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Home > Encyclopedia > 3-[[2-(Acetyloxy)ethyl][4-[2-(6-nitro-2-benzothiazolyl)diazenyl]phenyl]amino]propanenitrile

3-[[2-(Acetyloxy)ethyl][4-[2-(6-nitro-2-benzothiazolyl)diazenyl]phenyl]amino]propanenitrile

3-[[2-(Acetyloxy)ethyl][4-[2-(6-nitro-2-benzothiazolyl)diazenyl]phenyl]amino]propanenitrile structure

3-[[2-(Acetyloxy)ethyl][4-[2-(6-nitro-2-benzothiazolyl)diazenyl]phenyl]amino]propanenitrile 

structure
  • CAS No:

    68133-69-7

  • Formula:

    C20H18N6O4S

  • Chemical Name:

    3-[[2-(Acetyloxy)ethyl][4-[2-(6-nitro-2-benzothiazolyl)diazenyl]phenyl]amino]propanenitrile

  • Synonyms:

    Propanenitrile,3-[[2-(acetyloxy)ethyl][4-[2-(6-nitro-2-benzothiazolyl)diazenyl]phenyl]amino]-;Propanenitrile,3-[[2-(acetyloxy)ethyl][4-[(6-nitro-2-benzothiazolyl)azo]phenyl]amino]-;Propionitrile,3-[N-(2-hydroxyethyl)-p-[(6-nitro-2-benzothiazolyl)azo]anilino]-,acetate;3-[[2-(Acetyloxy)ethyl][4-[2-(6-nitro-2-benzothiazolyl)diazenyl]phenyl]amino]propanenitrile;C.I. 11122;C.I. Disperse Red 177;Resolin Red FRL;Serilene Red R-LS;Disperse Red 177;Disperse Red FRL;58051-98-2

  • Categories:

    Dyes and Pigments  >  Dye

3-[[2-(Acetyloxy)ethyl][4-[2-(6-nitro-2-benzothiazolyl)diazenyl]phenyl]amino]propanenitrile Basic Attributes

438.46

438.46

268-697-6

DTXSID8071146

Characteristics

165

5.42628

1.39

167 °C

665.8ºC at 760mmHg

356.4ºC

1.57e-06 M

Safety Information

P261, P272, P273, P280, P302+P352, P321, P333+P313, P363, P391, P501

H317

|Warning|H317 (87.76%): May cause an allergic skin reaction [Warning Sensitization, Skin]|P261, P272, P273, P280, P302+P352, P321, P333+P313, P363, and P501|Aggregated GHS information provided by 67 companies from 6 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

3-[[2-(Acetyloxy)ethyl][4-[2-(6-nitro-2-benzothiazolyl)diazenyl]phenyl]amino]propanenitrile Use and Manufacturing

Methods of Manufacturing

Using 2-amino-6-nitrobenzothiazole and N-cyanoethyl-N-acetoxyethylaniline as raw materials, first diazotize 2-amino-6-nitrobenzothiazole, and then diazotize with N- Cyanoethyl-N-acetoxyethyl aniline coupling product. After filtering, grinding and drying, the finished product is obtained. . Add 400g of H3PO4 to the diazotization reaction flask, raise the temperature to 60-65°C, add 2-amino-6-nitrobenzothiazole, stir to dissolve, reduce to room temperature and add 50g of co-solvent, continue to cool to 0-5 ℃, slowly add 12g of NaNO2 within 1-2h, and keep the reaction at 0-5℃ for 3h. Use after destroying excess sodium nitrite. Add 200g of water and 0.2g of dispersant into the coupling reaction flask, add 71g of N-cyanoethyl-N-acetoxyethylaniline in acetic acid solution (50%) with stirring, and after it is fully dispersed, cool to 0℃, add hydrochloric acid 40g, then add the above diazonium liquid dropwise within 1-1.5h, and continue to react at 0-5°C for 10h after the addition. The temperature is raised to 38°C and a certain amount of water is added, then filtered, washed, and dried to obtain a finished product.

Uses

Disperse red FRL is mainly used for dyeing and printing of polyester and its blended fabrics, suitable for high temperature and high pressure method and hot melt dyeing. High dyeing intensity, good level dyeing and bright color.

Propanenitrile, 3-[[2-(acetyloxy)ethyl][4-[2-(6-nitro-2-benzothiazolyl)diazenyl]phenyl]amino]-: ACTIVE

Computed Properties

Molecular Weight:438.5
XLogP3:4
Hydrogen Bond Acceptor Count:10
Rotatable Bond Count:9
Exact Mass:438.11102425
Monoisotopic Mass:438.11102425
Topological Polar Surface Area:165
Heavy Atom Count:31
Complexity:700
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes

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