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Home > Organic Chemistry > Organometallic Compounds > Di-μ-chlorobis(η3-2-propenyl)dipalladium for Sale > Catalyst Powder 12012-95-2 [PdCl(C3H5)]2 Allylpalladium(II) chloride dimer for Heck reaction 98%
Catalyst Powder 12012-95-2 [PdCl(C3H5)]2 Allylpalladium(II) chloride dimer for Heck reaction 98% buy - large image1
Catalyst Powder 12012-95-2 [PdCl(C3H5)]2 Allylpalladium(II) chloride dimer for Heck reaction 98% buy - image1

Catalyst Powder 12012-95-2 [PdCl(C3H5)]2 Allylpalladium(II) chloride dimer for Heck reaction 98%

Unit Price:

$1-2/G FOB

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CAS No.:

12012-95-2

Grade:

all

Content:

98%

Port:

WUHAN

Packaging:

1kg/Bottle

Price valid (until):

2059-12-31

Company Type:
Manufactory
Location:
China
Qualification:
Main Products:

palladium catalyst,Ruthenium Catalyst,Phosphine Ligands,Copper catalyst ,Nitrogen ligands

  • Product Description

  • Seller Information

  • Description

    12012-95-2
    Allylpalladium(II) chloride dimer
    Synonym: [PdCl(C3H5)]2

    CAS Number: 12012-95-2
    MDL: MFCD00044874
    Formula: C6H10Cl2Pd2
    Formula Weight: 365.89 g/mol
    assay 98%
    storage temp. 2-8°C
    Caution : air sensitive, refrigeration
    shelf life :12 month
    Supplier: LPBchem-Benjamin

    Related Categories
    12 Principles Aligned Products, C-H Activation, Catalysis, Catalysis and Inorganic Chemistry, Catalysts, Chemical Synthesis, Greener Alternative Products, Homogeneous Pd Catalysts, Palladium Catalysts

    General description
    Allylpalladium(II) chloride dimer is employed as catalyst in Heck reaction. It also participates as catalyst in the tandem nucleophilic allylation-alkoxyallylation reaction of the alkynylaldehydes with allyl chloride and allyltributylstannane.

    Application:
    Allylpalladium(II) chloride dimer has been employed for the following studies:
    - Synthesis of cationic palladium cataysts, used in the microwave-assisted Heck arylation.
    -Synthesis of N-heterocyclic carbene-palladium-η3-allyl chloride complexes, which are efficient catalyst for the Suzuki-Miyaura cross-coupling of aryl bromides and activated aryl chlorides.
    -Synthesis of 1,4-diallyl-1,2-dihydroisoquinolines.
    - As catalyst for greener Buchwald-Hartwig coupling in TPGS-750-M.

    Basic Info
    Product Name:

    Di-μ-chlorobis(η3-2-propenyl)dipalladium

    Other Name:

    Palladium,di-μ-chlorobis(η3-2-propenyl)di-;Palladium,di-π-allyldi-μ-chlorodi-;Palladium,dichlorodi-π-allyldi-;Diallyldipalladium dichloride;Di-μ-chlorobis(η3-2-propenyl)dipalladium;Di-μ-chlorodi-π-allyldipalladium;Allylpalladium chloride dimer;Allylpalladium chloride;Bis(π-allylpalladium chloride);Diallyldichlorodipalladium;Di-π-allyldi-μ-chlorodipalladium;π-Allylpalladium chloride dimer;π-Allyl palladium chloride;Bis(π-allyl)dichlorodipalladium;Bis[(π-allyl)chloropalladium];Palladium allyl chloride;Di-π-Allylpalladium chloride;Bis(π-allylpalladium) dichloride;Bis(chloro-π-allylpalladium);Bis(allylchloropalladium);Bis(allyl)dichlorodipalladium;Bis(η3-allyl)dichlorodipalladium;Allylchloropalladium dimer;Di-μ-chlorobis(η3-allyl)dipalladium;π-Allylpalladium(II) chloride dimer;Bis(allyl(μ-chloro)palladium);Bis((μ-chloro)(2-propenyl)palladium);Bis(chloro(η3-2-propenyl)palladium);Bis(μ-chloro)bis(η3-2-propenyl)dipalladium;Bis(chloro(π-propenyl)palladium);Di-μ-chlorobis(allylpalladium);Bis((η3-allyl)(chloro)palladium);Di-μ-chlorobis((η3-allyl)palladium);Bis[chloro(η3-allyl)palladium];Bis(η3-allyl)bis(μ-chloro)dipalladium;Di-μ-chlorobis(π-allyl)dipalladium;NSC 151255;Bis[(η3-allyl)-μ-chloropalladium];Bis[μ-chloro(η3-2-propenyl)palladium];Bis(η3-allyl)di(μ-chloro)dipalladium;Allylpalladium(II) chloride dimer;12075-55-7;753497-29-9

