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Tetrakis(hydroxymethyl)phosphonium sulfate THPS

TDS 5 Inquiries

Unit Price: Get Latest Price
CAS No.:

55566-30-8

Grade:

Industrial Grade

Content:

99%

Port:

QINGDAO

Brand:

EAST CHEMSOURCES

Packaging:

200kg drum

Price valid (until):

2024-03-15

Company Type:
Trader
Location:
China
Qualification:
Main Products:

Food additives,Pharmaceutical raw materials,Chemicals,Comestic raw materials

  • Product Description

  • Seller Information

  • Inquiry History

  • Description

    Shop TOLUENE DIISOCYANATE 26471-62-5-Detailed Image 1

    SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION
    MSDS Number: M650
    Effective Date: 1/11/2019
    Supersedes: 10/18/2010
    Product Name: Tetrakis (Hydroxymethyl) Phosphonium Sulfate (THPS,75%),
    Product Code: NEW-TECH Spec. 650
    Company Identification:
    EAST CHEMSOURCES LIMITED
    No.1581-12, Jinshui Road,
    Licang, Qingdao, China
    0086-532-81906761
    0086-532-81906761
    Phone:
    Fax:
    CHEMTREC (emergency):
    0086-532-81906761
    Outside China: 0086-532-81906761
    SECTION 2 – HAZARDS IDENTIFICATION
    OSHA
    EMERGENCY OVERVIEW
    Acidic liquid. Contact with the eyes may cause significant irritation or burns. May be harmful if absorbed through the skin,
    may cause skin sensitization. May be harmful if inhaled. Harmful if swallowed.
    POTENTIAL HEALTH EFFECTS
    INHALATION: Irritation to upper respiratory tract. May be harmful if inhaled.
    SKIN: Allergic skin reaction and sensitization may result from contact. Prolonged skin contact may cause irritation.
    EYES: Causes immediate severe irritation of the eye and eyelids. If not quickly removed by thorough irrigation with water,
    there may be prolonged or permanent visual impairment or total loss of sight.
    INGESTION: May be harmful if swallowed. May cause severe irritation to mucous membranes and respiratory tract.
    CLP/GHS
    Most important hazards:
    This mixture is classified as hazardous in accordance with regulation (ec) no 1272/2008. Classification:
    Acute toxicity - Category 3; h301
    Acute toxicity - Category 3; h331
    Serious eye damage/eye irritation - Category 1; h318
    Skin sensitization - Category 1; h317
    Reproductive toxicity - Category 2; h361d
    Acute aquatic hazard - Category 1; h400
    Chronic aquatic hazard - Category 1; h410
    The preparation is classified as dangerous in accordance with Directive 1999/45/EC. Hazardous classification:
    Xn - Harmful
    R22 - Harmful if swallowed.
    T - Toxic
    R23 - Toxic by inhalation.
    Xi - Irritant
    R41 - Risk of serious damage to eyes.
    R43 - May cause sensitization by skin contact.
    N - Dangerous for the environment
    R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.MATERIAL SAFETY DATA SHEET
    Tetrakis (Hydroxymethyl) Phosphonium Sulfate Solution 75% (THPS, 75%)
    Page 2 of 7
    Xn - Harmful
    Repr.Cat.3;R63 - Possible risk of harm to the unborn child.
    Label elements
    Signal word: Danger!
    Hazard statements
    H301 - Toxic if swallowed.
    H331 - Toxic if inhaled.
    H318 - Causes serious eye damage.
    H317 - May cause an allergic skin reaction.
    H361d - Suspected of damaging the unborn child.
    H410 - Very toxic to aquatic life with long lasting effects.
    Precautionary statements:
    P261 - Avoid breathing mist.
    P271 - Use only outdoors or in a well-ventilated area.
    P280 - Wear protective gloves and eye/face protection.
    P301+P310 - IF SWALLOWED: Immediately call a POISON CENTRE or doctor/physician.
    P330 - Rinse mouth.
    P304+P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
    P311 - Call a POISON CENTRE or doctor/physician.
    P302+P352 - IF ON SKIN: Wash with plenty of soap and water.
    P333+P313 - If skin irritation or rash occurs, seek medical advice/attention.
    P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
    easy to do. Continue rinsing.
    P310 - Immediately call a POISON CENTRE or doctor/physician.
    P501 - Dispose of contents/container in accordance with local regulation.
    Hazard pictograms:
    CARCINOGENICITY
    NTP? No
    IARC MONOGRAPHS? No
    OSHA REGULATED? No
    SECTION 3 – COMPOSITION / INFORMATION ON INGREDIENTS
    CAS#
    HAZARDOUS COMPONENTS
    %
    (by weight)
    OSHA PEL
    ACGIH TWA SARA
    TITLE
    III
    RQ
    LBS
    PPM MG/M3 PPM MG/M3
    55566-30-8 Tetrakis(hydroxymethyl)phosphonium sulfate
    75 - 77
    Not established
    0.12
    2
    7732-18-5
    Water
    23 - 25MATERIAL SAFETY DATA SHEET
    Tetrakis (Hydroxymethyl) Phosphonium Sulfate Solution 75% (THPS, 75%)
