Propene, ammoxidized, by-products from Safety Data Sheets
SAFETY DATA SHEETS
According to the UN GHS revision 8
SECTION 1: Identification
1.1 GHS Product identifier
| Product name | Propene, ammoxidized, by-products from |
|---|
1.2 Other means of identification
| Product number | - |
|---|---|
| Other names | - |
1.3 Recommended use of the chemical and restrictions on use
| Identified uses | Fuels and fuel additives,Functional fluids (closed systems),Intermediates,Laboratory chemicals |
|---|---|
| Uses advised against | no data available |
1.4 Supplier's details
| Company | Echemi.com |
|---|---|
| Address | Echemi.com |
| Telephone | Echemi.com |
1.5 Emergency phone number
| Emergency phone number | Echemi.com |
|---|---|
| Service hours | Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours). |
SECTION 2: Hazard identification
2.1 Classification of the substance or mixture
no data available
2.2 GHS label elements, including precautionary statements
| Pictogram(s) | no data available |
|---|---|
| Signal word | no data available |
| Hazard statement(s) | no data available |
| Precautionary statement(s) | |
| Prevention | no data available |
| Response | no data available |
| Storage | no data available |
| Disposal | no data available |
2.3 Other hazards which do not result in classification
no data available
SECTION 3: Composition/information on ingredients
3.1 Substances
| Chemical name | Common names and synonyms | CAS number | EC number | Concentration |
|---|---|---|---|---|
| Propene, ammoxidized, by-products from | Propene, ammoxidized, by-products from | 90530-12-4 | 292-050-7 | 100% |
SECTION 4: First-aid measures
4.1 Description of necessary first-aid measures
If inhaled
Fresh air, rest. Artificial respiration may be needed. Refer for medical attention.
Following skin contact
ON FROSTBITE: rinse with plenty of water, do NOT remove clothes. Refer for medical attention .
Following eye contact
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Following ingestion
Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately.
4.2 Most important symptoms/effects, acute and delayed
Moderate concentration in air causes dizziness, drowsiness, and unconsciousness. Contact with liquefied propylene will cause ``freezing burn.'' (USCG, 1999)
4.3 Indication of immediate medical attention and special treatment needed, if necessary
If splashes of liquid propylene cause freezing of the skin, never rinse the affected area with hot or tepid water. If liquid propylene contacts the eyes flush eyes with water for 15 minutes.
SECTION 5: Fire-fighting measures
5.1 Suitable extinguishing media
Do not extinguish fire unless flow can be stopped. If possible use foam, carbon dioxide, or dry chemical to extinguish fire. If none of these compounds are available use water in flooding quantities as a fog, being sure to cool all affected containers. Apply water from as far a distance as possible, and do not use solid streams of water since they may be ineffective. Keep material out of water sources and sewers and build dikes as necessary to contain flow. Wear self contained breathing apparatus, boots, protective gloves and goggles and be sure to wash away any material which may have contacted the body with copious amounts of water or soap and water. Do not handle damaged packages without protective equipment. If fire becomes uncontrollable or a container is exposed to direct flame, evacuate for a radius of 2500 feet. If material leaking (and is not on fire), downwind evacuation must be considered.
5.2 Specific hazards arising from the chemical
Behavior in Fire: Containers may explode. Vapor is heavier than air and may travel considerable distance to a source of ignition and flash back. (USCG, 1999)
5.3 Special protective actions for fire-fighters
Wear self-contained breathing apparatus for firefighting if necessary.
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Avoid dust formation. Avoid breathing mist, gas or vapours.Avoid contacting with skin and eye. Use personal protective equipment.Wear chemical impermeable gloves. Ensure adequate ventilation.Remove all sources of ignition. Evacuate personnel to safe areas.Keep people away from and upwind of spill/leak.
6.2 Environmental precautions
Evacuate danger area! Consult an expert! Ventilation. Remove all ignition sources. NEVER direct water jet on liquid. Personal protection: chemical protection suit including self-contained breathing apparatus.
6.3 Methods and materials for containment and cleaning up
Spills in Water: Contain contaminated water if possible by using natural barriers or oil spill control booms to limit spreading. A universal gelling agent may be applied to solidify trapped mass and to increase effectiveness of the booms. If solubilized, application of activated carbon at 10% spill amount over region occupied by 10 mg/L or greater concentrations is recommended. Spills on Land: Contain if possible by forming mechanical and/or chemical barriers to prevent spreading. Apply universal gelling agent to immobilize spill or use fly ash or cement powder to absorb the liquid. Leaking containers should be removed to an isolated well-ventilated area and if possible, the contents transferred to other suitable containers. Safety goggles, impervious clothing and positive pressure self-contained breathing apparatus should be worn. Plastic or neoprene-coated canvas gloves should be worn when liquid propylene is handled.
