FACTORY OF SODIUM BENZOATE 99%

Material Safety Data Sheet

Section 1: Chemical Product and Company Identification

Product Name: Sodium benzoate

CAS#: 532-32-1

Synonym: Antimol; Benzoate of soda; Sodium benzoic acid; Benzoate sodium

Chemical Name: Benzoic acid, sodium salt

Chemical Formula: C7-H5-C-O2-Na

Section 2: Composition and Information on Ingredients

Composition:

Name Sodium benzoate

CAS # 532-32-1

Section 3: Hazards Identification

Potential Acute Health Effects:

Hazardous in case of skin contact (irritant), of eye contact (irritant), of inhalation. Slightly hazardous in case ingestion.

Potential Chronic Health Effects:

CARCINOGENIC EFFECTS: Not available.

MUTAGENIC EFFECTS: Not available.

TERATOGENIC EFFECTS: Classified POSSIBLE for human.

DEVELOPMENTAL TOXICITY: Classified Reproductive system/toxin/female, Reproductive system/toxin/male.

[SUSPECTED]

The substance is toxic to blood, the reproductive system, liver, central nervous system.

Repeated or prolonged exposure to the substance can produce target organs damage.

Section 4: First Aid Measures

Eye Contact:

Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention.

Skin Contact:

In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove contaminated clothing and shoes. Cold water may be used. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention.

Serious Skin Contact:

Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical attention.

Inhalation:

If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.

Serious Inhalation: Not available.

Ingestion:

Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms appear.

Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: May be combustible at high temperature.

Auto-Ignition Temperature: Not available.

Flash Points: Not available.

Flammable Limits: Not available.

Products of Combustion: These products are carbon oxides (CO, CO2).

Fire Hazards in Presence of Various Substances:

Slightly flammable to flammable in presence of heat.

Non-flammable in presence of shocks.

Explosion Hazards in Presence of Various Substances:

Risks of explosion of the product in presence of mechanical impact: Not available.

Slightly explosive in presence of open flames and sparks.

Fire Fighting Media and Instructions:

SMALL FIRE: Use DRY chemical powder.

LARGE FIRE: Use water spray, fog or foam. Do not use water jet.

Special Remarks on Fire Hazards: When heated to decomposition it emits acrid fumes and disodium oxide.

Special Remarks on Explosion Hazards:

Fine dust dispersed in air in sufficient concentration, and in the presence of an ignition source is a potential dust explosion hazard.

Section 6: Accidental Release Measures

Small Spill:

Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.

Large Spill:

Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system.

Section 7: Handling and Storage

Precautions:

Keep locked up. Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk, evaporate the residue under a fume hood. Ground all equipment containing material. Do not ingest. Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as oxidizing agents.

Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Hygroscopic.

Section 8: Exposure Controls/Personal Protection

Engineering Controls:

Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit.

Personal Protection:

Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.

Personal Protection in Case of a Large Spill:

Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product.

Section 9: Physical and Chemical Properties

Physical state and appearance: Solid.(powder or columnar or granular.)

Odor: Odorless.

Taste: Sweetish, astringent.

Molecular Weight: 144.11 g/mole

Color: White.

Melting Point: >300°C (572°F)

Vapor Density: 4.97 (Air = 1)

Dispersion Properties: See solubility in water.

Solubility: Easily soluble in cold water, hot water.

Section 10: Stability and Reactivity Data

Stability: The product is stable.

Instability Temperature: Not available.

Conditions of Instability: Excess heat, dust generation.

Incompatibility with various substances: React with oxidizing agents.

Special Remarks on Reactivity: Hygroscopic; keep container tightly closed.

Polymerization: Will not occur.

Section 11: Toxicological Information

Routes of Entry: Inhalation. Ingestion.

Chronic Effects on Humans:

TERATOGENIC EFFECTS: Classified POSSIBLE for human.

DEVELOPMENTAL TOXOCOTY: Classified Reproductive system/toxin/female, Reproductive system/toxin/male.

[SUSPECTED]

May cause damage to the following organs: blood, the reproductive system, liver, central nervous system(CNS).

Other Toxic Effects on Humans:

Hazardous in case of skin contact (irritant), of inhalation. Slightly hazardous in case of ingestion.

Special Remarks on Chronic Effects on Humans:

May cause adverse reproductive effects and birthdefects(teratogenic).

May affect genetic material(mutagenic)

Special Remarks on other Toxic Effects on Humans:

Acute Potential Health Effects:

Skin: May cause skin irritation.

Eyes: Dust may cause mechanical

Inhalation: May cause respiratory tract irritation.

Inhalation: Ingestion of large amounts may cause gastrointestinal tract irritation with gastric pain, nausea, and vomiting. May also affect behavior/central nervous system (tremor, convulsions, change in motor activity), and respiration (dyspnea).

Chronic Potential Health Effects:

Ingestion: Prolonged or repeated ingestion may affect behavior/central nervous system (sypmptoms similar to acute exposure) as well as liver, metabolism, blood, and urinary system.

Section 12: Ecological Information

Products of Biodegradation:

Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.

Toxicity of the Products of Biodegradation: The products itself and its products of degradation are more toxic.

Section 13: Disposal Considerations

Waste Disposal:

Waste must be disposed of in accordance with federal, state and local environmental control regulations.

Section 14: Transport Information

DOT Classification: Not a DOT controlled material (United States).

Identification: Not applicable.

Special Provisions for Transport: Not applicable.

Section 15: Other Regulatory Information

Federal and State Regulations: TSCA 8(b) inventory: Sodium benzoate

Other Regulations:

OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).

EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.

Other Classifications:

WHMIS (Canada): Not controlled under WHMIS (Canada).

DSCL (EEC):

R20/21/22- Harmful by inhalation, in contact with skin and if swallowed.

R36/38- Irritating to eyes and skin.

R63- Possible risk of harm to the unborn child.

S24/25- Avoid contact with skin and eyes.

HMIS (U.S.A.):

Health Hazard: 2

Fire Hazard: 1

Reactivity: 0

Personal Protection: E

National Fire Protection Association (U.S.A.):

Health: 2

Flammability: 1

Reactivity: 0

Specific hazard:

Protective Equipment:

Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Splash goggles.

Section 16: Other Information

References: Not available.

Other Special Considerations: Not available.

Created: 10/10/2006 08:14 PM

Last Updated: 10/10/2018 08:14 PM

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