    Page 3 of 7
    SECTION 4 – FIRST AID MEASURES
    Inhalation: Remove affected person to fresh air; if breathing has not returned to normal within a few minutes after
    exposure, get medical attention.
    Skin: Remove contaminated clothing; wash affected area with soap and water; launder contaminated clothing before
    reuse; if irritation persists, seek medical attention.
    Eyes: Check for and remove contact lenses. Immediately, flush eyes for 15 minutes in clear running water while holding
    eyelids open; seek medical attention immediately.
    Ingestion: Drink two glasses of water followed by milk, milk of magnesia or other non-alcoholic liquids; Do not induce
    vomiting; seek medical attention immediately.
    SECTION 5 – FIRE FIGHTING MEASURES
    Flash Point (Method used):
    None
    Flammable Limits:
    LEL: Not Applicable UEL:
    Not Applicable
    Autoignition Temperature:
    534° F (279° C)
    NFPA CLASS: IIIB
    General Hazards: Contact with eyes causes immediate severe irritation of the eye and eyelids. Product will support
    combustion. Products of combustion include smoke, toxic fumes, oxides of carbon to include carbon monoxide,
    phosphorous oxides, phosphine and sulfur oxides.
    Extinguishing Media
    Carbon dioxide, water fog, dry chemical, chemical foam.
    Fire Fighting Procedure
    Self - contained respiratory equipment; cool containers to prevent pressure buildup and possible explosion when exposed
    to extreme heat. Caution - material will support combustion!
    Unusual Fire and Explosion Hazards:
    Closed containers can explode due to buildup of pressure when exposed to extreme heat.
    Hazardous Combustion Products:
    Products of combustion include smoke, toxic fumes, oxides of carbon to include carbon monoxide, phosphorous oxides,
    phosphine and sulfur oxides.
    SECTION 6 – ACCIDENTAL RELEASE MEASURES
    STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Product will support combustion. Avoid
    contact with eyes. Do not wash to sanitary sewer. Large spills - confine spill, soak up with approved absorbent, shovel
    product into approved container for disposal.MATERIAL SAFETY DATA SHEET
    Tetrakis (Hydroxymethyl) Phosphonium Sulfate Solution 75% (THPS, 75%)
    Page 4 of 7
    SECTION 7 – HANDLING AND STORAGE
    PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Keep container closed when not in use; protect
    containers from abuse; protect from extreme temperatures, open flames. This material will support combustion. Keep this
    and other chemicals out of reach of children.
    SECTION 8 – EXPOSURE CONTROLS / PERSONAL PROTECTION
    ENGINEERING CONTROLS:
    The use of local exhaust ventilation is recommended to control emissions near the source. Provide mechanical ventilation
    of confined spaces. Use corrosion-resistant, explosion-proof ventilation equipment.
    PERSONAL PROTECTION:
    RESPIRATORY PROTECTION (SPECIFY TYPE): None required while threshold limits are kept below maximum
    allowable concentrations; if TWA exceeds standard workplace limits, NIOSH approved respirator must be worn. Refer to
    29 CFR 1910.134 or European Standard EN149 for complete regulations.
    PROTECTIVE GLOVES: Neoprene, butyl or nitrile rubber gloves with cuffs.
    EYE PROTECTION: Chemical safety goggles. Refer to 29 CFR 1910.133 or European Standard EN166.
    OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Coveralls, apron, or other equipment should be worn to prevent
    skin contact, safety eyewash station nearby.
    WORK / HYGIENIC PRACTICES: Practice safe workplace habits. Minimize body contact with this, as well as all
    chemicals in general.
    SECTION 9 – PHYSICAL AND CHEMICAL PROPERTIES
    Vapor Pressure (MM Hg): 1.7 kPa @ 25° C
    Vapor Density (Air = 1) : >1
    Specific Gravity (water = 1): 1.37 - 1.40 @ 25°C
    Evaporation Rate (water = 1) : <1
    Solubility in Water: Complete
    Freezing Point: <-20°C (< -4°F)
    pH: 3 to 5
    Appearance and Odor: colorless liquid, characteristic odor
    Boiling Point: 229⁰F (109°C)
    Physical State:Liquid
    Viscosity: Like that of water
    Volatile Organic Compounds (Total VOC’s): NoneMATERIAL SAFETY DATA SHEET
    Tetrakis (Hydroxymethyl) Phosphonium Sulfate Solution 75% (THPS, 75%)
    Page 5 of 7
    SECTION 10 – STABILITY AND REACTIVITY
    Stability: Stable
    Conditions to Avoid: Avoid excessively high temperatures. Unstable at high pH.
    Incompatibility (Materials to Avoid): Strong oxidizers, strong alkalies, strong acids andstrong reducing agents
    Hazardous Decomposition or byproducts: Decomposition will not occur if handled and stored properly. In case of a