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.
7.2 Conditions for safe storage, including any incompatibilities
Fireproof. Cool.Protect cylinder against physical damage and from excessive temperature rise by storing away from sources of heat. No part of a cylinder should be subjected to a temperature above 52 deg C. Store cylinders in an upright position and firmly secured. Segregate full and empty cylinders. Isolate from oxygen and other oxidizers. Avoid exposure to areas where salt or other corrosive chemicals are present. Ground and bond all lines and equipment used with propylene. Do not use near sparking motors or other non explosion proof equipment.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Occupational Exposure limit values
no data available
Biological limit values
no data available
8.2 Appropriate engineering controls
Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.
8.3 Individual protection measures, such as personal protective equipment (PPE)
Eye/face protection
Wear tightly fitting safety goggles with side-shields conforming to EN 166(EU) or NIOSH (US).
Skin protection
Wear fire/flame resistant and impervious clothing. Handle with gloves. Gloves must be inspected prior to use. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.
Respiratory protection
If the exposure limits are exceeded, irritation or other symptoms are experienced, use a full-face respirator.
Thermal hazards
no data available
SECTION 9: Physical and chemical properties and safety characteristics
| Physical state | Propylene is a colorless gas with a faint petroleum like odor. It is shipped as a liquefied gas under its own vapor pressure. For transportation it may be stenched. Contact with the liquid can cause frostbite. It is easily ignited. The vapors are heavier than air. Any leak can either be liquid or vapor. It can asphyxiate by the displacement of air. Under prolonged exposure to fire or intense heat the containers may rupture violently and rocket. It is used to make other chemicals. Can cause explosion. |
|---|---|
| Colour | Colorless gas |
| Odour | Aromatic |
| Melting point/freezing point | -301.4° F (NTP, 1992) |
| Boiling point or initial boiling point and boiling range | -53.9° F at 760 mm Hg (NTP, 1992) |
| Flammability | Extremely flammable. |
| Lower and upper explosion limit/flammability limit | Lower 2.4%, Upper 10.3% by volume in air. |
| Flash point | -162° F (NTP, 1992) |
| Auto-ignition temperature | 851° F (USCG, 1999) |
| Decomposition temperature | no data available |
| pH | no data available |
| Kinematic viscosity | 83.4 micropoises at 16.7 deg C |
| Solubility | 44.6 mL/100 mL (NTP, 1992) |
| Partition coefficient n-octanol/water | log Kow = 1.77 |
| Vapour pressure | 1 mm Hg at -205.4° F ; 760 mm Hg at -53.9° F (NTP, 1992) |
| Density and/or relative density | 0.609 at -52.6° F (USCG, 1999) |
| Relative vapour density | 1.46 at 32° F (NTP, 1992) (Relative to Air) |
| Particle characteristics | no data available |
SECTION 10: Stability and reactivity
10.1 Reactivity
Reacts violently with oxidants. This generates fire and explosion hazard.
10.2 Chemical stability
no data available
10.3 Possibility of hazardous reactions
DANGEROUS FIRE RISK.The gas is heavier than air and may travel along the ground; distant ignition possible. The gas is heavier than air and may accumulate in lowered spaces causing a deficiency of oxygen. As a result of flow, agitation, etc., electrostatic charges can be generated.During an experiment to produce lactic acid by oxidizing PROPYLENE with nitrogen peroxide, a violent explosion occurred. These mixtures (olefins and nitrogen peroxide) form extremely unstable nitrosates or nitrosites (Comp. Rend. 116:756 1893). Contact of very cold liquid propylene with water may result in vigorous or violent boiling of the product and extremely rapid vaporization due to the large temperature differences involved. If the water is hot, there is the possibility that a liquid "superheat" explosion may occur. Pressures may build to dangerous levels if liquid propylene contacts water in a closed container.
10.4 Conditions to avoid
no data available
10.5 Incompatible materials
Propylene reacts vigorously with oxidizing materials and with nitrogen dioxide (NO2), dinitrogen tetraoxide (N2O4), and dinitrogen oxide (N2O). Furthermore, liquid propylene will explode on contact with water at 42-75 deg C.
