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Sulfur-free Odorant for Gas

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Content:

99%

Port:

dalian

Brand:

Agni

Packaging:

180Kg

Price valid (until):

2025-08-29

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Agni Environmental

Company Type:

Manufactory

Location:

China

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Main Products:

S-Free Odrant

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Product Description
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Description

Safety Data Sheet (SDS)

Product Name: Sulfur-Free Odorant
Prepared in accordance with GB/T 16483 and GB/T 17519
Revision Date: February 6, 2024
Initial Preparation Date: February 6, 2024
Version: 1.0

Section 1 Chemical Product and Company Identification

English Name of Chemical: Sulfur-Free Odorant
Product Number: -
Company Name: Jinzhou Liehuo Environmental Protection Technology Co., Ltd.
Address: No. 46-16, Huanghai Street, Songshan New District, Jinzhou City, Liaoning Province
Postcode: 121000
Fax: 0416-3903900
Tel: 0416-3903900
E-mail: jinzhouliehuo@163.com
Emergency Tel: 400-133-8859 (24h)
Recommended and Restricted Uses of Product: Used as an odorant for natural gas and city gas.

Section 2 Hazards Identification

Emergency Overview:
Highly flammable liquid and vapour. Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled. Cause serious eye irritation. May cause respiratory irritation. Cause skin irritation. May cause an allergic skin reaction. Harmful to aquatic organisms with long-term lasting effects.

GHS Hazard Categories:
Flammable Liquids: Category 2
Acute Oral Toxicity: Category 4
Acute Dermal Toxicity: Category 4
Skin Corrosion/Irritation: Category 2
Skin Sensitizer: Category 1
Serious Eye Damage/Eye Irritation: Category 2A
Acute Inhalation Toxicity: Category 4
Specific Target Organ Toxicity - Single Exposure: Category 3 (Respiratory irritation)
Hazardous to the Aquatic Environment - Long-term Hazard: Category 3

Label Elements:
Pictogram:
Signal Word:
Danger
Hazard Statements:
H225 Highly flammable liquid and vapour
H302 Harmful if swallowed
H312 Harmful in contact with skin
H315 Cause skin irritation
H317 May cause an allergic skin reaction
H319 Cause serious eye irritation
H332 Harmful if inhaled
H335 May cause respiratory irritation
H412 Harmful to aquatic organisms with long-term lasting effects

Precautionary Statements:
● Preventive Measures:
P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P264 Wash thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.

. Accident Response:
P303+P361+P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P370+P378 In case of fire: Use extinguisher to fight fire.
P301+P312 If swallowed: Call a poison center/doctor if you feel unwell.
P330 Rinse mouth.
P302+P352 If on skin: Wash with plenty of water.
P312 Call a poison center/doctor if you feel unwell.
P362+P364 Take off contaminated clothing and wash before reuse.
P304+P340 If inhaled: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/attention.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.

Safe Storage:
P403+P235 Store in a well-ventilated place. Keep cool.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.

. Waste Disposal:
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.

Physical and Chemical Hazards:
Highly flammable liquid and vapour.

Health Hazards:
Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled. Cause serious eye irritation. May cause respiratory irritation. Cause skin irritation. May cause an allergic skin reaction.

Environmental Hazards:
Harmful to aquatic organisms with long-term lasting effects.

Section 3 Composition/Information on Ingredients

Component	Concentration or Concentration Range (mass fraction, %)	CAS No.
Ethyl acrylate	59.9%	140-88-5
Methyl acrylate	38.0%	96-33-3
2-Ethyl-3-methylpyrazine	2.0%	15707-23-0
2,6-Di-tert-butyl-4-methylphenol	0.1%	128-37-0

Section 4 First-Aid Measures

First-Aid:
Inhalation: Immediately move to fresh air. If breathing is difficult, give oxygen. If breathing and heartbeat stop, immediately perform cardiopulmonary resuscitation. Seek medical attention.
Skin Contact: Immediately remove contaminated clothing and rinse thoroughly with plenty of flowing water. Seek medical attention.
Eye Contact: Immediately separate the eyelids and rinse thoroughly with flowing water or physiological saline. Seek medical attention.
Ingestion: Rinse mouth. Do not induce vomiting. Seek medical attention.