    fire, smoke, toxic fumes, oxides of carbon to include carbon monoxide, phosphorous oxides, phosphine and sulfur oxides
    will be produced.
    Hazardous Polymerization: Will not occur.
    Conditions to Avoid: None.
    SECTION 11 – TOXICOLOGICAL INFORMATION
    Hazardous Ingredients
    CAS #
    EINECS #
    LD50 of Ingredient
    (Specify Species and Route)
    LD50 of Ingredient
    (Specify Species)
    Tetrakis(hydroxymethyl)phosphonium
    sulfate
    55566-30-8 259-709-0
    248 mg / kg
    Oral – rat
    0.59 mg / L / 4H
    Inhalation – rat
    SECTION 12 – ECOLOGICAL INFORMATION
    Acute Toxicity
    Rainbow Trout 96hr
    EC50 - 119 mg/l
    Acute Toxicity
    Bluegill Fish 96hr
    EC50 - 93 mg/l
    Acute Toxicity
    Daphnia magna 48hr
    EC50 – 19.4 mg/l
    Acute Toxicity
    Algae 72hr
    EC50 – 0.16 mg/l
    Neither COD nor BOD data are available. Biodegradation measured at >20% within a 28-day period (OECD 302B).
    SECTION 13 – DISPOSAL CONSIDERATIONS
    WASTE DISPOSAL METHOD: Dispose of in accordance with Local, State, and Federal Regulations. Refer to "40 CFR
    Protection of Environment Parts 260 - 299" for complete waste disposal regulations for acidic materials. Consult your
    local, state, or Federal Environmental Protection Agency before disposing of any chemical.
    SECTION 14 – TRANSPORT INFORMATION
    Transport document description (IMDG):
    corrosive liquid, Toxic, N.O.S (contains tetrakishydroxymethyl phosphonium sulphate)
    Marine Pollutants - DOT requirements specific to Marine Pollutants do not apply to
    non-bulk packagings transported by motor vehicles, rail cars or aircraft.
    DOT Hazard Class / Pack Group:8( 6.1) / III IATA Hazard Class / Pack Group:8( 6.1) / III
    Reference: 49 CFR 173.153, .203, .241
    IMDG Hazard Class: 8 (6.1) / III
    UN/NA Identification Number: UN 2922
    RID/ADR Dangerous Goods Code: 8
    Label: Corrosive
    UN TDG Class / Pack Group: 8 ( 6.1) / III
    Hazard Symbols: T
    Hazard Identification Number (HIN): 8
    Marine Pollutant: YES
    Note: Transportation information provided is for reference only. Client is urged to consult CFR 49 parts 100 - 177, IMDG,
    IATA, EC, United Nations TDG, and WHMIS (Canada) TDG information manuals for detailed regulations and exceptions
    covering specific container sizes, packaging materials and methods of shipping.
    SECTION 15 – REGULATORY INFORMATION
    TSCA (Toxic Substance Control Act)
    All components of this product are listed on the U.S. Toxic Substances Control Act Chemical Inventory (TSCA Inventory).
    SARA Title III (Superfund Amendments and Reauthorization Act)
    311/312 Hazard Categories.
    Immediate health, delayed health
    313 Reportable Ingredients:
    None
    CERCLA (Comprehensive Response Compensation and Liability Act)
    None
    California Prop 65, Safe Drinking Water and Toxic Enforcement Act of 1986
    This product contains a maximum of 0.09% formaldehyde known to the state of California to cause cancer.
    Pennsylvania, the Worker and Community Right-to-Know Act of 1986
    This product contains a maximum of 0.09% formaldehyde an Environmental Hazard and Special Hazardous Substance.
    CPR (Canadian Controlled Products Regulations)
    This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the
    MSDS contains all the information required by the Controlled Products Regulations. WHMIS Classification: D2B, E.
    IDL (Canadian Ingredient Disclosure List)
    Components of this product identified by CAS number and listed on the Canadian Ingredient Disclosure List are shown in
    Section 3.MATERIAL SAFETY DATA SHEET
    Tetrakis (Hydroxymethyl) Phosphonium Sulfate Solution 75% (THPS, 75%)
    Page 7 of 7
    DSL / NDSL (Canadian Domestic Substances List / Non-Domestic Substances List)
    Components of this product identified by CAS number are listed on the DSL.
    EINECS (European Inventory of Existing Commercial Chemical Substances)
    Components of this product identified by CAS numbers are on the European Inventory of Existing Commercial Chemical
    Substances.
    SECTION 16 – OTHER INFORMATION
    Specific toxicity tests have not been conducted on this product. Our hazard evaluation is based on Information from
    similar products, the ingredients, technical literature, and/or professional experience.
    HMIS HAZARD RATINGS
    Health
    3
    *= Chronic Health Hazard
    2= Moderate
    Flammability
    1
    0= Insignificant
    3= High
    Physical Hazard
    0
    1= Slight
    4= Extreme
    Personal Protective Equipment C
    Safety Glasses, Gloves, Apron
    Revision Summary 
    Items Specifications






