Product form | : | Substance |
Trade name | : | EDTA 4Na |
CAS-No. | : | 13235-36-4 |
Recommended use | : | Manufacture of cosmetic products, cleaning and maintenance products |
Restrictions on use | : | No information available |
Supplier
EAST CHEMSOURCES LIMITED
NO.666 HAIBIN 12TH ROAD,HUANGDAO,QINGDAO,CHINA
266100
T 0532-81906761
Emergency number | : | +86-532-81906761 |
GHS US classification
Acute toxicity - Oral Category 4 - (H302) |
Acute toxicity - Inhalation Category 4 - (H332) |
Serious eye damage/eye irritation Category 1 - (H318) |
Specific target organ toxicity - repeated Category 2 - (H373) |
2.2. GHS Label elements, including precautionary statements GHS US labelling
![Shop FACTORY OF EDTA 4NA-Detailed Image 7]()
![Shop FACTORY OF EDTA 4NA-Detailed Image 8]()
Hazard pictograms (GHS US) :
Signal word (GHS US) : Danger
Hazard statements (GHS US) : Harmful if swallowed.
Harmful if inhaled.
Causes serious eye damage.
May cause damage to organs through prolonged or repeated exposure.
Precautionary statements (GHS US) : Do not breathe dust/fume/gas/mist/vapours/spray.
Do not eat, drink or smoke when using this product
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Immediately call a POISON Center or doctor/physician. Dispose of contents/container in accordance with local/regional/ national/international regulations.
No additional information available
![Shop FACTORY OF EDTA 4NA-Detailed Image 11]()
Not applicable
06/20/2019 EN (English) Page 1
![Shop FACTORY OF EDTA 4NA-Detailed Image 13]()
![Shop FACTORY OF EDTA 4NA-Detailed Image 14]()
![Shop FACTORY OF EDTA 4NA-Detailed Image 15]()
Name | Product identifier | % |
EDTA 4Na | (CAS-No.) 13235-36-4 | 99.0 |
Full text of hazard classes and H-statements : see section 16
Not applicable
![Shop FACTORY OF EDTA 4NA-Detailed Image 17]()
First-aid measures general | : | In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data sheet if possible). |
First-aid measures after inhalation | : | IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical advice/attention if you feel unwell. |
First-aid measures after skin contact | : | Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Wash contaminated clothing before reuse. If skin irritation persists, call a physician. |
First-aid measures after eye contact | : | IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. |
First-aid measures after ingestion | : | Rinse mouth |
Harmful if swallowed. Harmful if inhaled. Causes serious eye damage. May cause damage to organs through prolonged or repeated exposure.
![Shop FACTORY OF EDTA 4NA-Detailed Image 19]()
Treat symptomatically.
Suitable extinguishing media | : | Dry chemical, CO2, water spray or regular foam. |
Unsuitable extinguishing media | : | No information available |
Thermal decomposition can lead to release of irritating and toxic gases and vapors.
Firefighting instructions | : | Eliminate all ignition sources if safe to do so. Move containers from fire area if it can be done without personal risk. Ensure adequate ventilation, especially in confined areas. |
Protection during firefighting | : | Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. |
General measures | : | Evacuate personnel to safe areas. Avoid contact with skin, eyes or clothing. Ensure adequate ventilation, especially in confined areas. Do not breathe dust/fume/gas/mist/vapors/spray. |
6.1.1. For non-emergency personnel
Emergency procedures | : | Ventilate spillage area. |
6.1.2. For emergency responders
Protective equipment | : | Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection". |
. Do not discharge into drains/surface waters/groundwater.
![Shop FACTORY OF EDTA 4NA-Detailed Image 25]()
Methods and material for containment and cleaning up | : | Collect spillage. Sweep up and shovel into suitable containers for disposal. Avoid generation of dust. |
Other information | : | Dispose of materials or solid residues at an authorized site. |
For further information refer to section 13.
