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Boron tribromide CAS:10294-33-4

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CAS No.:

10294-33-4

Grade:

Industrial Grade

Content:

99%

Port:

SHANGHAI

Brand:

Orient

Packaging:

25kg/bag,500kg/bag, customized

Price valid (until):

2025-12-26

Company Type:
Trader
Location:
China
Qualification:
Main Products:

pharmaceutical intermediates,peptides,electronic chemicals

  • Product Description

  • Seller Information

  • Inquiry History

  • Description
    Boron tribromide Basic information
    General Description Physical and Chemical Properties Boron trichloride Toxicity Uses Production method
    Product Name: Boron tribromide
    Synonyms: Boron tribromide, 1M solution in methylene chloride, AcroSeal;Boron tribroMide, 1M soln. in heptane;BORON TRIBROMIDE FOR SYNTHESIS;BorontribroMide , 99% BBr3;Boron tribroMide, 1.0 M solution in CH2Cl2;Boron tribroMide, 1.0 M solution in heptane, SpcSeal;Boron tribroMide, 1.0 M solution in Methylene chloride, SpcSeal;Boron Tribromide (29% in Heptane, ca. 1mol/L)
    CAS: 10294-33-4
    MF: BBr3
    MW: 250.52
    EINECS: 233-657-9
    Product Categories: metal halide;Piperazine derivates;Deprotecting Reagents;Others;Protection and Derivatization;Inorganics;bc0001
    Mol File: 10294-33-4.mol
    Shop Boron tribromide  CAS:10294-33-4-Detailed Image 1

    Boron tribromide Chemical Properties
    Melting point  −46 °C(lit.)
    Boiling point  ~90 °C
    density  2.60 g/mL at 20 °C(lit.)
    vapor density  8.6 (vs air)
    vapor pressure  40 mm Hg ( 14 °C)
    refractive index  1.4340
    Fp  30 °F
    storage temp.  Poison room
    solubility  Miscible with ethanol and carbon tetrachloride.
    form  Solution
    color  colorless
    Specific Gravity 2.65
    Water Solubility  Reacts with water.
    Sensitive  Moisture Sensitive
    Merck  14,1347
    Dielectric constant 2.6(0℃)
    Stability: Stable, but reacts violently with water.
    InChIKey ILAHWRKJUDSMFH-UHFFFAOYSA-N
    CAS DataBase Reference 10294-33-4(CAS DataBase Reference)
    EPA Substance Registry System Boron tribromide (10294-33-4)

    Safety Information
    Hazard Codes  T+,C,F,N
    Risk Statements  14-26/28-35-40-62-11-67-65-50/53-37-51/53-48/20
    Safety Statements  9-26-28-36/37/39-45-23-33-16-62-61-60
    RIDADR  UN 3390 6.1/PG 1
    OEL Ceiling: 1 ppm (10 mg/m3)
    WGK Germany  3
    RTECS  ED7400000
    10-21
    TSCA  Yes
    HazardClass  8
    PackingGroup  I
    HS Code  28129090
    Hazardous Substances Data 10294-33-4(Hazardous Substances Data)