    Certificates

    Basic Info
    Product Name:

    Tetrakis(hydroxymethyl)phosphonium sulfate

    Other Name:

    Phosphonium,tetrakis(hydroxymethyl)-,sulfate (2:1);Phosphonium,tetrakis(hydroxymethyl)-,sulfate (2:1) (salt);Tetrakis(hydroxymethyl)phosphonium sulfate;Pyroset TKO;THPS;Octakis(hydroxymethyl)diphosphonium sulfate;THPS 75;Bis[tetrakis(hydroxymethyl)phosphonium] sulfate;Retardol S;Proban NX;Tolcide PS;Tolcide PS 75;Tolcide PS 200;Tolcide;Magnacide 575;Bis[tetra(hydroxymethyl)phosphonium] sulfate;Aqucar THPS 75;Pyroset TKOW;Tolcide 20A;Tolcide 70A;Eccoshield FR 101;Bricorr 75;Odycide B 320;58591-11-0;65257-04-7;1497435-72-9

    CAS No.:

    55566-30-8

    Molecular Formula:

    C4H12O4P.1/2O4S

    InChIKeys:

    InChIKey=HFDZMBPIARIWLN-UHFFFAOYSA-L

    Molecular Weight:

    252.18000

    Exact Mass:

    252.00700

    EC Number:

    259-709-0

    UNII:

    5I8RSL9E6S

    DSSTox ID:

    DTXSID0021331

    Color/Form:

    Crystalline solid

    HScode:

    2931900090

    Categories:

    Non-ionic Surfactants

    Characteristics
    PSA:

    180.32000

    XLogP3:

    -1.11140

    Appearance:

    Tetrakis(hydroxymethyl)phosphonium sulfate is a clear colorless viscous liquid. (NTP, 1992)

    Density:

    1.41 g/cm3 @ Temp: 20 °C

    Melting Point:

    -35ºC

    Boiling Point:

    111ºC

    Flash Point:

    96ºC

    Water Solubility:

    In water, 1X10+6 mg/L /miscible/ at 25 deg C (est)

    Storage Conditions:

    Keep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition so

    Vapor Pressure:

    8.12 mm Hg at 25 deg C (est)

    Henrys Law Constant:

    Henry's Law constant = 1.7X10-23 atm-cu m/mol at 25 °C (est)

    Experimental Properties:

    When heated to decomposition it emits toxic fumes of POx and SOx.|Clear colorless viscous liquid. Formula: C8H24O12P2S. Formula Mass: 406.27; MP: -35.0 °C; BP: 111 °C; VP: 32 mm Hg; Density: 1.381 g/cu cm at 20 °C /Pyroset TKO/|Hydroxyl radical reaction rate constant = 2.73X10-11 cu cm/molecule-sec at 25 °C (est)

    Air and Water Reactions:

    Water soluble.

