Bis[dichloro[η5-(pentamethylcyclopentadienyl)]rhodium]
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![Bis[dichloro[η5-(pentamethylcyclopentadienyl)]rhodium] structure](https://file.echemi.com/fileManage/upload/cas/45/9f69c5a5-9a83-4f7f-8c18-027a5e551cb8.gif "Bis[dichloro[η5-(pentamethylcyclopentadienyl)]rhodium]")
Bis[dichloro[η5-(pentamethylcyclopentadienyl)]rhodium]
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CAS No:
12354-85-7
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Formula:
C20H30Cl4Rh2
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Chemical Name:
Bis[dichloro[η5-(pentamethylcyclopentadienyl)]rhodium]
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Synonyms:
Rhodium,di-μ-chlorodichlorobis[(1,2,3,4,5-η)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di-;1,3-Cyclopentadiene,1,2,3,4,5-pentamethyl-,rhodium complex;Di-μ-Chlorodichlorobis(pentamethyl-π-cyclopentadienyl)dirhodium;Tetrachlorobis(pentamethylcyclopentadienyl)dirhodium;Di-μ-chlorodichlorobis(pentamethylcyclopentadienyl)dirhodium;Bis(dichloro(pentamethylcyclopentadienyl)rhodium);Bis(chloro(μ-chloro)(η5-pentamethylcyclopentadienyl)rhodium);Tetrachlorobis(η5-pentamethylcyclopentadienyl)dirhodium;Bis[dichloro[η5-(pentamethylcyclopentadienyl)]rhodium];Bis(μ-chloro)bis(chloro(η5-pentamethylcyclopentadienyl)rhodium);Dichlorobis(μ2-chloro)bis(η5-pentamethylcyclopentadienyl)dirhodium;(η5-Pentamethylcyclopentadienyl)rhodium dichloride dimer;Bis(pentamethylcyclopentadienylrhodium dichloride);Di-μ-chlorodichlorobis((η5-pentamethylcyclopentadienyl)rhodium);Dichloro(pentamethylcyclopentadienyl)rhodium dimer;Di-μ-chlorobis[chloro(η5-pentamethylcyclopentadienyl)rhodium];Pentamethylcyclopentadienerhodium dichloride dimer;Dichloro(pentamethylcyclopentadienyl)rhodium(II) dimer;Dichloro(pentamethylcyclopentadienyl)rhodium(III) dimer;Di-μ-chlorodichlorobis(η5-pentamethylcyclopentadienyl)dirhodium;(Pentamethylcyclopentadienyl)rhodium dichloride dimer;Pentamethylcyclopentadienylrhodium(III) chloride dimer;[RhCl2Cp*]2;51160-00-0;60867-02-9;1629020-38-7;1845755-27-2;2249844-06-0
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CAS No:
Characteristics
0.00000
8.70200
red crystal
>300°C
soluble in chloroform and acetone. Slightly soluble in tetrahydrofuran and methanol. Insoluble in water and diethylether
Safety Information
NONH for all modes of transport
3
20/21/22-36/37/38-R36/37/38-R20/21/22
26-36-S36-S26-24/25
Xn
P261-P280-P305 + P351 + P338
H302-H312-H315-H319-H332-H335
Bis[dichloro[η5-(pentamethylcyclopentadienyl)]rhodium] Use and Manufacturing
Oxidative olefination reactions C-C bond cleavage of secondary alcohols Ortho C-H olefination of phenol derivatives Oxidative annulation of pyridines Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2 C-H bond A
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Bis[dichloro[η5-(pentamethylcyclopentadienyl)]rhodium]
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