    CAS No.:

    12012-95-2

    Molecular Formula:

    C6H10Cl2Pd2

    InChIKeys:

    InChIKey=PENAXHPKEVTBLF-UHFFFAOYSA-L

    Molecular Weight:

    365.89

    Exact Mass:

    363.822937

    EC Number:

    234-579-8

    HScode:

    28439090

    Characteristics
    PSA:

    0

    XLogP3:

    3.65900

    Appearance:

    Yellow to green-yellow Crystals or Crystalline Powder

    Melting Point:

    120°C(dec.)

    Water Solubility:

    Decomposes in water

    Storage Conditions:

    2-8°C

    Vapor Pressure:

    8480mmHg at 25°C

    Flammability characteristics:

    Flammable; burning produces toxic chloride fumes

    Hazard Identification

    Classification of the substance or mixture

    Skin irritation, Category 2

    Eye irritation, Category 2

    Specific target organ toxicity – single exposure, Category 3

    GHS label elements, including precautionary statements

    Pictogram(s)
    Signal word

    Warning

    Hazard statement(s)

    H315 Causes skin irritation

    H319 Causes serious eye irritation

    H335 May cause respiratory irritation

    Precautionary statement(s)
    Prevention

    P264 Wash ... thoroughly after handling.

    P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...

    P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

    P271 Use only outdoors or in a well-ventilated area.

    Response

    P302+P352 IF ON SKIN: Wash with plenty of water/...

    P321 Specific treatment (see ... on this label).

    P332+P317 If skin irritation occurs: Get medical help.

    P362+P364 Take off contaminated clothing and wash it before reuse.

    P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

    P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

    P319 Get medical help if you feel unwell.

    Storage

    P403+P233 Store in a well-ventilated place. Keep container tightly closed.

    P405 Store locked up.

    Disposal

    P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.

    Other hazards which do not result in classification

    no data available

    Handling and Storage

    Precautions for safe handling

    Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.

    Conditions for safe storage, including any incompatibilities

    Store the container tightly closed in a dry, cool and well-ventilated place. Store apart from foodstuff containers or incompatible materials.

  • Seller Information
    Business Type:

    Manufactory

    Main Products:

    palladium catalyst,Ruthenium Catalyst,Phosphine Ligands,Copper catalyst,Nitrogen ligands

    Location:

    East lake High Teck disctrict

    Payment Terms:

    TT against copy of documents,L/C

    Average lead Time:

    250

    Total Annual Revenue:

    $2.5 million-$5 million

    Total Employees:

    11-50

    Year of Establishment:

    2018

    Wuhan LPBchem Technology Co., Ltd, specializes in researchment, production and customization of organic phosphine compounds, organophosphorus palladium metal catalysts, Oled materials and pharmaceutical intermediates. Our products ranges from palladium series catalyst , Ruthenium series catalysts , Copper catalysts , phosphine ligands and N-ligands. 


    The company has over 40 employees, including 2 doctors and 11 with technical titles. Experienced technical backbones account for over 95% of the company. It set up a joint laboratory with Hubei University professors to provide customers high quality product customization and catalyst screening. We aimed to become a domestic first-class manufacturer of organophosphorus precious metal catalysts.


    We have various types of reactors apply to different conditions from high temperature, high pressure, to low temperature and ultra low temperature. We also have various analytical instruments such as gas chromatography (GC) and high performance liquid chromatography (HPLC) to ensure high quality. We are glad to create value with customers toghther!


    Benjamin is the main contact manager to get direct price 

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