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Home > Organic Chemistry > Organometallic Compounds > 1,3-BIS(2,4,6-TRIMETHYLPHENYL)IMIDAZOL-2-YLIDENE (1,4-NAPHTHOQUINONE)PALLADIUM(0) DIMER for Sale > Organic Synthesis Homogeneous Pd Catalysts cas 467220-49-1 for Suzuki cross-coupling reactions
Organic Synthesis Homogeneous Pd Catalysts cas 467220-49-1 for Suzuki cross-coupling reactions  buy - large image1
Organic Synthesis Homogeneous Pd Catalysts cas 467220-49-1 for Suzuki cross-coupling reactions  buy - image1

Organic Synthesis Homogeneous Pd Catalysts cas 467220-49-1 for Suzuki cross-coupling reactions

Unit Price:

$1/G FOB

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CAS No.:

467220-49-1

Grade:

Industrial Grade

Content:

98%

Port:

WUHAN

Packaging:

0.5kg/Bottle

Price valid (until):

2035-10-24

Company Type:
Manufactory
Location:
China
Qualification:
Main Products:

palladium catalyst,Ruthenium Catalyst,Phosphine Ligands,Copper catalyst ,Nitrogen ligands

  • Product Description

  • Seller Information

  • Description

    467220-49-1
    1,3-Bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (1,4-naphthoquinone)palladium(0) dimer
    Synonym: Bis[1,3-dihydro-1,3-(2,4,6-trimethylphenyl)-2H-imidazol-2-ylidene]bis[μ-[(2,3-η)-1,4-naphthalenedione-κO]]di-palladium, CX 12, Naphthoquinone-1,3-bis(2,4,6-trimethylphenyl)-imidazole-2-ylidenepalladium(0), CX 12, Pd(0)-naphthochinone-1,3-Bis(2,4,6-tri-methylphenyl)imidazol-2-ylidene, CX 12

    CAS Number: 467220-49-1
    MDL: MFCD06656102
    Formula: C62H60N4O4Pd2
    Formula Weight: 1,138.00 g/mol
    Appearance (Form) Powder or Crystals
    mp >300 °C
    Caution : air sensitive
    shelf life :12 month
    Supplier: LPBchem-Benjamin

    Related Categories
    Catalysis and Inorganic Chemistry, Chemical Synthesis, Homogeneous Pd Catalysts, NHC-based Palladium Catalysts, Palladium Catalysts

    General description
    1,3-Bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (1,4-naphthoquinone)palladium(0) dimer is an N-heterocyclic carbene based palladium catalyst that shows high catalytic activity in C-C coupling reactions.

    Application
    It can be used as a catalyst in the Kumada cross-coupling of aryl magnesium reagents with functionalized alkyl chlorides at room temperature to form substituted alkanes

    Basic Info
    Product Name:

    1,3-BIS(2,4,6-TRIMETHYLPHENYL)IMIDAZOL-2-YLIDENE (1,4-NAPHTHOQUINONE)PALLADIUM(0) DIMER

    Other Name:

    BIS[1,3-DIHYDRO-1,3-(2,4,6-TRIMETHYLPHENYL)-2H-IMIDAZOL-2-YLIDENE]BIS[MU-[(2,3-ETA)-1,4-NAPHTHALENEDIONE-KAPPAO]]DI-PALLADIUM;PD(0)-NAPHTHOCHINONE-1,3-BIS(2,4,6-TRI-METHYLPHENYL)IMIDAZOL-2-YLIDENE;NAPHTHOQUINONE-1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLE-2-YLIDENEPALLADIUM(0);1,3-Bis(2,4,6-trimethylphenyl)imidazol-2-ylidene(1,4-naphthoquinone)palladium(0)dimer,96%;bis[1,3-dihydro-1,3-(2,4,6-trimethylphenyl)-2h-imidazol-2-ylidene]bis[μ-[(2,3-η)-1,4-naphthalenedione-κo]]di-palladium;NAPHTHOQUINONE-1,3-BIS(MESITYL)IMIDAZOLE-2-YLIDENEPALLADIUM(0);Bis[1,3-dihydro-1,3-(2,4,6-trimethylphenyl)-2H-imidazol-2-ylidene]bis[μ-[(2,3-η:)-1,4-naphthalenedione-KO]]di-palladium,Naphthoquinone-1,3-bis(2,4,6-trimethylphenyl)-imidazole-2-ylidenepalladium(0),Pd(0)-naphthochinone-1,3-Bis(2,4,6-tri-methylphenyl)imidazol-2-ylidene;1,3-Bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (1,4-naphthoquinone)palladium dimer