    Boron tribromide Usage And Synthesis
    General Description Boron tribromide is commercially available and is a strong Lewis acid. It is an excellent demethylating or dealkylating agent for ethers, often in the production of pharmaceuticals.
    Shop Boron tribromide  CAS:10294-33-4-Detailed Image 2
    boron tribromide lewis structure
    Additionally, it also finds applications in olefin polymerisation and in Friedel–Crafts chemistry as a Lewis acid catalyst. The electronics industry uses boron tribromide as a boron source in pre-deposition processes for doping in the manufacture of semiconductors. Boron tribromide is a colourless, fuming liquid compound containing boron and bromine. It is usually made by heating boron trioxide with carbon in the presence of bromine: this generates free boron that reacts vigorously with the bromine. Boron tribromide is used extensively in industries associated with pharmaceutical manufacturing, image processing, semiconductor doping, plasma etching, and photovoltaic manufacturing and as a reagent for different chemical processes.
    Physical and Chemical Properties Fuming colorless viscous liquid with a strong irritant, toxic. Melting point is-46 ℃, the boiling point is 91.3 ℃. It was dissolved in carbon tetrachloride. Easily decomposed by water, alcohol. light or thermal decomposition, heated to explode. It can react with the phosphorus, nitrogen, oxygen, sulfur, halogens, ammonia, alkali, phosphorus halides, phosphines, and many substituents of ammonia. A strong corrosive. Strong irritative to Skin, eye or mucous membrane. Approximate toxicity of hydrogen bromide. United States provides operating maximum allowable concentration of boron tribromide in environment Air is 1ppm (10mg/m3). It is obtained in laboratory by Aluminum tribromide reacting with boron trifluoride, then distillation. can be used as a source of doped semiconductor silicon, but also for the preparation of high purity boron and organic boride.
    Other related chemical reactions involved by boron tribromide:
    In hydroiodic, at 300~400 ℃ continuously fed in boron tribromide, obtained mixture of BIBr2 and BI2Br, BI3, and then separated by distillation, derived dibromo iodide boron.
    Boron tribromide reacts with adamantine, generates 1-bromo-adamantane.
    Boron trichloride Boron trifluoride, boron trichloride, boron tribromide and boron triiodide are four kinds of common boron halides, the last three kinds of halogenated boron can be made in the presence of carbonaceous reducing agent by the high-temperature oxidation reduction of halogens and diboron trioxide, the reaction equation is as follows: B2O3 + 3C + 3Cl2 = 2BCl3 + 3CO, boron trifluoride is obtained by interaction of hydrogen fluoride (fluorspar with concentrated sulfuric acid) and diboron trioxide. Boron halide are all covalent molecules, in the vapor state existing in a planar triangles single molecule. Boron atoms using sp2 hybrid orbitals, p orbital of boron atoms filled of electron in the vertical plane perpendicular to the empty p orbital plane of a halogen atom can form large π bond π64. Experimental results show that the measured bond length (such as B-Cl bond length is 173pm) is shorter than a single bond (single bond B-Cl bond length is 187pm), indicating the presence of large π bond. The melting points of all these four kinds of halides are low, boron trifluoride is the lowest, and the boiling point increases with the increase of atomic number of halogen, indicating four kinds of halide are covalent halide molecules, intermolecular attraction is van der Waals forces. In 4 kinds of halides, stability is declined from boron trifluoride in turn to boron triiodide. Boron halides are easily hydrolyzed to produce boric acid.


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    ——  Q&A  ——

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    Certificates

    Basic Info
    Product Name:

    Boron tribromide

    Other Name:

    Borane,tribromo-;Boron bromide (BBr3);Tribromoborane;Boron bromide;Boron tribromide;Tribromoboron;Boron(III) bromide;5967-37-3

    CAS No.:

    10294-33-4

    Molecular Formula:

    BBr3

    InChIKeys:

    InChIKey=ILAHWRKJUDSMFH-UHFFFAOYSA-N

    Molecular Weight:

    250.52

    Exact Mass:

    250.52

    EC Number:

    233-657-9

    UNII:

    A453DV9339

    ICSC Number:

    0230

    UN Number:

    2692

    DSSTox ID:

    DTXSID4065028

    Color/Form:

    Colorless, fuming liquid

    HScode:

    28129090

    Characteristics
    PSA:

    0

    XLogP3:

    3.61

    Appearance:

    colorless Solution

    Density:

    2.6431 g/cm3 @ Temp: 18.4 °C

    Melting Point:

    -46.0 °C

    Boiling Point:

    90 °C

    Flash Point:

    30 °F

    Refractive Index:

    1.434

    Water Solubility:

    Reacts with water.Miscible with ethanol and carbon tetrachloride.

    Storage Conditions:

    Poison room

    Vapor Pressure:

    40 mm Hg ( 14 °C)

    Vapor Density:

    8.6 (vs air)

    Flammability characteristics:

    Decomposes toxic bromide and boride gas in contact with water or heat

    Explosive limit:

    May explode in moist air

    Odor:

    Sharp, irritating odor

    Experimental Properties:

    Decomposes on contact with alcohol. This produces toxic and corrosive fumes of hydrogen bromide. Reacts with water. This produces hydrogen bromide gas.|Decomposed by water or alcohol|Vapor (gas) specific gravity: 8.64; ratio of specific heats of vapor (gas): 1.140; heat of fusion: 2.9 cal/g|Critical volume: 272 cu cm/mol|For more Other Experimental Properties (Complete) data for BORON TRIBROMIDE (7 total), please visit the HSDB record page.