Advice to Rescuers: Move the patient to a safe place. Consult a doctor. Show this SDS to the doctor at the scene.
Special Instructions to Doctors: No data available

Section 5 Fire-Fighting Measures

Extinguishing Media:
Use water mist, dry powder, sand, foam or carbon dioxide extinguishing agents.
Avoid using straight water jet for fire fighting, as straight water may cause splashing of flammable liquids and spread the fire.

Special Hazards:
Flammable. Its vapours can form explosive mixtures with air, which can ignite and explode when exposed to open flames or high heat. Vapours are heavier than air and can spread to distant places at lower levels, and may ignite and backfire (flash explosion) when encountering ignition sources.

Fire-Fighting Precautions and Protective Measures:
Firefighters must wear full fire-resistant and toxic gas protective clothing and air respirators, and fight the fire upwind. In case of a large fire, firefighters must operate in a protected shelter. Spray water mist to keep the containers in the fire scene cool. If containers in the fire show abnormal changes or make abnormal sounds, they must be evacuated immediately.

Section 6 Accidental Release Measures

Protective Measures, Protective Equipment and Emergency Response Procedures for Operators:
Eliminate all ignition sources. Demarcate a warning zone based on the affected area of liquid flow and vapour diffusion, and evacuate irrelevant personnel from the crosswind and upwind directions to a safe area. It is recommended that emergency response personnel wear positive pressure self-contained breathing apparatus, anti-static clothing and rubber oil-resistant gloves. All equipment used during the operation must be grounded. Do not touch or cross the leaked material. Cut off the source of the leak as much as possible. Prevent the leaked material from entering water bodies, sewers, basements or confined spaces.
Small leaks: Absorb with sand or other non-combustible materials. Collect the absorbed materials with clean non-sparking tools.
Large leaks: Build dikes or dig pits for containment. Use alcohol-resistant foam to cover and reduce evaporation. Spraying water mist can reduce evaporation but cannot reduce the flammability of the leaked material in confined spaces. Transfer to tank trucks or special collectors with explosion-proof pumps. Spray water mist to disperse vapours and dilute liquid leaks.

Environmental Protection Measures: Contain the leaked material to avoid environmental pollution. Prevent the leaked material from entering sewers, surface water and groundwater.

Containment, Cleanup Methods for Leaked Chemicals and Disposal Materials Used:
Small leaks: Collect the leaked liquid in a sealable container as much as possible. Absorb with sand, activated carbon or other inert materials and transfer to a safe place. Do not flush into sewers.
Large leaks: Build dikes or dig pits for containment. Block drainage pipes. Cover with foam to inhibit evaporation. Transfer to tank trucks or special collectors with explosion-proof pumps for recovery or transportation to waste disposal sites for disposal.

Section 7 Handling and Storage

Handling Precautions:
No open flames, no sparks and no smoking. Closed systems, ventilation, explosion-proof electrical equipment and lighting. Do not use compressed air for filling, unloading or transferring. Use non-sparking hand tools. Operators should receive special training and strictly abide by operating procedures.
Handling should be carried out in places equipped with local ventilation or comprehensive ventilation facilities.
Avoid contact with eyes and skin, and avoid inhaling vapours.
For personal protective measures, see Section 8.
Keep away from fire sources and heat sources. No smoking in the workplace.
Use explosion-proof ventilation systems and equipment.
If filling is required, control the flow rate and equip with grounding devices to prevent static accumulation.
Avoid contact with incompatible substances such as oxidizing agents (see Section 10 for incompatible substances).
Handle with care during transportation to prevent damage to packaging and containers.
Empty containers may retain harmful substances.
Wash hands after use. Do not eat or drink in the workplace.
Equip with corresponding types and quantities of fire-fighting equipment and leak emergency treatment equipment.

Storage Precautions:
Fire-resistant equipment (conditions). Cool place. Store in the dark.

Section 8 Exposure Controls/Personal Protection

Occupational Exposure Limits:
USA (ACGIH): TLV-TWA: 5ppm; TLV-STEL: 15ppm

Biological Limits:
No data available

Monitoring Methods:
GBZ/T 160.1 ~ GBZ/T 160.81-2004 Determination of Toxic Substances in Workplace Air (series standards), EN 14042 Workplace Air - Guidelines for Procedures for Assessing Exposure to Chemical or Biological Agents

Engineering Controls:
Avoid all contact!
It is recommended that the workplace be separated from other workplaces.
Closed operation to prevent leakage.
Enhance ventilation.
Install automatic alarm devices and emergency ventilation facilities.
Set up emergency evacuation channels and necessary emergency escape areas.
Set up red warning lines, warning signs and warning instructions, and set up a communication alarm system.
Provide safety showers and eye wash equipment.