    CAS No.:

    467220-49-1

    Molecular Formula:

    2C21H24N2Pd.2C10H6O2

    InChIKeys:

    ZTBFODSKEBBIJJ-UHFFFAOYSA-N

    Molecular Weight:

    1138.02

    Exact Mass:

    1136.27000

    DSSTox ID:

    DTXSID00473396

    HScode:

    28439000

    Characteristics
    PSA:

    88.00000

    XLogP3:

    13.64300

    Appearance:

    orange-red Powder

    Melting Point:

    >300 °C

    Hazard Identification

    Classification of the substance or mixture

    Skin irritation, Category 2

    Skin sensitization, Category 1

    Eye irritation, Category 2

    Specific target organ toxicity – single exposure, Category 3

    GHS label elements, including precautionary statements

    Pictogram(s)
    Signal word

    Warning

    Hazard statement(s)

    H315 Causes skin irritation

    H317 May cause an allergic skin reaction

    H319 Causes serious eye irritation

    H335 May cause respiratory irritation

    Precautionary statement(s)
    Prevention

    P264 Wash ... thoroughly after handling.

    P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...

    P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

    P272 Contaminated work clothing should not be allowed out of the workplace.

    P271 Use only outdoors or in a well-ventilated area.

    Response

    P302+P352 IF ON SKIN: Wash with plenty of water/...

    P321 Specific treatment (see ... on this label).

    P332+P317 If skin irritation occurs: Get medical help.

    P362+P364 Take off contaminated clothing and wash it before reuse.

    P333+P317 If skin irritation or rash occurs: Get medical help.

    P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

    P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

    P319 Get medical help if you feel unwell.

    Storage

    P403+P233 Store in a well-ventilated place. Keep container tightly closed.

    P405 Store locked up.

    Disposal

    P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.

    Other hazards which do not result in classification

    no data available

    Handling and Storage

    Precautions for safe handling

    Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.

    Conditions for safe storage, including any incompatibilities

    Store the container tightly closed in a dry, cool and well-ventilated place. Store apart from foodstuff containers or incompatible materials.

  • Seller Information
    Business Type:

    Manufactory

    Main Products:

    palladium catalyst,Ruthenium Catalyst,Phosphine Ligands,Copper catalyst,Nitrogen ligands

    Location:

    East lake High Teck disctrict

    Payment Terms:

    TT against copy of documents,L/C

    Average lead Time:

    250

    Total Annual Revenue:

    $2.5 million-$5 million

    Total Employees:

    11-50

    Year of Establishment:

    2018

    Wuhan LPBchem Technology Co., Ltd, specializes in researchment, production and customization of organic phosphine compounds, organophosphorus palladium metal catalysts, Oled materials and pharmaceutical intermediates. Our products ranges from palladium series catalyst , Ruthenium series catalysts , Copper catalysts , phosphine ligands and N-ligands. 


    The company has over 40 employees, including 2 doctors and 11 with technical titles. Experienced technical backbones account for over 95% of the company. It set up a joint laboratory with Hubei University professors to provide customers high quality product customization and catalyst screening. We aimed to become a domestic first-class manufacturer of organophosphorus precious metal catalysts.


    We have various types of reactors apply to different conditions from high temperature, high pressure, to low temperature and ultra low temperature. We also have various analytical instruments such as gas chromatography (GC) and high performance liquid chromatography (HPLC) to ensure high quality. We are glad to create value with customers toghther!


    Benjamin is the main contact manager to get direct price 

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