimethyl-l, 5-dioxaspiro[5.5]undecan-9-one.; A continuous extraction apparatus is assembled. A 500 mL extraction solvent pot is charged with 250 mLπ-hexane and 5.00 g sodium bicarbonate. An oil bath is heated to 90°C. A 500 mL reaction pot is charged with 82.5 g (0.792 mol, 2.33 equiv) neopentyl glycol, 338 mLH

Uses

1,4-Cyclohexanedione mono(2,2-dimethyltrimethylene ketal)is a reagent used in the preparation of carbazole derivatives.

Computed Properties

Molecular Weight:198.26
XLogP3:1
Hydrogen Bond Acceptor Count:3
Exact Mass:198.125594432
Monoisotopic Mass:198.125594432
Topological Polar Surface Area:35.5
Heavy Atom Count:14
Complexity:223
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes

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