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SEC-BUTYLAMINE

SEC-BUTYLAMINE structure

SEC-BUTYLAMINE 

structure
  • CAS No:

    33966-50-6

  • Formula:

    C4H11N

  • Chemical Name:

    SEC-BUTYLAMINE

  • Synonyms:

    (+/-)-2-BUTYLAMINE;2-BUTYLAMINE;(+/-)-1-METHYLPROPYLAMINE;SEC-AMINOBUTANE;SBA;(RS)-S-BUTYLAMINE;(+/-)-ButylamineAminobutane;sec-Butylamine, 99% (2-Aminobutane)

  • Categories:

    Organic Chemistry  >  Amides

Description

COLOURLESS LIQUID WITH CHARACTERISTIC ODOUR.


Colorless liquid with ammonia smell, mp-72℃, bp63℃, n20D1.3928, relative density 0.724, fp-19℃, and water, alcohol mix.


ChEBI: Sec-butylamine is a primary aliphatic amine that is butane in which one hydrogen at position 2 is replaced by an amino group. A fumigant fungicide with a high potential for bioaccumulation, it is not approved for fungicidal use in the European Union. It has a role as an antifungal agrochemical. It is a primary aliphatic amine and an aliphatic nitrogen antifungal agent.

SEC-BUTYLAMINE Basic Attributes

73.14

73.14

684-161-8

29211990

Characteristics

26

0.74

0.724 g/mL at 25 °C(lit.)

−72 °C(lit.)

63 °C(lit.)

−3 °F

n20/D1.3928(lit.)

Solubility in water: miscible

-20°C

Vapour pressure, kPa at 20°C: 18

Relative vapour density (air = 1): 2.52

Containers may explode in fire.

-20°C

Safety Information

II

3

UN 2733 3/PG 2

2

F,C,N

9-16-26-28-36/37/39-45-61

EO3325000

F,C,N

Fireproof. Separated from strong oxidants and strong acids. Cool. Dry. Keep in a well-ventilated room.

Stable

P210, P233, P240, P241, P242, P243, P260, P261, P264, P270, P271, P273, P280, P301+P312, P301+P330+P331, P303+P361+P353, P304+P312, P304+P340, P305+P351+P338, P310, P312, P321, P330, P363, P370+P378, P391, P403+P235, P405, P501

11-20/22-35-50

UN 2733 3/PG 2

SEC-BUTYLAMINE Use and Manufacturing

Methods of Manufacturing

The preparation method is obtained by the action of methyl ethyl ketone and ammonia. Add methyl ethyl ketone and Raney nickel to the autoclave, add gaseous ammonia after evacuating the air, heat to 160℃, pressure to 4MPa, and then hydrogenate to pressure 6MPa, hydrogenate 3 times before and after, all react for 10h, and let it stand overnight. Cool down to room temperature, discharge the material, filter out the nickel powder, add dilute sulfuric acid under ice water cooling, the temperature does not exceed 30 ℃, steam distill the sulfate to remove sec-butanol, the resulting sulfate solution is concentrated under reduced pressure and dehydrated Obtain sec-butylamine sulfate, add alkali for fractional distillation and refining to obtain finished products.

Uses

It is mainly used as an organic raw material for the synthesis of drugs, dyes, and pesticides, dextromethamine herbicides, etc.

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