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Di-μ-chlorobis(η3-2-propenyl)dipalladium

Di-μ-chlorobis(η3-2-propenyl)dipalladium structure

CAS No:
12012-95-2
Formula:
C6H10Cl2Pd2
Chemical Name:
Di-μ-chlorobis(η3-2-propenyl)dipalladium
Synonyms:
Palladium,di-μ-chlorobis(η3-2-propenyl)di-;Palladium,di-π-allyldi-μ-chlorodi-;Palladium,dichlorodi-π-allyldi-;Diallyldipalladium dichloride;Di-μ-chlorobis(η3-2-propenyl)dipalladium;Di-μ-chlorodi-π-allyldipalladium;Allylpalladium chloride dimer;Allylpalladium chloride;Bis(π-allylpalladium chloride);Diallyldichlorodipalladium;Di-π-allyldi-μ-chlorodipalladium;π-Allylpalladium chloride dimer;π-Allyl palladium chloride;Bis(π-allyl)dichlorodipalladium;Bis[(π-allyl)chloropalladium];Palladium allyl chloride;Di-π-Allylpalladium chloride;Bis(π-allylpalladium) dichloride;Bis(chloro-π-allylpalladium);Bis(allylchloropalladium);Bis(allyl)dichlorodipalladium;Bis(η3-allyl)dichlorodipalladium;Allylchloropalladium dimer;Di-μ-chlorobis(η3-allyl)dipalladium;π-Allylpalladium(II) chloride dimer;Bis(allyl(μ-chloro)palladium);Bis((μ-chloro)(2-propenyl)palladium);Bis(chloro(η3-2-propenyl)palladium);Bis(μ-chloro)bis(η3-2-propenyl)dipalladium;Bis(chloro(π-propenyl)palladium);Di-μ-chlorobis(allylpalladium);Bis((η3-allyl)(chloro)palladium);Di-μ-chlorobis((η3-allyl)palladium);Bis[chloro(η3-allyl)palladium];Bis(η3-allyl)bis(μ-chloro)dipalladium;Di-μ-chlorobis(π-allyl)dipalladium;NSC 151255;Bis[(η3-allyl)-μ-chloropalladium];Bis[μ-chloro(η3-2-propenyl)palladium];Bis(η3-allyl)di(μ-chloro)dipalladium;Allylpalladium(II) chloride dimer;12075-55-7;753497-29-9
Categories:
Organic Chemistry > Organometallic Compounds

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Di-μ-chlorobis(η3-2-propenyl)dipalladium Basic Attributes

Molecular Weight：

365.89

Exact Mass：

363.822937

EC Number：

234-579-8

HScode：

28439090

Characteristics

PSA：

XLogP3：

3.65900

Appearance：

Yellow to green-yellow Crystals or Crystalline Powder

Melting Point：

120°C(dec.)

Water Solubility：

Decomposes in water

Storage Conditions：

2-8°C

Vapor Pressure：

8480mmHg at 25°C

Flammability characteristics：

Flammable; burning produces toxic chloride fumes

Safety Information

Packing level：

Hazard category：

6.1(a)

Transport codes：

UN 3278

wgk germany：

hazard class code：

36/37/38-40

safety instructions：

26-36-36/37

RTECS Number：

RT3510000

Marks：

Xi,Xn

Storage features：

Treasury is ventilated, low temperature and dry; stored separately from food materials

Stability/Shelf Life：

Stable at room temperature in closed containers under normal storage and handling conditions. May decompose on exposure to moist air or water.

Precautionary statement(s)：

P280-P304 + P340 + P312-P305 + P351 + P338-P337 + P313

Hazard Statements：

H315-H319-H335

GHS Classification：

|Warning|H302 (16%): Harmful if swallowed [Warning Acute toxicity, oral]|P261, P264, P270, P271, P280, P301+P312, P302+P352, P304+P340, P305+P351+P338, P312, P321, P330, P332+P313, P337+P313, P362, P403+P233, P405, and P501|Aggregated GHS information provided by 50 companies from 6 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Di-μ-chlorobis(η3-2-propenyl)dipalladium Use and Manufacturing

1. Precatalyst for olefin enantioselective hydrosilylation. 2. Pre-catalyst for asymmetric alkylation and amination of cyclopropenyl acetate. 3. Cross-coupling reaction catalyst. 4. Dimers can be used as Trost ligands. 5. As a useful precursor for allyl alkylation and amination with high enantioselectivity. 6. Olefin tin alkylation catalyst.

Computed Properties

Molecular Weight:365.9
Hydrogen Bond Acceptor Count:2
Exact Mass:365.82333
Monoisotopic Mass:363.82292
Heavy Atom Count:10
Complexity:14.4
Covalently-Bonded Unit Count:4
Compound Is Canonicalized:Yes

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Guide of Di-μ-chlorobis(η3-2-propenyl)dipalladium

Basic Attributes
Characteristics
Safety Information
Use and Manufacturing
Computed Properties
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