Personal Protective Equipment:
Respiratory Protection: Ventilation, local exhaust ventilation or respiratory protection.
Hand Protection: Protective clothing. Protective gloves.
Eye Protection: Safety glasses or eye protection combined with respiratory protection.
Skin and Body Protection: Wear chemical-resistant overalls.

Section 9 Physical and Chemical Properties

Appearance and Physical State: Colourless or slightly yellow liquid
Odour: Pungent irritating odour
pH Value: 7
Melting Point/Freezing Point (°C): < -70°C
Boiling Point, Initial Boiling Point and Boiling Range (°C): 78°C
Autoignition Temperature (°C): 397°C
Flash Point (°C): 5°C
Decomposition Temperature (°C): No data available
Explosion Limits [%(v/v)]: 1.6% ~ 23.0% (volume)
Evaporation Rate [butyl acetate (n-) = 1]: No data available
Saturated Vapour Pressure (kPa): 8,300 Pa. Temperature: 25°C.
Flammability (solid, gas): No data available
Relative Density (water = 1): 0.91 g/cm³
Vapour Density (air = 1): 3.44
Odour Threshold (mg/m³): No data available
n-Octanol/Water Partition Coefficient (lg P): Pure CAS 140-88-5: 1.32; Pure CAS 96-33-3: 0.8; Pure CAS 15707-23-0: log Pow = 1.42. Temperature: 25°C.
Solubility: Water solubility: 0.07%
Viscosity: No data available

Section 10 Stability and Reactivity

Stability: The product is stable under normal storage and use conditions at ambient temperature.

Hazardous Reactions: React violently with oxidizing agents, peroxides, strong alkalis and polymerization initiators. React violently with strong oxidizing agents, and the released heat may cause the reactants to burn. React with alkalis to release a certain amount of heat.

Conditions to Avoid: Static discharge, heat, moisture, exposure to sunlight, rain, etc.

Incompatible Substances: Strong oxidizing agents, acids, alkalis, peroxides.

Hazardous Decomposition Products: Carbon monoxide, carbon dioxide.

Section 11 Toxicological Information

Acute Toxicity:
Oral: Pure CAS 140-88-5: LD50 Rat oral 760-1020 mg/kg; Pure CAS 96-33-3: LD50 Rat oral 277 mg/kg; Pure CAS 15707-23-0: LD50 - rat (male/female) - 600 mg/kg bw.
Inhalation: Pure CAS 140-88-5: LC50 Rat inhalation 1000-2000 ppm/4 hr; Pure CAS 96-33-3: LC50 Rat inhalation 1350 ppm/4 hr.
Dermal: Pure CAS 140-88-5: LD50 Rabbit percutaneous 1800 mg/kg.

Skin Irritation or Corrosion:
No data available

Eye Irritation or Corrosion:
No data available

Respiratory or Skin Sensitization:
No data available

Germ Cell Mutagenicity:
No data available

Carcinogenicity:
No data available

Reproductive Toxicity:
No data available

Specific Target Organ Toxicity - Single Exposure:
This substance irritates the eyes, skin and respiratory tract.

Specific Target Organ Toxicity - Repeated Exposure:
Repeated or long-term exposure may cause skin sensitization. Tumours were found in experimental animals, but may not be relevant to humans.

Inhalation Hazard:
No data available

Section 12 Ecological Information

Ecotoxicity:
Acute Fish Toxicity Test: Pure CAS 140-88-5: LC50; Species: Pimephales promelas (Fathead minnow, age 32 days, length 18.7 mm, weight 0.095 g); Conditions: freshwater, flow through, 25.3 deg C, pH 7.5, hardness 46.9 mg/L CaCO3, alkalinity 39.7 mg/L CaCO3, dissolved oxygen 6.8 mg/L; Concentration: 2500 ug/L for 96 hr (95% confidence interval: 2310-2700 ug/L) /99% purity.
Acute Daphnia Immobility Test: Pure CAS 15707-23-0: EC50 - Daphnia magna - > 100 mg/L - 48 h.
Algae Growth Inhibition Test: Pure CAS 140-88-5: Algae: Microcystis aeruginosa: inhibition of cell multiplication starts at 14 mg/L; Pure CAS 96-33-3: EC50; Species: Pseudokirchneriella subcapitata (Green algae, age 3-7 days); Conditions: freshwater, static, 24 deg C, pH 6.3-9.3; Concentration: 15.53 mg/L for 96 hr (95% confidence interval: 0-46.78 mg/L); Effect: decreased population biomass; Pure CAS 15707-23-0: EC50 - Pseudokirchneriella subcapitata (previous names: Raphidocelis subcapitata, Selenastrum capricornutum) - > 100 mg/L - 72 h.

