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Home > Encyclopedia > TRIS(3-METHOXYPHENYL)PHOSPHINE

TRIS(3-METHOXYPHENYL)PHOSPHINE

TRIS(3-METHOXYPHENYL)PHOSPHINE structure

TRIS(3-METHOXYPHENYL)PHOSPHINE 

structure
  • CAS No:

    29949-84-6

  • Formula:

    C21H21O3P

  • Chemical Name:

    TRIS(3-METHOXYPHENYL)PHOSPHINE

  • Synonyms:

    Tris(m-methoxyphenyl)phosphine, 98+%;tris(3-Methoxyphenyl)phosphane;Tris(3-methoxyphenyl)phosphine,98%;Tris(3-methoxyphenyl);TRIS(M-METHOXYPHENYL)PHOSPHINE;TRIS(M-ANISYL)PHOSPHINE;TRIS(3-METHOXYPHENYL)PHOSPHINE;Phosphine,tris(3-methoxyphenyl)-

  • Categories:

    Organic Chemistry  >  Phosphines

Description

White to almost white crystalline powder

TRIS(3-METHOXYPHENYL)PHOSPHINE Basic Attributes

352.36

352.122833

1312995-182-4

132543

DTXSID80184054

2931900090

Characteristics

27.7

4.5

White to almost white Crystalline Powder

113-115 °C(lit.)

476.3°C at 760 mmHg

301.7±27.6 °C

8.9E-09mmHg at 25°C

Safety Information

3

36/37/38

26-37/39

Xi

P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, P501

H315

|Warning|H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]|P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, and P501|Aggregated GHS information provided by 43 companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

TRIS(3-METHOXYPHENYL)PHOSPHINE Use and Manufacturing

Methods of Manufacturing

General procedure: To a solution of 1 (0.2 mmol) in 2 mL of CH3CN/H2O(v/v = 100/1) was added Selectfluor (71 mg, 0.2 mmol). The mixture was stirred at room temperature for 5-60minutes. After removal of the solvent, the residue was then purified by flash column chromatography on silica gel with petroleum ether/ethyl acetate to give the desired product 2.

Uses

suzuki reaction

Computed Properties

Molecular Weight:352.4
XLogP3:4.5
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:6
Exact Mass:352.12283153
Monoisotopic Mass:352.12283153
Topological Polar Surface Area:27.7
Heavy Atom Count:25
Complexity:334
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes

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