![Shop FACTORY OF EDTA 4NA-Detailed Image 27]()
Precautions for safe handling | : | Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. Avoid generation of dust. Do not breathe dust/fume/gas/mist/vapors/spray. |
Hygiene measures | : | Do not eat, drink or smoke when using this product. Always wash hands after handling the product. |
Storage conditions | : | Keep tightly closed in a dry and cool place. |
EDTA 4Na (13235-36-4) |
Derived No Effect Level (DNEL) |
|
|
Inhalation Worker - inhalative, long-term – local Worker - inhalative, short-term – local Consumer - inhalative, long-term - local Consumer - inhalative, short-term - local | 1.5 mg/m³ 3 mg/m³ 0.6 mg/m³ 1.2 mg/m³ |
Oral Consumer - oral, long-term - systemic | 25 mg/kg bw/day |
Predicted No Effect Concentration (PNEC) |
|
|
Fresh Water | 2.2 mg/L |
|
Sea Water | 0.22 mg/L |
|
Intermittent releases to water | 1.2 mg/L |
|
Soil | 0.72 mg/L |
|
Impact on Sewage Treatment | 43 mg/L |
|
Appropriate engineering controls | : | Ensure good ventilation of the work station. |
Environmental exposure controls | : | Avoid release to the environment. |
Hand protection: |
Wear chemically resistant gloves (tested to EN374) in combination with intensive management supervision controls. |
Eye protection: |
Wear safety glasses with side shields (or goggles). |
Skin and body protection: |
Suitable protective clothing. |
Respiratory protection: |
In case of insufficient ventilation, wear suitable respiratory equipment. |
Physical state | : | Solid |
Appearance | : | White powder |
Color | : | white |
Odour | : | odourless |
Odour threshold | : | No data available |
pH | : | 10.5-11.5 |
Melting point | : | Decomposition >150℃) |
Freezing point | : | Not applicable |
Boiling point | : | No data available |
Flash point | : | Not applicable |
Relative evaporation rate (butylacetate=1) | : | No data available |
Flammability (solid, gas) | : | Not highly flammable solid. Combustible solid. |
Vapour pressure | : | 2E-012 hPa at 25°C) |
Relative vapour density at 20 °C | : | No data available |
Relative density | : | 1. 67(20 °C) |
Density | : | 1. 67 g/cm³ (20 °C) |
Solubility | : | Water: 500 g/l (20℃) |
Log Pow | : | No data available |
Auto-ignition temperature | : | >200°C at 1013.25 hPa |
Decomposition temperature | : | Decomposition >150℃) |
Viscosity, kinematic | : | Not applicable |
Viscosity, dynamic | : | No data available |
Explosive limits | : | Not applicable |
Explosive properties | : | Non explosive. |
Oxidising properties | : | No Oxidising |
No additional information available
![Shop FACTORY OF EDTA 4NA-Detailed Image 35]()
The product is non-reactive under normal conditions of use, storage and transport.
Stable under normal conditions.
No dangerous reactions known under normal conditions of use.
Dust formation.
![Shop FACTORY OF EDTA 4NA-Detailed Image 39]()
Strong oxidizing agents.
![Shop FACTORY OF EDTA 4NA-Detailed Image 40]()
Ammonia
Carbon oxides (COx) Nitrogen oxides (NOx)
![Shop FACTORY OF EDTA 4NA-Detailed Image 42]()
Acute toxicity | : | Harmful if inhaled. |
EDTA 4Na ( 13235-36-4) |
LD50 rat (oral) mate | 1913 mg/kg bw |
LD50 rat (oral) female | 1780 mg/kg bw |
LD50 rat (oral) female/male | >1780-<2000 mg/kg bw |
LOAEC (inhalation) | Ca. 30 mg/m³ air (male) based on: act. ingr. (Na2H2EDTA) (Basis for effect level: histopathology of the respiratory tract and lung weights) |
Skin corrosion/irritation | : | Causes skin irritation. |
Serious eye damage/irritation | : | Causes serious eye damage. |
Respiratory or skin sensitisation | : | No sensitization responses were observed. |
Germ cell mutagenicity | : | Not classified |
Carcinogenicity | : | Not classified |
Reproductive toxicity | : | Not classified |
STOT-single exposure | : | Not classified |
STOT-repeated exposure | : | May cause damage to organs through prolonged or repeated exposure. |
Aspiration hazard | : | Not classified |
![Shop FACTORY OF EDTA 4NA-Detailed Image 44]()
Ecology - general : The product is not considered harmful to aquatic organisms nor to cause long-term adverse effects in the environment.