    Air and Water Reactions:

    Fumes in air, evolving hydrobromic acid. Reacts vigorously with water or explosively [Mellor 5:124 1946-47]. Borob Tribromide reacts vigorously with water to generate gaseous HBr. Based on a scenario where the chemical is spilled into an excess of water (at least 5 fold excess of water), half of the maximum theoretical yield of Hydrogen Bromide gas will be created in 0.18 minutes. Experimental details are in the following: "Development of the Table of Initial Isolation and Protective Distances for the 2008 Emergency Response Guidebook", ANL/DIS-09-2, D.F. Brown, H.M. Hartmann, W.A. Freeman, and W.D. Haney, Argonne National Laboratory, Argonne, Illinois, June 2009.

    Reactive Group:

    Halogenating Agents

    Reactivity Alerts:

    Water-Reactive

    Reactivity Profile:

    BORON TRIBROMIDE strongly attacks wood and rubber with generation of flammable hydrogen gas. Reacts exothermically and violently with water. Mixing tungsten trioxide and boron tribromide caused an explosion when the reaction was not cooled in an ice bath.

    Ionization Potential:

    9.70 eV

    Flammable Limits:

    Noncombustible Liquid

    Physical Dangers:

    The vapour is heavier than air.

    Corrosivity:

    Strongly attacks metals and wood|Corrosive to rubber and bakelite|Corrosive to tissue

    Heat of Vaporization:

    30.5 kJ/mol at 91 °C

    Critical Temperature & Pressure:

    Critical temperature: 581 K (308 °C)

    Hazard Identification

    Classification of the substance or mixture

    Acute toxicity - Category 2, Oral

    Skin corrosion, Sub-category 1A

    Acute toxicity - Category 2, Inhalation

    GHS label elements, including precautionary statements

    Pictogram(s)
    Signal word

    Danger

    Hazard statement(s)

    H300 Fatal if swallowed

    H314 Causes severe skin burns and eye damage

    H330 Fatal if inhaled

    Precautionary statement(s)
    Prevention

    P264 Wash ... thoroughly after handling.

    P270 Do not eat, drink or smoke when using this product.

    P260 Do not breathe dust/fume/gas/mist/vapours/spray.

    P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...

    P271 Use only outdoors or in a well-ventilated area.

    P284 [In case of inadequate ventilation] wear respiratory protection.

    Response

    P301+P316 IF SWALLOWED: Get emergency medical help immediately.

    P321 Specific treatment (see ... on this label).

    P330 Rinse mouth.

    P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

    P363 Wash contaminated clothing before reuse.

    P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

    P316 Get emergency medical help immediately.

    P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

    P320 Specific treatment is urgent (see ... on this label).

    Storage

    P405 Store locked up.

    P403+P233 Store in a well-ventilated place. Keep container tightly closed.

    Disposal

    P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.

    Other hazards which do not result in classification

    no data available

    Handling and Storage

    Precautions for safe handling

    NO contact with water or steam. NO contact with hot surfaces. Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.

    Conditions for safe storage, including any incompatibilities

    Separated from incompatible materials. See Chemical Dangers. Cool. Dry. Ventilation along the floor.Separate from alkalies, oxidizing materials, alcohols, ethers, alkali metals, phosphorus, wood. Store in a cool, dry, well-ventilated location.

  • Seller Information
    Business Type:

    Trader

    Main Products:

    pharmaceutical intermediates,peptides,electronic chemicals

    Location:

    Room 102, 1st Floor, East Office Building, No. 45 Pengwan Road, Qianwan Bonded Port Area, Qingdao Zone, China (Shandong) Pilot Free Trade Zone

    Payment Terms:

    100% TT in advance

    Average lead Time:

    10

    Total Annual Revenue:

    $10 million-$25 million

    Total Employees:

    51-100

    Year of Establishment:

    2024

    A reliable supplier is like insurance.

    We are mainly specilized in supply of pharmaceutical intermediates, electronic chemicals,food additives, and other fine chemical products.
    Integrity is the foundation, quality is life. We would like to work together with you to build a greener and brighter future.

    Website: orientchem.cc
    Email: scarlett@orientchem.cc
    WhatsApp: +86 17753254221

  • Inquiry History
    3 Inquiries
    Country Product Purchase Quantity Date Posted
    Canada

    Boron tribromide

    1 KG Jul 5, 2024
    Norway

    Boron Tribromide

    2 L Jan 14, 2025
    Estonia

    Boron tribromide 99%

    21 KG Apr 12, 2024
    Post an enquiry for this product
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