Toxicity to Microorganisms: No data available

Persistence and Degradability:
No data available

Bioaccumulative Potential:
No data available

Mobility in Soil:
No data available

Section 13 Disposal Considerations

Waste Chemicals:
Recycle as much as possible.
If recycling is not possible, dispose by incineration.
Do not dispose of this product by discharging into sewers.

Contaminated Packaging:
Return containers to the manufacturer or dispose in accordance with national and local regulations.

Disposal Precautions:
Refer to national and local regulations before disposal.
Refer to Section 8 for safety precautions of disposal personnel.

Section 14 Transport Information

UN Dangerous Goods No. (UN No.): UN1993
UN Transport Name: Flammable liquid, n.o.s.
UN Hazard Class: 3
Packing Group: II
Packing Methods: Pack in accordance with the manufacturer's recommended methods, such as: open steel drums. Ampoules in ordinary wooden cases. Screw-cap glass bottles, iron-cap pressure glass bottles, plastic bottles or metal drums (cans) in ordinary wooden cases, etc.
Marine Pollutant (Yes/No): Yes
Transport Precautions:
Marine pollutant.

Section 15 Regulatory Information

The following laws, regulations, rules and standards regulate the management of this chemical:

Component Ethyl acrylate CAS: 140-88-5
Law of the People's Republic of China on the Prevention and Control of Occupational Diseases:
Catalogue of Occupational Hazard Factors (2015): Not included
Regulations on the Safety Management of Hazardous Chemicals:
Catalogue of Hazardous Chemicals (2015): Included
Catalogue of Explosive-Prone Hazardous Chemicals (2017): Not included
Catalogue of Key Supervised Hazardous Chemicals:
First and Second Batches of Key Supervised Hazardous Chemicals Catalogues: Not included
Measures for the Environmental Management Registration of Hazardous Chemicals (Trial):
Catalogue of Key Environmentally Managed Hazardous Chemicals: Not included
Regulations on the Administration of Narcotic Drugs and Psychotropic Substances:
Catalogue of Narcotic Drugs: Not included
Catalogue of Psychotropic Substances: Not included
Measures for the Environmental Management of New Chemical Substances:
Inventory of Existing Chemical Substances in China (2013): Included

Component Methyl acrylate CAS: 96-33-3
Law of the People's Republic of China on the Prevention and Control of Occupational Diseases:
Catalogue of Occupational Hazard Factors (2015): Included
Regulations on the Safety Management of Hazardous Chemicals:
Catalogue of Hazardous Chemicals (2015): Included
Catalogue of Explosive-Prone Hazardous Chemicals (2017): Not included
Catalogue of Key Supervised Hazardous Chemicals:
First and Second Batches of Key Supervised Hazardous Chemicals Catalogues: Not included
Measures for the Environmental Management Registration of Hazardous Chemicals (Trial):
Catalogue of Key Environmentally Managed Hazardous Chemicals: Not included
Regulations on the Administration of Narcotic Drugs and Psychotropic Substances:
Catalogue of Narcotic Drugs: Not included
Catalogue of Psychotropic Substances: Not included
Measures for the Environmental Management of New Chemical Substances:
Inventory of Existing Chemical Substances in China (2013): Included

Component 2-Ethyl-3-methylpyrazine CAS: 15707-23-0
Law of the People's Republic of China on the Prevention and Control of Occupational Diseases:
Catalogue of Occupational Hazard Factors (2015): Not included
Regulations on the Safety Management of Hazardous Chemicals:
Catalogue of Hazardous Chemicals (2015): Not included
Catalogue of Explosive-Prone Hazardous Chemicals (2017): Not included
Catalogue of Key Supervised Hazardous Chemicals:
First and Second Batches of Key Supervised Hazardous Chemicals Catalogues: Not included
Measures for the Environmental Management Registration of Hazardous Chemicals (Trial):
Catalogue of Key Environmentally Managed Hazardous Chemicals: Not included
Regulations on the Administration of Narcotic Drugs and Psychotropic Substances:
Catalogue of Narcotic Drugs: Not included
Catalogue of Psychotropic Substances: Not included
Measures for the Environmental Management of New Chemical Substances:
Inventory of Existing Chemical Substances in China (2013): Included