10.6 Hazardous decomposition products
Combustion products of propylene ... include carbon dioxide and carbon monoxide.
SECTION 11: Toxicological information
Acute toxicity
- Oral: no data available
- Inhalation: LC50 Rat inhalation 570,000 ppm/15 min Conditions of bioassay not specified in source examined
- Dermal: no data available
Skin corrosion/irritation
no data available
Serious eye damage/irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
Evaluation: There is inadequate evidence in humans for the carcinogenicity of propylene. There is inadequate evidence in experimental animals for the carcinogenicity of propylene. Overall evaluation: Propylene is not classifiable as to its carcinogenicity to humans (Group 3).
Reproductive toxicity
no data available
STOT-single exposure
no data available
STOT-repeated exposure
no data available
Aspiration hazard
no data available
SECTION 12: Ecological information
12.1 Toxicity
- Toxicity to fish: no data available
- Toxicity to daphnia and other aquatic invertebrates: no data available
- Toxicity to algae: no data available
- Toxicity to microorganisms: no data available
12.2 Persistence and degradability
In water bodies, propylene is readily degraded by microorganisms and is therefore not expected to bioaccumulate or bioconcentrate in organisms and food chains.
12.3 Bioaccumulative potential
An estimated BCF of 5 was calculated for propylene(SRC), using a log Kow of 1.77(1) and a regression-derived equation(2). According to a classification scheme(3), this BCF suggests the potential for bioconcentration in aquatic organisms is low(SRC).
12.4 Mobility in soil
The Koc of propylene is estimated as 220(SRC), using a log Kow of 1.77(1) and a regression-derived equation(2). According to a classification scheme(3), this estimated Koc value suggests that propylene is expected to have moderate mobility in soil.
12.5 Other adverse effects
no data available
SECTION 13: Disposal considerations
13.1 Disposal methods
Product
The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Contaminated packaging
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
SECTION 14: Transport information
14.1 UN Number
| ADR/RID: no data available | IMDG: no data available | IATA: no data available |
14.2 UN Proper Shipping Name
| ADR/RID: no data available | IMDG: no data available | IATA: no data available |
14.3 Transport hazard class(es)
| ADR/RID: no data available | IMDG: no data available | IATA: no data available |
14.4 Packing group, if applicable
| ADR/RID: no data available | IMDG: no data available | IATA: no data available |
14.5 Environmental hazards
| ADR/RID: No | IMDG: No | IATA: No |
14.6 Special precautions for user
no data available
14.7 Transport in bulk according to IMO instruments
no data available
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations specific for the product in question
| Chemical name | Common names and synonyms | CAS number | EC number |
|---|---|---|---|
| Propene, ammoxidized, by-products from | Propene, ammoxidized, by-products from | 90530-12-4 | 292-050-7 |
| European Inventory of Existing Commercial Chemical Substances (EINECS) | Listed. | ||
| EC Inventory | Listed. | ||
| United States Toxic Substances Control Act (TSCA) Inventory | Not Listed. | ||
| China Catalog of Hazardous chemicals 2015 | Not Listed. | ||
| New Zealand Inventory of Chemicals (NZIoC) | Not Listed. | ||
| Philippines Inventory of Chemicals and Chemical Substances (PICCS) | Not Listed. | ||
| Vietnam National Chemical Inventory | Not Listed. | ||
| Chinese Chemical Inventory of Existing Chemical Substances (China IECSC) | Not Listed. | ||
| Korea Existing Chemicals List (KECL) | Not Listed. | ||
SECTION 16: Other information
Information on revision
| Creation Date | July 15, 2019 |
|---|---|
| Revision Date | July 15, 2019 |
Abbreviations and acronyms
- CAS: Chemical Abstracts Service
- ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
- RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
- IMDG: International Maritime Dangerous Goods
- IATA: International Air Transportation Association
- TWA: Time Weighted Average
- STEL: Short term exposure limit
- LC50: Lethal Concentration 50%
- LD50: Lethal Dose 50%
- EC50: Effective Concentration 50%
References
- IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home
- HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
- IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/
- eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
- CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
- ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
- ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg
- Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
- ECHA - European Chemicals Agency, website: https://echa.europa.eu/
Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. We as supplier shall not be held liable for any damage resulting from handling or from contact with the above product.
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