    Reactive Group:

    Quaternary Ammonium and Phosphonium Salts

    Reactivity Profile:

    TETRAKIS(HYDROXYMETHYL)PHOSPHONIUM SULFATE is incompatible with oxidizing materials and alkalis. (NTP, 1992)

    Hazard Identification

    Classification of the substance or mixture

    Acute toxicity - Category 4, Oral

    Skin sensitization, Sub-category 1A

    Serious eye damage, Category 1

    Acute toxicity - Category 3, Inhalation

    Reproductive toxicity, Category 2

    Hazardous to the aquatic environment, short-term (Acute) - Category Acute 1

    Hazardous to the aquatic environment, long-term (Chronic) - Category Chronic 2

    GHS label elements, including precautionary statements

    Pictogram(s)
    Signal word

    Danger

    Hazard statement(s)

    H302 Harmful if swallowed

    H317 May cause an allergic skin reaction

    H318 Causes serious eye damage

    H331 Toxic if inhaled

    H361 Suspected of damaging fertility or the unborn child

    H400 Very toxic to aquatic life

    H411 Toxic to aquatic life with long lasting effects

    Precautionary statement(s)
    Prevention

    P264 Wash ... thoroughly after handling.

    P270 Do not eat, drink or smoke when using this product.

    P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

    P272 Contaminated work clothing should not be allowed out of the workplace.

    P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...

    P271 Use only outdoors or in a well-ventilated area.

    P203 Obtain, read and follow all safety instructions before use.

    P273 Avoid release to the environment.

    Response

    P301+P317 IF SWALLOWED: Get medical help.

    P330 Rinse mouth.

    P302+P352 IF ON SKIN: Wash with plenty of water/...

    P333+P317 If skin irritation or rash occurs: Get medical help.

    P321 Specific treatment (see ... on this label).

    P362+P364 Take off contaminated clothing and wash it before reuse.

    P305+P354+P338 IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

    P317 Get medical help.

    P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

    P316 Get emergency medical help immediately.

    P318 IF exposed or concerned, get medical advice.

    P391 Collect spillage.

    Storage

    P403+P233 Store in a well-ventilated place. Keep container tightly closed.

    P405 Store locked up.

    Disposal

    P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.

    Other hazards which do not result in classification

    no data available

    Handling and Storage

    Precautions for safe handling

    Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.

    Conditions for safe storage, including any incompatibilities

    Store the container tightly closed in a dry, cool and well-ventilated place. Store apart from foodstuff containers or incompatible materials.

  • Seller Information
    Business Type:

    Trader

    Main Products:

    Food additives,Pharmaceutical raw materials,Chemicals,Comestic raw materials

    Location:

    Room 501, Unit 6, No. 40, hushan road,Licang,Qingdao

    Payment Terms:

    TT against copy of documents,TT against B/L draft before shipment,100% TT in advance

    Average lead Time:

    10

    Total Annual Revenue:

    $1 million-$2.5 million

    Total Employees:

    11-50

    Year of Establishment:

    2017

    QINGDAO EASTCHEMSORCES TRADE LIMITED is a leading Manufactory supplier of Sorbitol, Citric acid, Sodium hypochlorite based in Qingdao, Shandong, China. With a commitment to quality and customer satisfaction, QINGDAO EASTCHEMSORCES TRADE LIMITED has become a trusted name in the industry. Our product line includes a range of high-quality Sorbitol, Citric acid, Sodium hypochlorite, which are available at competitive prices. QINGDAO EASTCHEMSORCES TRADE LIMITED has established itself as a reliable supplier of chemical products on the echemi.com.

  • Inquiry History
    5 Inquiries
    Country Product Purchase Quantity Date Posted
    India

    Tetrakis (hydroxymethyl) Phosphonium Sulfate

    7 MT Mar 21, 2024
    Poland

    Tetrakis Hydroxymethyl Phosphonium Sulfate

    400 MT May 22, 2026
    United States

    Thps 75%

    100  May 26, 2025
    India

    phosphonium sulfate

    500.00 KG Aug 21, 2025
    Egypt

    THPS 78%

    100 MT Oct 23, 2023
    Post an enquiry for this product
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