Component 2,6-Di-tert-butyl-4-methylphenol CAS: 128-37-0
Law of the People's Republic of China on the Prevention and Control of Occupational Diseases:
Catalogue of Occupational Hazard Factors (2015): Not included
Regulations on the Safety Management of Hazardous Chemicals:
Catalogue of Hazardous Chemicals (2015): Not included
Catalogue of Explosive-Prone Hazardous Chemicals (2017): Not included
Catalogue of Key Supervised Hazardous Chemicals:
First and Second Batches of Key Supervised Hazardous Chemicals Catalogues: Not included
Measures for the Environmental Management Registration of Hazardous Chemicals (Trial):
Catalogue of Key Environmentally Managed Hazardous Chemicals: Not included
Regulations on the Administration of Narcotic Drugs and Psychotropic Substances:
Catalogue of Narcotic Drugs: Not included
Catalogue of Psychotropic Substances: Not included
Measures for the Environmental Management of New Chemical Substances:
Inventory of Existing Chemical Substances in China (2013): Included

Section 16 Other Information

Preparation and Revision Information:
This version is Version 1.0, prepared in accordance with GB/T 16483-2008, GB/T 17519-2013 and GB 30000 series classification standards.

References:
[1] International Programme on Chemical Safety: International Chemical Safety Cards (ICSC), URL: http://www.ilo.org/dyn/icsc/showcard.home.
[2] International Agency for Research on Cancer, URL: http://www.iarc.fr/.
[3] OECD Global Portal on Chemicals Information, URL: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en.
[4] U.S. CAMEO Chemicals Database, URL: http://cameochemicals.noaa.gov/search/simple.
[5] U.S. National Library of Medicine: ChemIDplus, URL: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp.
[6] U.S. Environmental Protection Agency: Integrated Risk Information System, URL: http://cfpub.epa.gov/iris/.
[7] U.S. Department of Transportation: Emergency Response Guidebook, URL: http://www.phmsa.dot.gov/hazmat/library/erg.
[8] German GESTIS - Database on Hazardous Substances, URL: http://gestis-en.itrust.de/.

Abbreviations and Acronyms:
MAC: Maximum Allowable Concentration, referring to the concentration of toxic chemicals that should not be exceeded at any time in the workplace during a working day.
PC-TWA: Permissible Concentration-Time Weighted Average, referring to the average allowable exposure concentration for an 8h working day and 40h working week, weighted by time.
PC-STEL: Permissible Concentration-Short Term Exposure Limit, referring to the allowable short-term (15 min) exposure concentration under the premise of complying with PC-TWA.

Other Information:
Adding stabilizers or polymerization inhibitors may affect the toxicological properties of this product. Do not take work clothes home.
For any questions, please contact sds@xixisys.com for consultation.

Disclaimer:
The information in this SDS applies only to the specified product and, unless otherwise specified, does not apply to mixtures of this product with other substances. This SDS only provides information on product use safety for those who have received appropriate professional training in the use of the product. Users of this SDS must make an independent judgment on the applicability of this SDS. The preparer of this SDS shall not be liable for any damages resulting from the use of this SDS.

Items	Specifications

Basic Info

Product Name:

Odorant for Gas

Categories:

Hydrocarbons and Derivatives

Seller Information

Business Type:
Manufactory

Main Products:
S-Free Odrant

Location:
No. 46-16, Huanghai Street, Songshan New District, Jinzhou City, Liaoning Province, China

Payment Terms:
TT against copy of documents,D/P,L/C,D/A,O/A,TT against B/L draft before shipment,100% TT in advance

Average lead Time:
200

Total Annual Revenue:
$2.5 million-$5 million

Total Employees:
51-100

Year of Establishment:
2008

Certifications:
ISO,EMS,OHS

Our company is a professional manufacturer of sulfur-free odorants for natural gas, with an annual production capacity of 8,000 tons. Currently, our products have been widely used by urban gas companies and well-received.Company Profile

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