Chemical Name | Algae/aquatic plants | Fish | Crustacea |
EDTA 4Na (13235-36-4) | EC50 (72 h): > 100 mg/L | LC50 (96 h): 41 mg/L test | EC50 (48 h): 140 mg/L test |
| test mat. (nominal) based | mat. (nominal) based on: | mat. (nominal) based on: |
| on: growth rate | mortality (34 - 62 mg/L, | mobility (100-180 mg/L)[ BASF AG |
| EC50 (72 h): > 60 mg/L | very soft water)[ Batchelder TL, | (1989)] |
| test mat. (meas. (geom. | Alexander HC, |
|
| mean)) based on: growth | McCarty WM | NOEC (21 d): 25 mg/L test |
| rate | (1980)] | mat. (nominal) based on: |
| NOEC (72 h): 79.4 mg/L | LC50 (96 h): 159 mg/L test | reproduction[BASF AG (1998)] |
| test mat. (nominal) based | mat. (nominal) based on: |
|
| on: growth rate | mortality (136-204 mg/L, |
|
| NOEC (72 h): 48.4 mg/L | medium hard water)[ EU Risk |
|
| test mat. (meas. (geom. | Assessment |
|
| mean)) based on: growth | (2004c)] |
|
| rate | LC50 (96 h): 532 mg/L test |
|
| LOEC (72 h): 99.9 mg/L | mat. (nominal) based on: |
|
| test mat. (nominal) based | mortality (473-598 mg/L, |
|
| on: growth rate | very hard water)[ EU Risk |
|
| LOEC (72 h): 60.6 mg/L | Assessment |
|
| test mat. (meas. (geom. | (2004d)] |
|
| mean)) based on: growth |
|
|
| rate[Akzo Nobel | NOEC (35 d): >= 25.7 |
|
| Chemicals | mg/L act. ingr. (H4EDTA) |
|
| Research, | (meas. (not specified))[ BASF AG |
|
| Environmental | (2001b)] |
|
| Chemistry |
|
|
| Department (2001)] |
|
|
12.2. Persistence and degradability
No additional information available
12.3. Bioaccumulative potential
Material does not bioaccumulate.
12.4. Mobility in soil
No additional information available
12.5. Other adverse effects
No additional information available
![Shop FACTORY OF EDTA 4NA-Detailed Image 46]()
Waste treatment methods | : | Dispose of contents/container in accordance with licensed collector’s sorting instructions. |
Sewage disposal recommendations | : | Disposal must be done according to official regulations. |
Product/Packaging disposal recommendations | : | Dispose in a safe manner in accordance with local/national regulations. |
![Shop FACTORY OF EDTA 4NA-Detailed Image 47]()
SECTION 14: Transport information
Department of Transportation (DOT) |
In accordance with DOT |
Not regulated |
Transportation of Dangerous Goods |
Not regulated |
Transport by sea |
Not regulated |
Air transport |
Not regulated |
SECTION 15: Regulatory information
15.1. US Federal regulations
No additional information available
15.2. International regulations CANADA
EU-Regulations
No additional information available
National regulations
EDTA 4Na (13235-36-4) |
Listed on the AICS (Australian Inventory of Chemical Substances) Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China) Listed on NZIoC (New Zealand Inventory of Chemicals) Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances) Listed on INSQ (Mexican National Inventory of Chemical Substances) Listed on the TCSI (Taiwan Chemical Substance Inventory) |
EDTA 4Na (13235-36-4) |
Listed on the AICS (Australian Inventory of Chemical Substances) Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China) Listed on NZIoC (New Zealand Inventory of Chemicals) Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances) Listed on INSQ (Mexican National Inventory of Chemical Substances) Listed on the TCSI (Taiwan Chemical Substance Inventory) |
15.3. US State regulations
Listed on TSCA (Toxic Substance Control Act)
SECTION 16: Other information
Data sources | : | ECHA reference. LOLI. |
Abbreviations and acronyms:
ADN | European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways |
ADR | European Agreement concerning the International Carriage of Dangerous Goods by Road |
IATA | International Air Transport Association |
IMDG | International Maritime Dangerous Goods |
RID | Regulations concerning the International Carriage of Dangerous Goods by Rail |